• Journal of the Korean Crystal Growth and Crystal Technology
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• 제25권1호
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• pp.27-31
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• 2015

The degradation of refractories can be caused by erosion, friction of abrasive particles, as well as by corrosion by molten slag in the gasification reactors. There was little knowledge about the erosion of refractories so far. The castable refractories of which the maximum applying temperature of 1300 and $1500^{\circ}C$ were abraded using SiC particles varying the incidence angles. It was revealed that the maximum abrasion was occurred at the incidence angle of $60{\sim}75^{\circ}$ not at $90^{\circ}$ and thought that the porosity of the refractories was the principle factor.

• Transactions of the Korean hydrogen and new energy society
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• 제25권1호
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• pp.97-104
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• 2014

In a coal gasifier for IGCC, hot syngas leaving the gasifier at about 1550oC is rapidly quenched by cold syngas recycled from the gas cleaning process. This study investigated the flow and heat transfer characteristics in the gas quench system of a commercial IGCC process plant under different operating pressures. As the operating pressure increased from 30 bar to 50 bar, the reduced gas velocity shortened the hot syngas core. The hot fly slag particles were retained within the core more effectively, and the heat transfer became more intensive around the hot gas core under higher pressures. Despite the high particle concentrations, the wall erosion by particle impaction was estimated not significant. However, large particles became more stagnant in the transfer duct due to the reduced gas velocity and drag force under higher pressures.

• Journal of the Korean Society of Combustion
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• 제18권1호
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• pp.21-26
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• 2013

In the Shell coal gasification process, the syngas produced in a gasifier passes through a syngas cooler for steam production and temperature control for gas cleaning. Fly slag present in the syngas may cause major operational problems such as erosion, slagging, and corrosion, especially in the upper part of the syngas cooler (gas reversal chamber, GRC). This study investigates the flow, heat transfer and particle behaviors in the GRC for a 300 MWe IGCC process using computational fluid dynamics. Three operational loads of 100%, 75% and 50% were considered. The gas and particle flows directly impinged on the wall opposite to the syngas inlet, which may lead to erosion of the membrane wall. The heat transfer to the wall was mainly by convection which was larger on the side wall at the inlet level due to the expansion of the cross-section. In the evaporator below the GRC, the particles were concentrated more on the outer channels, which needs to be considered for alleviation of fouling and blockage.

• 한국연소학회:학술대회논문집
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• 한국연소학회 2012년도 제45회 KOSCO SYMPOSIUM 초록집
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• pp.107-109
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• 2012

In Korean coal power plants, rising coal prices have recently led to the rapid utilization of low lank coals such as sub-bituminous coal with low calorific values and low ash fusion temperatures. Using these coals beyond the design range has resulted in important issues including slagging and fouling, which cause negative effects in boiler performances and unstable operations. The purpose of this study is to observe slagging and fouling characteristics resulted from burning various ranks of pulverized coals. We have tested 3 different coals: FLAME(bituminous), KCH(sub-bituminous) and MOOLARBEN(bituminous)coals in the pilot system $50kW_{th}$ scale. A stainless steel tube with preheated air inside was installed in the downstream in order to simulate water wall. Collected ash on the probe and the slag inside the furnace near burner were analyzed by SEM (scanning electron microscopy) to verify the formation degree, surface features and color changes of the pasty ash particles. Induced coupled plasma and energy dispersive X-ray spectroscopy were also performed to figure out the chemical characteristics of collected samples. As a result, KCH was observed that more slag was developed inside the walls of the furnace and on the probe than the other two kinds of coals, as shown in the calculate slagging and fouling indices as well.

• Journal of the Korea Institute of Building Construction
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• 제15권6호
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• pp.597-605
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• 2015

The method of concrete mix design used in this study aims to achieve the identical specified design strength, applying different types and replacement ratio of mineral admixtures and afterwards, fire tests were conducted using the standard time-temperature curve specified in the ASTM E119 to identify the influences of the types of mineral admixtures on the fire resistance performance of high strength concrete(HSC). The least spalling was observed in the test specimen containing blast furnace slag as a partial replacement of cement, while the most significant spalling phenomena were observed in the blast furnace slag test specimen that silica-fume was added in. In particular, the reasonable volume of spalling was observed when solely replaced by silica fume. However, the influence of the cement replacement by silica fume and blast furnace slag on the increases of spalling can be explained through blocked pores by the fine particles of silica fume, leading to decreases in permeability.

• Proceedings of the Korea Concrete Institute Conference
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• 한국콘크리트학회 2008년도 춘계 학술발표회 제20권1호
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• pp.677-680
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• 2008

The surface of particles was energetically modified by inter-grinding OPC and BFS in vibration mill for improvement of the early strength and low-heat evolution of concretes. BFS was pre-grinding in ball-mill to 2535(BS2) and 3245 $cm^2/g$(BS3), in blaine surface area. The inter-grinding time in vibration mill was changed from 10 minutes to 30 minutes. And Mixing ration of BFS to OPC was changed in 60, 70, 80%. After inter-grinding, the change of specific surface area, particle size distribution, hydration heat of cement and compressive strength of mortar were measured. As the result of comparison test with LHC, it was found that the mixture and inter-grinding time satisfying the value of over 100% of compressive strength for 7 days and under 170J/g of heat of hydration for 72 hours. and it was confirmed that the possibility of low heat slag cement utilizing blast furnace slag(BS2, BS3) with the low fineness in high volumes.

• Transactions of the Korean hydrogen and new energy society
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• 제22권5호
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• pp.686-698
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• 2011

Mathematical models for char-slag interaction and near-wall particle segregation developed by Montagnaro et. al. were applied to predict various aspects of coal gasification in an up-flow entrained gasifier of commercial scale. For this purpose, some computer simulations were performed using gPROMS as the numerical solver. Typical design parameters and operating conditions of the commercial gasifiers were used as input values for the simulation. Development of a densely dispersed phase of solid carbon was found to have a critical effect on both carbon conversion and ash flow behavior. In general, such a slow-moving phase was turned out to enhance carbon conversion by lengthening the residence time of char or soot particles. Furthermore, it was also found that guiding the transfer of char or soot into the closer part of the wall to coal burner is favorable in terms of gasification efficiency and vitrified ash collection. Finally, to a certain degree densely dispersed phase of carbon showed an yield-enhancing effect of syngas.

• Journal of the Korea Institute of Building Construction
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• 제19권5호
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• pp.391-399
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• 2019

This study reviewed the possibility of recycling into exhausted aggregate resources in Korea as a means of utilizing coal gasification slag(CGS) from integrated gasification combined cycle(IGCC) while being commissioned in order to introduce the new system to Korea. In other words, in order to solve the problem of insufficient aggregate resources, CGS generated by IGCC as a residual aggregate for concrete secondary products, which is an empty mortar, was considered to replace CGS in the range of 0 to 100 % for mixed residual aggregate mixed with crushed sand A(CSa) of good quality and sea sand(SS) of deep particles, which are the most commonly used in the domestic construction industry. According to the study, replacing CGS with CSa or crushed sand B(CSb)+SS by 25 % to 50 % resulted in good results in the aspect of the granularity of the aggregate and the workability and compressive strength of cement mortar, which were found to be usable.

• Journal of the Architectural Institute of Korea Structure & Construction
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• 제35권9호
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• pp.199-206
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• 2019

Experimental study on the durability characteristics to examine the feasibility of concrete with high water-tightness and self-healing performance to minimize maintenance of concrete for artificial ground is as follows. 1) When blending agent, swelling agents, and curing accelerator were added on the ternary system cement with blast-furnace slag fine particles and fly ash to give a self-healing property, higher blending strengths by 82% at design standard strength of 24MPa and by 74% at design strength of 30MPa, respectively could be obtained. 2) The permeability test for the specimens having high water-tightness and no shrinkage showed that the permeability was reduced at maximum of 98%. However, the permeability was decreased as the design strength was increased, showing the reduction rate of 87% at the design strength of 50MPa. 3) The depth of carbonation of blast-furnace slag and fly ash was increased in all the specimens compared with those of OPC only. However, as the material age was increased, carbonation penetration depth was decreased compared with the reference blend. 4) Compared with the reference blending using only OPC, the freeze-thaw resistance was higher in the case of blending with 40% of blast-furnace slag and 10% of fly ash at the design standard strength of 50MPa. In addition, the freeze-thaw resistance in general was superior in the design standard strength of 50MPa with the lower water-binder ratio (W/B) as compared with the design standard strength of 24MPa and 30MPa with the high water-binder ratios.

• Journal of the Korean Recycled Construction Resources Institute
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• 제12권1호
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• pp.94-101
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• 2024

In this paper, the performance of air pollution reduction by coating the photocatalyst solution on the mortar surface was analyzed to ensure the possibility of applying the photocatalyst to structures with a large specific surface area. The photocatalytic concentrations of the coating solution were set to 1.5 % and 3.0 %, and the types of binders were considered as experimental variables, such as ultra-high performance concrete (UHPC), ordinary portland cement (OPC), and blast furnace slag. As the photocatalyst concentration increases, the air pollution reduction performance increases. In addition, as a result of the air pollution reduction performance, the NO_x concentration reduction rate was the highest for UHPC, and the air pollution reduction performance increased as the blast furnace slag was replaced. Therefore, the amount of TiO₂ remaining on the surface varies depending on the density of the tissue due to the difference in particles caused by the difference in the amount of TiO₂ remaining on the surface.