• Journal of the Korean Institute of Telematics and Electronics
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• v.16 no.6
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• pp.11-15
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• 1979

Electrical switching phenomenon was observed in the Fe2O3-Bi2O3 system for the sintering temperature range of 700$^{\circ}$~85$0^{\circ}C$ for DC conductivity measurements of these sinterd materials in the ambient temperature range of 30$^{\circ}$~20$0^{\circ}C$ have shown that the conductivity increases with increasing the sitering temperature and ambient temperature. The formation of the current channel and the experimental evidence of the dependence of switching threshold voltage on the ambient temperature, strongly indicates that the main electrical switching mechanism of sintered Fe2O3-Bi2O3 is thermal effect.

• Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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• 1993.05a
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• pp.88-91
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• 1993

In this study 9.5/65/35 PLZT was selected which has the excellent quadratic electro-optic property and slim-loop. It was fabricated by the methods of vacuum hot-pressing and sintering. The electrode of color filter was evaporated using the interdigital type masks. Hysteresis and transmission characteristics were measured. The coercive field and the nontransmited field were correlative. Aging effect was measured according to time at same temperature. Wavelengths of RGB were chosen 700[nm] for red, 545[nm] for green and 435[nm] for blue by the standard of the Commission Internationale del Eclaiage.

• Proceedings of the Korean Society of Precision Engineering Conference
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• 1994.10a
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• pp.169-175
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• 1994

This study attempts to develop a process which can produce three-dimensional shapes of metals directly from CAD data. Prototypes made from metals, can not only be used to test the mecchanical properties of the product, but also potentially become the actual die or product itself. The test-device of the process has been designed and manufactured. The laser scanning method using a scanning path schedule composed of circle and arc elements, scanning speed variation method and dwell method have been developed, which resist warping phenomenon and increase the adhesiveness between the layers. For the production of prototypes with pure iron powder, the optimal values of the principal process parameters have been determined, through which cross-shaped and twisted clover-shaped prototypes have been fabricated. In order to improve the strength of the prototype, the experimental studies of solid-phase sintering, and copper infiltration have been done.

• Journal of the Korean Ceramic Society
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• v.28 no.3
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• pp.179-188
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• 1991

The semiconducting BaTiO3 ceramics used in this study were sintered in the reducing atomosphere(hydrogen gas) and neutral atmosphere(nitrogen gas), then were heat-treated in air to vary defect concentrations. In this experiment, the correlations between the composition analysis and electrical characteristics of these samples were investigated. When the BaTiO3 ceramics were sintered in N2 atmosphere, it was observed that the Ba contents near the interface were lower than that of the grain center, and these samples showed superior PTCR effects. From analysis of the resistivities of grains and grain boundaries by CIRM(Complex Impedance Resonance Method), it was confirmed that the PTCR effects were caused by the resistivity of grain boundaries. And from measurement of the capacitance at each temperature, the samples sintered in N2 atmosphere show the increase of room temperature resistance and the decrease of capacitance as a result of the increase of the charge depletion layers. This phenomenon agrees well with the cation deficiencies in the analytical results.

• Korean Journal of Materials Research
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• v.30 no.6
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• pp.301-307
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• 2020

In this study, factors considered to be causes of promotion of densification of sintered pellets identified during phase change are reviewed. As a result, conclusions shown below are obtained for each factor. In order for MA powder to soften, a temperature of 1,000 K or higher is required. In order to confirm the temporary increase in density throughout the sintered pellet, the temperature rise due to heat during phase change was found not to have a significant effect. While examining the thermal expansion using the compressed powder, which stopped densification at a temperature below the MA powder itself, and the phase change temperature, no shrinkage phenomenon contributing to the promotion of densification is observed. The two types of powder made of Ti-silicide through heat treatment are densified only in the high temperature region of 1,000 K or more; it can be estimated that this is the effect of fine grain superplasticity. In the densification of the amorphous powder, the dependence of sintering pressure and the rate of temperature increase are shown. It is thought that the specific densification behavior identified during the phase change of the Ti-37.5 mol.%Si composition MA powder reviewed in this study is the result of the acceleration of the powder deformation by the phase change from non-equilibrium phase to equilibrium phase.

• Journal of the Korean Crystal Growth and Crystal Technology
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• v.23 no.3
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• pp.146-151
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• 2013

In this study, the effect of addition of waste glassy slag produced from recycling of spent catalyst (denoted as waste glass hereafter) on the physical properties of artificial aggregates made of coal bottom ash and dredged soil (7 : 3 by weight base) was evaluated. Especially, the bloating behavior of artificial aggregates was analyzed by performing the relation study between the apparent density, water absorption and microstructure. The apparent density of artificial aggregates increased slightly with sintering temperature at $1050{\sim}1150^{\circ}C$, but decreased above $1150^{\circ}C$ showing bloating phenomenon. The bloating behavior of artificial aggregates was decreased so the apparent density increased with amount of waste glass added. Also, the water absorption of artificial aggregates decreased with sintering temperature. Above $1200^{\circ}C$, big fissure and much liquid were formed at the surface of artificial aggregates and these phenomena could be suppressed by increasing amount of waste glass added. The artificial aggregates fabricated in this study had an apparent density of 1.1~1.6 and water absorption of 8~22 % which meet KS requirements for the artificial lightweight aggregates.

• Ceramist
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• v.23 no.2
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• pp.211-230
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• 2020

Perovskite-type oxides with the nominal composition of ABO₃ can exsolve the B-site transition metal upon the controlled reduction. In this exsolution process, the transition metal emerges from the oxide lattice and migrates to the surface at which it forms catalytically active nanoparticles. The exsolved nanoparticles can recover back to the bulk lattice under oxidation treatment. This unique regeneration character by the redox treatment provides uniformly dispersed noble metal nanoparticles. Therefore, the conventional problem of traditional impregnated metal/support, i.e., sintering during reaction, can be effectively avoided by using the exsolution phenomenon. In this regard, the catalysts using the exsolution strategy have been well studied for a wide range of applications in energy conversion and storage devices such as solid oxide fuel cells and electrolysis cells (SOFCs and SOECs) because of its high thermal and chemical stability. On the other hand, although this exsolution strategy can also be applied to gas phase reaction catalysts, it has seldomly been reviewed. Here, we thus review recent applications of the exsolution catalysts to the gas phase reactions from the aspects of experimental measurements, where various functions of the exsolved particles were utilized. We also review non-perovskite type metal oxides that might have exolution phenomenon to provide more possibilities to develop higher efficient catalysts.

• Journal of the Korean Crystal Growth and Crystal Technology
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• v.20 no.6
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• pp.301-306
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• 2010

The artificial aggregates were fabricated by using the inorganic wastes, dredged soil produced at a dredging work. The input temperature ($800{\sim}1000^{\circ}C$), output temperature ($1100{\sim}1200^{\circ}C$) and heating rate ($5{\sim}10^{\circ}C$/min) in sintering process were controlled to fabricate the aggregates with various value of density and water absorption, and their properties were analyzed as a function of those factors. The specimens sintered at the lower input temperature showed the higher density and the lower water absorption while those with higher input temperature had many pores inside of the aggregates, lower density and higher water absorption. Also increasing the input temperature accelerated the black core phenomenon in the aggregates. The bloating phenomena which the gigantic pores were generated inside the aggregates were improved as increasing the output temperature, but its effect was lower than that of input temperature. It could be realized that the bloating tendency was improved from the results that the density was increased and water absorption was decreased with increasing heating rate from 5 to $10^{\circ}C$/min. It was found that the artificial aggregates of light or heavy weight with various value of density and water absorption could be fabricated by using dredged soils naturally involving gas and fluxing components by controlling the sintering conditions.

• Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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• 1993.11a
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• pp.144-148
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• 1993

This paper is a study on electromagnetic wave absorption properties for the composition ratio of Ni-Zn-Fe$_2$O$_4$. Li-Zn-Fe$_2$O$_4$was composed of Fe$_2$O$_3$ 48∼51mo1%, LiO 18 ∼22mo1%, ZnO 34∼27mo1%. and sintering was carried out at 1200$^{\circ}C$. Through the experiments, the resonance phenomenon occured at low frequence range for high permeability, and vice versa. Specialy, In the case of Fe$_2$O$_3$49mol%, NiO 20mo1%, ZnO 3lmol% ,and the matching thickness was 10mm , the absorbing bandwith was 0.35 ∼0.95GHz. Also, In the case of Fe$_2$O$_3$51mo1%. NiO 22mo1%, ZnO 27mol%, we could get the absorbing bandwith of 0.45∼1.2GHz when the matching thickness was 6mm. Therefore. it is proved that electromagnetic wave absorbers with the above bandwidth range can be fabricated successful1y.

• Journal of the Korean Ceramic Society
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• v.27 no.3
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• pp.412-422
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• 1990

Porous SiC ceramics were proposed to be promising materials for high-temperature thermoelectric energy conversion. Throughthe thermoelectric property measurements and microstructure observations on the porous alpha SiC and the mixture of $\alpha$-and $\beta$-SiC, it was experimentally clarified that elimination of stacking faults and twin boundaries by grain growth is effective to increase the seebeck coefficient and increasing content of $\alpha$-SiC gives rise to lower electrical conductivity. Furthermore, the effects of additives on the thermoelectric properties of 6H-SiC ceramics were also studied. The electrical conductivity and the seebeck coefficient were measured at 35$0^{\circ}C$ to 105$0^{\circ}C$ in argon atmospehre. The thermoelectric conversion efficiency of $\alpha$-SiC ceramics was lower than that of $\beta$-SiC ceramics. The phase homogeneity would be needed to improve the seebeck coefficient and electrical conductivity decreased with increasing the content of $\alpha$-phase. In the case of B addition, XRD analysis showed that the phase transformation did not occur during sintering. On the other hand, AlN addiiton enhanced the reverse phase transformation from 6H-SiC to 4H-SiC, and this phenomenon had a great effect upon the electrical conductivity.