• Bulletin of the Korean Chemical Society
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• v.27 no.5
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• pp.679-686
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• 2006

The positions of $PbI _2$ molecule synthesized into the molecular-dimensioned cavities of $\mid K_6 (Pb _4I_2)(PbI_2) _{0.67}-(H_2O)_2\mid [Si _{12}Al _{12}O _{48}]$-LTA have been determined. A single crystal of $\mid Pb _6\mid [Si _{12}Al _{12}O _{48}]$-LTA, prepared by the dynamic ion-exchange of $\mid Na _{12}\mid [Si _{12}Al _{12}O _{48}]$-LTA with aqueous 0.05 M $Pb _(NO _3)_2$ and washed with deionized water, was placed in a stream of flowing aqueous 0.05 M KI at 294 K for three days. The resulting crystal structure of the product $( \mid K_6 (Pb _4I_2)(PbI_2) _{0.67}(H_2O)_2\mid [Si _{12}Al _{12}O _{48}]$-LTA, a = 12.353(1) $\AA$) was determined at 294 K by single-crystal X-ray diffraction in the space group Pm3 m. It was refined with all measured reflections to the final error index $R_1$ = 0.062 for 623 reflections which $F_o$ > 4$\sigma$($F_o$). 4.67 $Pb ^{2+}$ and six $K^+$ ions per unit cell are found at three crystallographically distinct positions: 3.67 $Pb ^{2+}$ and three $K^+$ ions on the 3-fold axes opposite six-rings in the large cavity, three $K^+$ ions off the plane of the eight-rings, and the remaining one $Pb ^{2+}$ ion lies opposite four-ring in the large cavity. 0.67 $Pb ^{2+}$ ions and 1.34 $I^-$ ions per unit cell are found in the sodalite units, indicating the formation of a $PbI _2$ molecule in 67% of the sodalite units. Each $PbI _2$ (Pb-I = 3.392(7) $\AA$) is held in place by the coordination of its one $Pb ^{2+}$ ion to the zeolite framework (a $Pb ^{2+}$ cation is 0.74 $\AA$ from a six-ring oxygens) and by the coordination of its two $I^-$ ions to $K^+$ ions through six-rings (I-K = 3.63(4) $\AA$). Two additional $I^-$ ions per unit cell are found opposite a four-ring in the large cavity and form $Pb _2K_2I^{5+}$ and $Pb _2K_2I^{3+}$ moieties, respectively, and two water molecules per unit cell are also found on the 3-fold axes in the large cavity.

• 제어로봇시스템학회:학술대회논문집
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• 2003.10a
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• pp.1547-1552
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• 2003

In this paper, we present a planar single-crystalline silicon x-axis micro-gyroscope fabricated with a perfectly aligned vertical actuation combs on one silicon wafer, using the extended SBM technology. The fabricated x-axis micro-gyroscope has the resolution of 0.1 deg/sec, the bandwidth of 100 Hz. These research results allow integrating 6 axes inertial measurement (3 accelerations and 3 angular rates) on the same silicon substrate using the same process for the first time.

• Journal of the Korean Magnetics Society
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• v.4 no.2
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• pp.184-187
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• 1994

Nuclear magnetic resonance of $^{133}Cs$ in a $CsMnCl_{3}$ single crystal grown by the Czochralski method has been investigated by employing a Bruker FT NMR spectrometer. The $^{133}Cs$ resonance of two different groups were recorded. Various transitions belonging to two cesium spectra of a different intensity ratio are analyzed. The quadrupole coupling constant of Cs(I) is $0.15{\pm}0.01$ MHz, and that of Cs(II) is $0.21{\pm}0.01$ MHz. The anisotropy parameter is zero for both. The principal axes of the EFG tensors for these two sites are found to be the same. The Z axis, conventionally the largest component of the EFG tensor, is parallel to the crystallographic c-axis.

• Journal of Power Electronics
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• v.19 no.1
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• pp.89-98
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• 2019

This paper analyzes the input side performance of a conventional three-phase to single-phase matrix converter (3-1MC). It also presents the input-side waveform quality under this topology. The suppression of low-frequency input current harmonics is studied using the 3-1MC plus capacitance compensation unit. The constraint between the modulation function of the output and compensation sides is analyzed, and the relations among the voltage utilization ratio and the output compensation capacitance, filter capacitors and other system parameters are deduced. For a 3-1MC without large-capacity energy storage, the system performance is susceptible to input voltage imbalance. This paper decouples the inner current of the 3-1MC using a Lyapunov function in the input positive and negative sequence bi-coordinate axes. Meanwhile, the outer loop adopts a voltage-weighted synthesis of the output and compensation sides as a cascade of control objects. Experiments show that this strategy suppresses the low-frequency input current harmonics caused by input voltage imbalance, and ensures that the system maintains good static and dynamic performances under input-unbalanced conditions. At the same time, the parameter selection and debugging methods are simple.

• Bulletin of the Korean Chemical Society
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• v.10 no.3
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• pp.230-234
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• 1989

The crystal structure of $Ag^+$-exchanged zeolite A vacuum-dehydrated at $370^{\circ}C$ and then treated with carbon monoxide at $$23^{\circ}C$ has been determined by single crystal x-ray diffraction methods in the cubic space group Pm3m at $23^(1){\circ}C$ ; a = 12.116 (2)${\AA}$. The structure was refined to the final error indices $R_1\;=\;0.061\;and\;R_2$(weighted) = 0.068 using 349 independent reflections for which I > 3${\sigma}(I).\;3.6\;Ag_+-CO$ complexes, where -CO may represent -CHO or -$CH_2OH$, were found in each large cavity. By coordination to silver atoms followed by reaction with $Ag^{\circ}and\;H^+$ within the zeolite, carbon monoxide has been partially reduced. In about 28% of the sodalite units, a $Ag_6(Ag^+)_2$ cluster may be present. In about 37% of the sodalite units, three $Ag^+$ ions are found on threefold axes where they may be bridged by three water molecules. The remaining 35% of the sodalite units are empty of silver species. Two $Ag^+$ ions per unit cell are associated with 8-ring oxygens. The remaining ca $$3Ag^+$ ions per unit cell have been reduced during the synthesis and have migrated to form small silver crystallities on the surface of the zeolite single crystal.

• Bulletin of the Korean Chemical Society
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• v.14 no.2
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• pp.258-262
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• 1993

Two single crystals of fully dehydrated $Rb^+$ -exchanged zeolite A have been prepared by the reduction of all $Ca^{2+}$ ions in dehydrated $Ca_6$-A by rubidium vapor. Their structures were determined by single crystal X-ray diffraction methods in the cubic space group Pm3m (a=12.160(2) $^{\AA}$ and 12.166(2) $^{\AA}$) at 22(1)$^{\circ}$C. In these structures, 12.4(2) to 13.3(2) Rb species are found per unit cell, more than 12 Rb$^+$ ions needed to balance the anionic charge of the zeolite framework, indicating that the sorption $Rb^0$ has occurred. In each structure, three $Rb^+$ ions per unit cell are located at the centers of the 8-rings. Six to eight $Rb^+$ ions are found opposite the 6-rings on threefold axes, and three $Rb^+$ ions are found in a sodalite unit. About 0.5 $Rb^+$ ion lies opposite a 4-ring. The structural analysis indicates the presence of a triangular rubidium cluster in the sodalite cavities. The triangular rubidium clusters may be stabilized by the coordination to two and/or three rubidium ions in the large cavity. Therefore, this cluster may be viewed as $(Rb_5)^{4+}$ and/or $(Rb_6)^{4+}$.

• 제어로봇시스템학회:학술대회논문집
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• 2003.10a
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• pp.865-870
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• 2003

A motion controller has been used variously in industry such as semiconductor manufacture equipment, industrial robot, assembly/conveyor line applications and CNC equipment. There are several types of controller in motion control. One of these is a PC-based motion controller such as PCI or ISA, and another is stand-alone motion controller. The PC bus-based motion controller is popular because of improving bus architectures and GUI (Graphic User Interface) that offer convenience of use to user. There are some problems in this. The PC bus-based solution allows for only one of the form factors, so it has a poor flexibility. The overall system package size is bigger than other motion control system. And also, additional axes of control require additional slot, however the number of slots is limited. Furthermore, unwieldy and many wirings come to connect plants or I/O. The stand-alone motion controller has also this limit of axes of control and wiring problems. To resolve these problems, controller must have capability of operating as stand-alone devices that resides outside the computer and it needs network capability to communicate to each motion device. In this paper, a network-based stand-alone motion system is proposed. This system integrates PC and motion controller into one stand-alone motion system, and uses CAN (Controller Area Network) as network protocol. Single board computer that is type of 3.5" FDD form factor is used to reduce the system size and cost. It works with Windows XP Embedded as operating system. This motion system operates by itself or serves as master motion controller that communicates to slave motion controller. The Slave motion controllers can easily connect to master motion system through CAN-network.

• Earthquakes and Structures
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• v.12 no.1
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• pp.1-12
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• 2017

Historical earthquakes have shown that successive seismic events may occur in regions of high seismicity. Such a sequence of earthquakes has the potential to increase the damage level of the structures, since any rehabilitation between the successive ground motions is practically impossible due to lack of time. Few studies about this issue can be found in literature, most of which focused their attention on the seismic response of SDOF systems or planar frame structures. The aim of the present study is to examine the impact of seismic sequences on the damage level of 3D multistorey R/C buildings with various structural systems. For the purposes of the above investigation a comprehensive assessment is conducted using three double-symmetric and three asymmetric in plan medium-rise R/C buildings, which are designed on the basis of the current seismic codes. The buildings are analyzed by nonlinear time response analysis using 80 bidirectional seismic sequences. In order to account for the variable orientation of the seismic motion, the two horizontal accelerograms of each earthquake record are applied along horizontal orthogonal axes forming 12 different angles with the structural axes. The assessment of the results revealed that successive ground motions can lead to significant increase of the structural damage compared to the damage caused by the corresponding single seismic events. Furthermore, the incident angle can radically alter the successive earthquake phenomenon depending on the special characteristics of the structure, the number of the sequential earthquakes, as well as the distance of the record from the fault.

• Korean Journal of Optics and Photonics
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• v.7 no.4
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• pp.419-427
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• 1996

Thermally-stabilized fiber-optic current sensors are proposed and demonstrated. The sensor head is made of two coil formers combined perpendicularly. In this sensor head, bending-induced birefringences can be reduced to the level much smaller than those of the single former type because the eigen-axes of the two perpendicular coil formers are made orthogonal to each other. Moreover, thermal variation of the birefringence is also expected to be minimized by the orthogonality of the two polarization eigen-axes. We changed the temperature slowly in the range of 20~45$^{\circ}C$ during 100 minutes. The overall linearity of the sensor is better than 1.2% in the range of 0~1000A. The long-term fluctuation of the sensor is less than 1% when measured for 3 hours at 500A and room temperature. Two orthogonally-polarized laser diodes are combined together to make the incident beam unpolarized. In the signal processing, the signals are separated by two parts and normalized respectively, which minimize the efects of optical fluctuations coming from sources, connectors, etc.

• Steel and Composite Structures
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• v.6 no.1
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• pp.71-85
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• 2006

This paper presents the results of a series of tests carried out on cold-formed steel rectangular hollow and concrete infilled beam to column connections and frames. A stub column was chosen such that overall buckling does not influence the connection behaviour. The beam chosen was a short-span cantilever with a concentrated load applied at the free end. The beam was connected to the columns along the strong and weak axes of columns and these connections were tested to failure. Twelve experiments were conducted on cold-formed steel direct welded tubular beam to column connections and twelve experiments on connections with concrete infilled column subjected to monotonic loading. In all the experiments conducted, the stiffness of the connection, the ductility characteristics and the moment rotation behaviour were studied. The dominant mode of failure in hollow section connections was chord face yielding and not weld failure. Provision of concrete infill increases the stiffness and the ultimate moment carrying capacity substantially, irrespective of the axis of loading of the column. Weld failure and bearing failure due to transverse compression occurred in connections with concrete infilled columns. Six single-bay two storied frames both with and without concrete infill, and columns loaded along the major and minor axes were tested to failure. Concentrated load was applied at the midspan of first floor beam. The change in behaviour of the frame due to provision of infill in the column and in the entire frame was compared with hollow frames. Failure of the weld at the junction of the beam occurred for frames with infilled columns. Design expressions are suggested for the yielding of the column face in hollow sections and bearing failure in infilled columns which closely predicted the experimental failure loads.