• 제목/요약/키워드: single walled-carbon nanotube

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Electrochemical Immunosensor Using the Modification of an Amine-functionalized Indium Tin Oxide Electrode with Carboxylated Single-walled Carbon Nanotubes

  • Aziz, Md.Abdul;Yang, Hae-Sik
    • Bulletin of the Korean Chemical Society
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    • v.28 no.7
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    • pp.1171-1174
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    • 2007
  • We have developed an electrochemical immunosensor that combines the electrocatalytic property of carbon nanotube and the low background current of indium tin oxide (ITO) electrode. A partial monolayer of carboxylated single-walled carbon nanotube (CCNT) is covalently formed on an ITO electrode modified with amine-terminated phosphonic acid. Nonspecifically adsorbed avidin on the hydrophobic sidewalls of CCNT is used to immobilize biotinylated antibody and to reduce the nonspecific binding to CCNT. The biotinylated antimouse IgG bound on avidin and the antimouse IgG conjugated with alkaline phosphatase (ALP) sandwiches a target mouse IgG. ALP catalyzes the conversion of p-aminophenyl phosphate monohydrate into p-aminophenol, which is electrocatalytically oxidized to p-quinone imine on CCNT surface. Moderate electrocatalytic electrode obtained with the combination of CCNT and ITO allows low detection limit (0.1 ng/ mL).

Separation of Single-Walled Carbon Nanotubes by Length and Diameter (단일벽 탄소 나노튜브의 길이와 지름에 따른 분류)

  • Oh Young-Seok;Lee Dock-Jin;Chang Yyun-Seok;Choi Jae-Boong;Kim Young-Jin;Baik Seung-Hyun
    • Journal of the Korean Society for Precision Engineering
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    • v.23 no.3 s.180
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    • pp.171-178
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    • 2006
  • The sonication mettled is widely used with surfactants to suspend individual single-walled carbon nanotubes in solution, and it is well known that sonication-induced tube cutting occurs. Recently, it is found out that ultrasonicated nanotubes yield simultaneous separation by tube length and diameter. Nanotubes that have been cut shortest possess the greatest enrichments of large-diameter species. In this study, single-walled carbon nanotubes are cut using a ball milling method. Similar fracture behavior is observed fur the ball milled nanotubes: i.e., large diameter tubes are cut shorter. The ability to separate carbon nanotubes by diameter and length will contribute to tile development of nanotube-based applications.

Thermal Conductivity of Single-Walled Carbon Nanotube by Using Memory Function (메모리함수에 의한 단일 벽 탄소 나노튜브의 열전도도)

  • Park, Jung-Il;Cheong, Hai-Du
    • Journal of the Korean Vacuum Society
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    • v.22 no.3
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    • pp.144-149
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    • 2013
  • We use Memory function to examine the thermal conductivity as a function of the temperature in single-walled carbon nanotube (SWNT). We determine the Umklapp, normal and SWNT-substrate phonon scattering rate from the computed inverse spin relaxation time. Thermal conductivity increased as the diameter increased when we assumed that the zigzag (10,0) transition was a more dominant phonon scattering than the (9,0) transition.

Dispersion of Highly Pure Single-Walled Carbon Nanotube in Aqueous Solution of Various Surfactants (다양한 계면활성제를 이용한 고순도 단일벽 탄소나노튜브의 수계 분산)

  • Goak, Jeung-Choon;Kim, Myoung-Su;Lee, Nae-Sung
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2008.06a
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    • pp.153-153
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    • 2008
  • Practical application of single-walled carbon nanotubes (SWCNTs) qualified as a promising material has been limited by either poor dispersion or their insolubility in aqueous or organic media due to formation of bundling by relatively high surface energy. Thus, major attention to overcome this issue has been paid at surface modification of CNTs by functionalization, but this introduces defects to the sidewall of CNTs, consequently perturbing the inherent electronic and optical properties. Therefore, using surfactants is a general approach to disperse SWCNTs with lower damages by which bundled nanotubes could be dispersed up to the level of individuals or small bundles. Here, we have investigated various surfactants for their efficiency in dissolving purified SWCNTs produced by arc discharge in deionized water. To compare the surfactants respectively, we have determined the least amount of each surfactant to suspend the nanotubes under optimized experimental conditions(CNT amount, sonication power, and centrifugation speed, etc.) set on the basis of the most common surfactant (sodium dodecyl sulfate, SDS) and discussed the qualitative and quantitative characterization of SWCNT dispersions by UV-Vis absorption spectroscopy. Quantitative aspect about nanotube dispersion was that in particular N-methyl-2-pyrrolidone (NMP) and sodium dodecylbenzene sulfonate (NaDDBS) were found to be effective in dispersing individual tubes.

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Ultrasonic waves in a single walled armchair carbon nanotube resting on nonlinear foundation subjected to thermal and in plane magnetic fields

  • Selvamani, Rajendran;Jayan, M. Mahaveer Sree;Ebrahimi, Farzad
    • Coupled systems mechanics
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    • v.10 no.1
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    • pp.39-60
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    • 2021
  • The present paper is concerned with the study of nonlinear ultrasonic waves in a magneto thermo (MT) elastic armchair single-walled carbon nanotube (ASWCNT) resting on polymer matrix. The analytical formulation is developed based on Eringen's nonlocal elasticity theory to account small scale effect. After developing the formal solution of the mathematical model consisting of partial differential equations, the frequency equations have been analyzed numerically by using the nonlinear foundations supported by Winkler-Pasternak model. The solution is obtained by ultrasonic wave dispersion relations. Parametric work is carried out to scrutinize the influence of the non local scaling, magneto-mechanical loadings, foundation parameters, various boundary condition and length on the dimensionless frequency of nanotube. It is noticed that the boundary conditions, nonlocal parameter, and tube geometrical parameters have significant effects on dimensionless frequency of nano tubes. The results presented in this study can provide mechanism for the study and design of the nano devices like component of nano oscillators, micro wave absorbing, nano-electron technology and nano-electro- magneto-mechanical systems (NEMMS) that make use of the wave propagation properties of armchair single-walled carbon nanotubes embedded on polymer matrix.

Solid-State Laser Mode-Locking Near 1.25 μm Employing a Carbon Nanotube Saturable Absorber Mirror

  • Cho, Won-Bae;Choi, Sun-Young;Kim, Jun-Wan;Yeom, Dong-Il;Kim, Ki-Hong;Rotermund, Fabian;Lim, Han-Jo
    • Journal of the Optical Society of Korea
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    • v.15 no.1
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    • pp.56-60
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    • 2011
  • We demonstrate passive mode-locking of a Cr:forsterite laser with a single-walled carbon nanotube saturable absorber mirror (SWCNT-SAM). Without compensation of intra-cavity dispersion, the self-mode-locked laser generates 11.7 ps pulses at a repetition rate of 86 MHz. The dispersion-compensated laser yields ultrashort pulses as short as 80 fs near $1.25\;{\mu}m$ at 78 MHz with average output powers up to 295 mW, representing the highest power ever reported for mode-locked solid-state lasers based on saturable absorption of SWCNTs in this spectral region.

Carbon Nanotube DNA Bioconjugates as Nano-Bio Markers (탄소 나노튜브와 DNA와의 결합을 통한 나노-바이오 마커 응용)

  • Hwang Eung-Soo;Chengfan Cao;Hong Sang-Hyun;Jung Hye-Jin;Cha Chang-Yong;Choi Jae-Boong;Kim Young-Jin;Baik Seung-Hyun
    • Proceedings of the Korean Society of Precision Engineering Conference
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    • 2005.06a
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    • pp.668-671
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    • 2005
  • Carbon nanotubes exhibit strong fluorescence emissions in the region of near infrared regions where most biomolecules are transparent. Such signals are highly sensitive to environment variations as well as adsorption of specific biomolecules. In this research, single walled carbon nanotubes(SWNTs) are assembled with different types of DNAs and used to target specific types of DNAs. Dot blot investigations and corresponding raman spectroscopy observations demonstrated excellent selectivity of carbon nanotube-DNA bioconjugates. The results show possibility of using SWNT as generic nano-bio markers for precise detection of different kinds of genes.

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Thermoelectric Seebeck and Peltier effects of single walled carbon nanotube quantum dot nanodevice

  • El-Demsisy, H.A.;Asham, M.D.;Louis, D.S.;Phillips, A.H.
    • Carbon letters
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    • v.21
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    • pp.8-15
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    • 2017
  • The thermoelectric Seebeck and Peltier effects of a single walled carbon nanotube (SWCNT) quantum dot nanodevice are investigated, taking into consideration a certain value of applied tensile strain and induced ac-field with frequency in the terahertz (THz) range. This device is modeled as a SWCNT quantum dot connected to metallic leads. These two metallic leads operate as a source and a drain. In this three-terminal device, the conducting substance is the gate electrode. Another metallic gate is used to govern the electrostatics and the switching of the carbon nanotube channel. The substances at the carbon nanotube quantum dot/metal contact are controlled by the back gate. Results show that both the Seebeck and Peltier coefficients have random oscillation as a function of gate voltage in the Coulomb blockade regime for all types of SWCNT quantum dots. Also, the values of both the Seebeck and Peltier coefficients are enhanced, mainly due to the induced tensile strain. Results show that the three types of SWCNT quantum dot are good thermoelectric nanodevices for energy harvesting (Seebeck effect) and good coolers for nanoelectronic devices (Peltier effect).

Critical buckling load of chiral double-walled carbon nanotube using non-local theory elasticity

  • Chemi, Awda;Heireche, Houari;Zidour, Mohamed;Rakrak, Kaddour;Bousahla, Abdelmoumen Anis
    • Advances in nano research
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    • v.3 no.4
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    • pp.193-206
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    • 2015
  • The present paper investigate the elastic buckling of chiral double-walled carbon nanotubes (DWCNTs) under axial compression. Using the non-local elasticity theory, Timoshenko beam model has been implemented. According to the governing equations of non-local theory, the analytical solution is derived and the solution for non-local critical buckling loads is obtained. The numerical results show the influence of non-local small-scale coefficient, the vibrational mode number, the chirality of carbon nanotube and aspect ratio of the (DWCNTs) on non-local critical buckling loads of the (DWCNTs). The results indicate the dependence of non-local critical buckling loads on the chirality of single-walled carbon nanotube with increase the non-local small-scale coefficient, the vibrational mode number and aspect ratio of length to diameter.

Using modified Halpin-Tsai approach for vibrational analysis of thick functionally graded multi-walled carbon nanotube plates

  • Tahouneh, Vahid
    • Steel and Composite Structures
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    • v.23 no.6
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    • pp.657-668
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    • 2017
  • In the most of previous studies, researchers have restricted their own studies to consider the effect of single walled carbon nanotubes as a reinforcement on the vibrational behavior of structures. In the present work, free vibration characteristics of functionally graded annular plates reinforced by multi-walled carbon nanotubes resting on Pasternak foundation are presented. The response of the elastic medium is formulated by the Winkler/Pasternak model. Modified Halpin-Tsai equation was used to evaluate the Young's modulus of the multi-walled carbon nanotube/epoxy composite samples by the incorporation of an orientation as well as an exponential shape factor in the equation. The exponential shape factor modifies the Halpin-Tsai equation from expressing a straight line to a nonlinear one in the multi-walled carbon nanotubes wt% range considered. The 2-D generalized differential quadrature method as an efficient and accurate numerical tool is used to discretize the equations of motion and to implement the various boundary conditions. The effects of two-parameter elastic foundation modulus, geometrical and material parameters together with the boundary conditions on the frequency parameters of the plates are investigated. This study serves as a benchmark for assessing the validity of numerical methods or two-dimensional theories used to analysis of annular plates.