• Title/Summary/Keyword: single phase structure

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Fabrication of Three-dimensionally Ordered Macroporous Electrode Materials by Using PMMA Template (PMMA 구를 주형으로 이용한 3DOM 전극 구조체의 제조)

  • Seo Kyoung Soo;Jung Ha-Kyun;Son Yongkeun
    • Korean Journal of Materials Research
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    • v.14 no.8
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    • pp.587-594
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    • 2004
  • Three-dimensionally ordered macroporous (3DOM) structures of the $LiCoO_2$ electrode materials for Li secondary batteries were fabricated by using the close-packed arrays of PMMA spheres served as templates. In order to successfully fabricate the cathode materials with highly ordered array form, the metal citrates were applied to new precursors. The precursor/template composites were prepared by the infiltration with metal citrate precursors into the voids of template. By removing the PMMA templates, then, the inverse opal structures with the uniform pores of narrow size distribution were resulted. It was confirmed that the 3DOM $LiCoO_2$ material is to take a single phase of rocksalt (R3m) structure. In addition, 3DOM $LiNiO_2$ and $LiMn_{2}O_4$ cathode materials were fabricated using an identical preparation procedure. Also, the morphology of the 3DOM cathode materials calcined at $500^{\circ}C\;to\;700^{\circ}C$ was observed by scanning electron microscope.

A Study on the Revolution Characteristics of the Ultrasonic Motor with Windmill Type Structure (풍차형 구조를 갖는 초음파 전동기의 회전 특성에 관한 연구)

  • Kim, Jin-Su;Lee, Deok-Chul
    • The Transactions of the Korean Institute of Electrical Engineers C
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    • v.48 no.10
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    • pp.681-686
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    • 1999
  • In this study, a windmill type ultrasonic motor operated by single-phase AC electric field was fabricated, and then revolution characteristics and 3-dimensional vibration mode of the ultrasonic motor were investigated. Brass metal was pressed with umbrella-type using metal mold, then slot of 4 kind was processed at various thickness. It was found that the revolution speed of the ultrasonic motor increased with decreasing the thickness of elastic body. The revolution speed of the ultrasonic motor increased with increasing the slots of elastic body. When the characteristics was measured, applied voltage was changed from $10V_{max}\; to\; 100V_{max}$. Then, revolution was began from $30V_{max}$, if voltage was applied over $90V_{max}$ revolution speed was saturated, and not increased. The maximum revolution speed was 510[rpm] when using elastic body with 6 slots and thickness of 0.15mm. And 3-dimensional displacement mode was rotated clockwise direction.

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Structural and electrical properties of perovskite Ba(Sm1/2Nb1/2)O3-BaTiO3 ceramic

  • Nath, K. Amar;Prasad, K.
    • Advances in materials Research
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    • v.1 no.2
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    • pp.115-128
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    • 2012
  • The structural and electrical properties of $(1-x)Ba(Sm_{1/2}Nb_{1/2})O_3-xBaTiO_3$; ($0{\leq}x{\leq}1$) ceramics were prepared by conventional ceramic technique at $1375^{\circ}C$/7 h in air atmosphere. The crystal symmetry, space group and unit cell dimensions were derived from the X-ray diffraction (XRD) data using FullProf software whereas crystallite size and lattice strain were estimated from Williamson-Hall approach. XRD analysis of the compound indicated the formation of a single-phase cubic structure with the space group Pm m. Dielectric study revealed that the compound $0.75Ba(Sm_{1/2}Nb_{1/2})O_3-0.25BaTiO_3$ is having low and ${\varepsilon}^{\prime}$ and ${\varepsilon}^{{\prime}{\prime}}$ a low $T_{CC}$ (< 5%) in the working temperature range (up to+$100^{\circ}C$) which makes this composition suitable for capacitor application and may be designated as 'Stable Low-K' Class I material as per the specifications of the Electronic Industries Association. The correlated barrier hopping model was employed to successfully explain the mechanism of charge transport in the system. The ac conductivity data were used to evaluate the density of states at Fermi level, minimum hopping length and apparent activation energy of the compounds.

A Study for Automated Division of Composite Walls for Quantity Take-off in Construction Document Phase (실시설계단계에서 수량산출을 위한 복합벽체 자동분할에 관한 연구)

  • Park, Seunghwa;Kim, Heungsoo;Yoon, Dooyung
    • Korean Journal of Computational Design and Engineering
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    • v.20 no.2
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    • pp.124-132
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    • 2015
  • When Building Information Modeling (BIM) was introduced at the early stage, it was only utilized as a three-dimensional visualization tool. Nowadays, however, BIM is being studied for increasing design productivity and managing enormous information on building life cycle. One of the representative research is developing 'common prototype BIM libraries'. BIM data made of common prototype libraries should be utilized in various ways, quantity takeoff, code checking, energy analysis and so on. However, common prototype BIM libraries are not enough to estimate accurate cost. For example, composite wall libraries should be divided into several single objects, wall structure and finishes, for the quantity takeoff and construction cost calculation. In this paper, we are suggesting an automated division algorithm of composite wall and developing a system prototype for it. This study is expected to reduce extra modeling work and contribute to fast and accurate cost calculation in the construction.

A facile chemical synthesis of a novel photo catalyst: SWCNT/titania nanocomposite

  • Paul, Rima;Kumbhakar, Pathik;Mitra, Apurba K.
    • Advances in nano research
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    • v.1 no.2
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    • pp.71-82
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    • 2013
  • A simple chemical precipitation technique is reported for the synthesis of a hybrid nanostructure of single-wall carbon nanotubes (SWCNT) and titania ($TiO_2$) nanocrystals of average size 5 nm, which may be useful as a prominent photocatalytic material with improved functionality. The synthesized hybrid structure has been characterized by transmission electron microscopy (HRTEM), energy-dispersive X-ray analysis (EDAX), powder X-ray diffractometry (XRD), Fourier transform infrared spectroscopy (FTIR) and Raman spectroscopy. It is clearly revealed that nearly monodispersed titania nanocrystals (anatase phase) of average size 5 nm decorate the surfaces of SWCNT bundles. The UV-vis absorption study shows a blue shift of 16 nm in the absorbance peak position of the composite material compared to the unmodified SWCNTs. The photoluminescence study shows a violet-blue emission in the range of 325-500 nm with a peak emission at 400 nm. The low temperature electrical transport property of the synthesized nanomaterial has been studied between 77-300 K. The DC conductivity shows semiconductor-like characteristics with conductivity increasing sharply with temperature in the range of 175-300 K. Such nanocomposites may find wide applications as improved photocatalyst due to transfer of photo-ejected electrons from $TiO_2$ to SWCNT, thus reducing recombination, with the SWCNT scaffold providing a firm and better positioning of the catalytic material.

Proposal and Analysis of Distributed Reflector-Laser Diode Integrated with an Electroabsorption Modulator

  • Kwon, Oh Kee;Beak, Yong Soon;Chung, Yun C.;Park, Hyung-Moo
    • ETRI Journal
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    • v.35 no.3
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    • pp.459-468
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    • 2013
  • A novel integrated laser, that is, a distributed reflector laser diode integrated with an electroabsorption modulator, is proposed to improve the output efficiency, single-mode stability, and chirp. The proposed laser can be realized using the selective metalorganic vapor phase epitaxy technique (that is, control of the width of the insulating mask), and its fabrication process is almost the same as the conventional electroabsorption modulated laser (EML) process except for the asymmetric coupling coefficient structure along the cavity. For our analysis, an accurate time-domain transfer-matrix-based laser model is developed. Based on this model, we perform steady-state and large-signal analyses. The performances of the proposed laser, such as the output power, extinction ratio, and chirp, are compared with those of the EML. Under 10-Gbps NRZ modulation, we can obtain a 30% higher output power and about 50% lower chirp than the conventional EML. In particular, the simulation results show that the chirp provided by the proposed laser can appear to have a longer wavelength side at the leading edge of the pulse and a shorter wavelength side at the falling edge.

Kinesiology Based Human-like Walking Pattern Design for a Bipedal Robot (인체운동학에 기반한 이족로봇의 인간형 걸음새 설계)

  • Park, Jin-Hee;Kwon, Sang-Joo
    • Journal of Institute of Control, Robotics and Systems
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    • v.17 no.7
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    • pp.659-667
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    • 2011
  • The study of bipedal robot is towards similar shape and function with human. In this paper, we propose a human-like walking pattern compatible to the flexible foot with toe and heel structure. The new walking pattern for a bipedal robot consists of ZMP, center of mass (CoM), and ankle trajectory and is drawn by considering human kinesiology. First, the ZMP trajectory moves forward without stopping at a point even in the single support phase. The corresponding CoM trajectory to the ZMP one is derived by solving differential equations. As well, a CoM trajectory for the vertical axis is added by following the idea of human motion. The ankle trajectory closely mimics the rotational motion of human ankles during taking off and landing on the ground. The advantages of the proposed walking pattern are demonstrated by showing improved stability, decreased ankle torque, and the longer step length capability. Specifically, it is interesting to know that the vertical CoM motion is able to compensate for the initial transient response.

Cadmium Sulphide Nanorods: Synthesis, Characterization and their Photocatalytic Activity

  • Giribabu, Krishnamoorthy;Suresh, Ranganathan;Manigandan, Ramadoss;Vijayaraj, Arunachalam;Prabu, Raju;Narayanan, Vengidusamy
    • Bulletin of the Korean Chemical Society
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    • v.33 no.9
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    • pp.2910-2916
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    • 2012
  • Cadmium sulphide (CdS) nanorods were prepared by a single precursor thermal decomposition (SPTD) method. The formation of CdS nanorods and their structure, morphology and elemental composition were studied by means of FT-IR, XRD, FE-SEM, HR-TEM and EDAX analysis. Photoluminescence (PL) and lifetime measurements were recorded to study the luminescence properties of the material. The PL spectrum of the CdS nanorods showed one broad peak and four shoulders and the cause for this emission was discussed. The PL emissions from the band edge and deep trap state of the CdS nanorods were studied by lifetime measurements. Further, the synthesized CdS nanorods showed an increase in efficiency of photocatalytic degradation of methylene blue (MB) and rhodamine B (RhB). The increase in the photocatalytic activity was attributed to the mixed phase of the CdS nanorods.

Development, implementation and verification of a user configurable platform for real-time hybrid simulation

  • Ashasi-Sorkhabi, Ali;Mercan, Oya
    • Smart Structures and Systems
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    • v.14 no.6
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    • pp.1151-1172
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    • 2014
  • This paper presents a user programmable computational/control platform developed to conduct real-time hybrid simulation (RTHS). The architecture of this platform is based on the integration of a real-time controller and a field programmable gate array (FPGA).This not only enables the user to apply user-defined control laws to control the experimental substructures, but also provides ample computational resources to run the integration algorithm and analytical substructure state determination in real-time. In this platform the need for SCRAMNet as the communication device between real-time and servo-control workstations has been eliminated which was a critical component in several former RTHS platforms. The accuracy of the servo-hydraulic actuator displacement control, where the control tasks get executed on the FPGA was verified using single-degree-of-freedom (SDOF) and 2 degrees-of-freedom (2DOF) experimental substructures. Finally, the functionality of the proposed system as a robust and reliable RTHS platform for performance evaluation of structural systems was validated by conducting real-time hybrid simulation of a three story nonlinear structure with SDOF and 2DOF experimental substructures. Also, tracking indicators were employed to assess the accuracy of the results.

Numerical simulation of combustor afterward sprayed in hot product stream (고온기류중에 재분사된 연소기 후류의 수치해석)

  • Kim, Tae-Han;Gwon, Hyeong-Jeong
    • Transactions of the Korean Society of Mechanical Engineers B
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    • v.21 no.7
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    • pp.841-848
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    • 1997
  • Combustion of gaseous fuel combustor in a high temperature vitiated air stream was studied with computer simulation. It is for application to afterburner of gas turbine engine which the exact mechanism is not yet clarified. As the jet velocity from fuel nozzle is very high and the geometry of combustor is three dimensional complex structure, many time and money are required to have good results. To consider this demerit, it is simplified to 2-dimensional and modified with the nozzle hole area to same area of annual status. As the thickness of annual is too thin, it is to divide with the many grids for reasonable results. Accordingly, new method which injected fuel mass, momentum and energy are added to source terms of each governing conservation equation as a source terms is introduced like as two phase analysis. Reaction rate is determined by taking into account the Arrhenius reaction based on a single step reaction mechanism. It is focused to temperature and product concentration distribution at each equivalence ratio of inlet hot product.