• Title/Summary/Keyword: single cell

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Single cell property and numerical analysis of metal-supported solid oxide fuel cell (금속지지체형 고체산화물 연료전지의 단전지 특성 및 전산해석)

  • Lee, Chang-Bo;Bae, Joong-Myeon
    • Proceedings of the KSME Conference
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    • 2007.05b
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    • pp.2222-2227
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    • 2007
  • Newly structured metal-supported solid oxide fuel cell was fabricated and characterized by impedance analysis and galvanodynamic experiment. Using a cermet adhesive, thin ceramic layer composed of anode(Ni/YSZ) and electrolyte(YSZ) was joined with STS430 metal support of which flow channel was fabricated. $La_{0.8}Sr_{0.2}Co_{0.4}Mn_{0.6}O_3$ perovskite oxide was used as cathode material. Single cell performance was increased and saturated at operating time to 300hours at 800$^{\circ}C$ because of cathode sintering effect. The sintering effect was reinvestigated by half cell test and exchange current density was measured as 0.005A/$cm^2$. Maximum power density of the cell was 0.09W/$cm^2$ at 800$^{\circ}C$. Numerical analysis was carried out to classify main factors influencing the single cell performances. Compared to experimental IV curve, simulated curve based on experimental parameters such as exchange current density was in good agreement.

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Spatial Distribution of Injected Charge Carriers in SONOS Memory Cells

  • Kim Byung-Cheul;Seob Sun-Ae
    • Proceedings of the Korean Institute of Information and Commucation Sciences Conference
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    • 2006.05a
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    • pp.894-897
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    • 2006
  • Spatial distribution of injected electrons and holes is evaluated by using single-junction charge pumping technique in SONOS(Poly-silicon/Oxide/Nitride/Oxide/Silicon) memory cells. Injected electron are limited to length of ONO(Oxide/Nitride/oxide) region in locally ONO stacked cell, while are spread widely along with channel in fully ONO stacked cell. Hot-holes are trapped into the oxide as well as the ONO stack in locally ONO stacked cell.

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Transflective liquid crystal display with single cell gap and simple structure

  • Kim, Mi-Young;Lim, Young-Jin;Jeong, Eun;Chin, Mi-Hyung;Kim, Jin-Ho;Srivastava, Anoop Kumar;Lee, Seung-Hee
    • 한국정보디스플레이학회:학술대회논문집
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    • 2008.10a
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    • pp.340-343
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    • 2008
  • This work reports the simple fabrication of the single cell gap transflective liquid crystal display (LCD) using wire grid polarizer. The nano sized wire grid polarizer was patterned on common electrode itself, on the reflective part of FFS (Fringe field switching) mode whereas the common electrode was unpatterned at transmissive part. However, this structure didn't show single gamma curve, so we further improved the device by patterning the common electrode at transmissive part. As a result, V-T curve of proposed structure shows single gamma curve. Such a device structure is free from in-cell retarder, compensation film and reflector and furthermore it is very thin and easy to fabricate.

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Fabrication of Microbe-Attached SWNT Film for Biosensor Applications and Organophosphorus Compounds Detection (바이오센서 적용을 위한 미생물이 고정된 부양형 탄소나노튜브 필름 제작과 유기인 화합물 검출)

  • Kim, Intae;An, Taechang;Kim, Chang Sup;Cha, Hyung Joon;Kim, Jin Ho;Lim, Soo Taek;Lim, Geunbae
    • Journal of Sensor Science and Technology
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    • v.23 no.1
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    • pp.35-41
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    • 2014
  • Microbes have been used extensively in various fields of researches and industries but has not been used widely for microfluidic biosensor applications because it is difficult to immobilize properly to a small space. Therefore, we developed a microbial immobilization method for microfluidic devices using single-walled nanotubes and dielectrophoretic force. Single-walled nanotubes and Escherichia coli were aligned between two cantilever electrodes by a positive dielectrophoretic force resulting in a film of single-walled nanotubes with attached Escherichia coli. The optimal condition of film formation without a cell lysis was investigated. Diameter of single-walled nanotubes and electric field (intensity and duration of application) had an effect on the cell viability. On the other hand, the cell concentration of the suspension did not affect the cell viability. Paraoxon was detected using single-walled nanotubes film with attached Escherichia coli that expressed organophosphorus hydrolase. This film which is suspended from the substrate showed faster response time than sensors that are not suspended from the substrate.

Fabrication of Anode-Supported SOFC Single Cells via Tape-Casting of Thin Tapes and Co-Firing (박막 테이프캐스팅과 동시소성에 의한 연료극 지지형 SOFC 단전지 제조)

  • Moon, Hwan;Kim, Sun-Dong;Hyun, Sang-Hoon;Kim, Ho-Sung
    • Journal of the Korean Ceramic Society
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    • v.43 no.12 s.295
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    • pp.788-797
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    • 2006
  • An anode-supported SOFC single cell having $5{\mu}m$ thin electrolyte was fabricated cost-effectively by tape casting, laminating, and co-filing of anode (NiO-YSZ), cathode (LSM-YSZ), and electrolyte (YSZ) components. The optimal slurry compositions of the green tapes for SOFC components were determined by an analysis of the mean diameter, the slurry viscosity, the tensile strength/strain of the green tapes, and their green microstructures. The single cells with a dense electrolyte and porous electrodes could be co-fired successfully at $1325\sim1350^{\circ}C$ by controlling the contents of pore former and the ratio of coarse YSZ and fine YSZ in the anode and the cathode. The single cell co-fired at $1350^{\circ}C$ showed $100.2mWcm^{-2}$ of maximum power density at $800^{\circ}C$ but it was impossible to apply it to operate at low temperature because of low performance and high ASR, which were attributed to formation of the secondary phases in the cathode and the interface between the electrolyte and the cathode.

Detection of Unbalanced Voltage Cells in Series-connected Lithium-ion Batteries Using Single-frequency Electrochemical Impedance Spectroscopy

  • Togasaki, Norihiro;Yokoshima, Tokihiko;Oguma, Yasumasa;Osaka, Tetsuya
    • Journal of Electrochemical Science and Technology
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    • v.12 no.4
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    • pp.415-423
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    • 2021
  • For a battery module where single cells are connected in series, the single cells should each have a similar state of charge (SOC) to prevent them from being exposed to an overcharge or over-discharge during charge-discharge cycling. To detect the existence of unbalanced SOC cells in a battery module, we propose a simple measurement method using a single-frequency response of electrochemical impedance spectroscopy (EIS). For a commercially available graphite/nickel-cobalt-aluminum-oxide lithium-ion cell, the cell impedance increases significantly below SOC20%, while the impedance in the medium SOC region (SOC20%-SOC80%) remains low with only minor changes. This impedance behavior is mostly due to the elementary processes of cathode reactions in the cell. Among the impedance values (Z, Z', Z"), the imaginary component of Z" regarding cathode reactions changes heavily as a function of SOC, in particular, when the EIS measurement is performed around 0.1 Hz. Thanks to the significant difference in the time constant of cathode reactions between ≤SOC10% and ≥SOC20%, a single-frequency EIS measurement enlarges the difference in impedance between balanced and unbalanced cells in the module and facilitates an ~80% improvement in the detection signal compared to results with conventional EIS measurements.

VARIOUS NIR SAMPLE PRESENTATIONS FOR AGRICULTURAL PRODUCTS SUCH AS INTACT FRUITS, SINGLE GRAINS, VEGETABLE JUICE, MILK AND THE OTHERS

  • Kawano, Sumio
    • Proceedings of the Korean Society of Near Infrared Spectroscopy Conference
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    • 2001.06a
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    • pp.1021-1021
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    • 2001
  • Sample presentation, which means how to set samples to an NIR instrument, is very important in Near Infrared (NIR) Spectroscopy. When sample presentation is not suitable for the samples that you use, very good spectra can not be obtained even if you use a sophisticated NIR instrument. In my presentation, various NIR sample presentations for agricultural products such as intact fruits, single grains, vegetable juice and the others will be explained. In case of peaches with thin peel, the fiber optics of Interactance can be used. However, the fiber optics are not suitable for oranges with relatively thick peel. In this case, transmittance method is useful. As for a small sample such as single grains, a specially designed cell is needed. The cell in transmittance mode has been developed and then applied to single kernels of rice and soybean. In this case we also used the fiber optics. As regards liquid type of sample, a cuvette cell made of quartz in transmittance mode is popular. However, it is time-consuming to wash and dry it. In order to compensate this disadvantage the sample presentation using normal test tubes as sample cells have been developed and applied to milk, rumen juice and urine of a milking cow. An individual test tube can be used for each sample if you use the calibration equation with sample cell compensation. The test tube cell has also been applied to spinach juice for determination of undesirable constituents. It is concluded that sample presentation is most important for NIR Spectroscopy.

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Fabrication and Characterization of Cu-Ni- YSZ SOFC Anodes for Direct Utilization of Methane via Cu pulse plating (펄스 도금법에 의한 메탄연료 직접 사용을 위한 Cu-Ni-YSZ SOFC 연료극 제조 및 특성평가)

  • Park, Eon-Woo;Moon, Hwan;Lee, Jong-Jin;Hyun, Sang-Hoon
    • Journal of the Korean Ceramic Society
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    • v.45 no.12
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    • pp.807-814
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    • 2008
  • The Cu-Ni-YSZ cermet anodes for direct use of methane in solid oxide fuel cells have been fabricated by electroplating Cu into the porous Ni-YSZ cermet anode. The uniform distribution of Cu in the Ni-YSZ anode could be obtained via pulse electroplating in the aqueous solution mixture of $CuSO_4{\cdot}5H_{2}O$ and ${H_2}{SO_4}$ for 30 min with 0.05 A of average applied current. The power density ($0.17\;Wcm^{-2}$) of a single cell with a Cu-Ni-YSZ anode was shown to be slightly lower in methane at $700^{\circ}C$, compared with the power density ($0.28\;Wcm^{-2}$) of a single cell with a Ni-YSZ anode. However, the performance of the Ni-YSZ anode-supported single cell was abruptly degraded over 21 h because of carbon deposition, whereas the Cu-Ni-YSZ anode-supported single cell showed the enhanced durability upto 52 h.

Torsion strength of single-box multi-cell concrete box girder subjected to combined action of shear and torsion

  • Wang, Qian;Qiu, Wenliang;Zhang, Zhe
    • Structural Engineering and Mechanics
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    • v.55 no.5
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    • pp.953-964
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    • 2015
  • A model has been proposed that can predict the ultimate torsional strength of single-box multi-cell reinforced concrete box girder under combined loading of bending, shear and torsion. Compared with the single-cell box girder, this model takes the influence of inner webs on the distribution of shear flow into account. According to the softening truss theory and thin walled tube theory, a failure criterion is presented and a ultimate torsional strength calculating procedure is established for single-box multi-cell reinforced concrete box girder under combined actions, which considers the effect of tensile stress among the concrete cracks, Mohr stress compatibility and the softened constitutive law of concrete. In this paper the computer program is also compiled to speed up the calculation. The model has been validated by comparing the predicted and experimental members loaded under torsion combined with different ratios of bending and shear. The theoretical torsional strength was in good agreement with the experimental results.

THD Analysis of Output Voltage According to PWM Carriers in Single-Delta Bridge Cell MMC (Single-Delta Bridge Cell MMC의 전압합성을 위한 PWM 반송파 형태에 따른 출력전압의 THD 분석)

  • Jae-Myeong, Kim;Jae-Jung, Jung
    • The Transactions of the Korean Institute of Power Electronics
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    • v.27 no.6
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    • pp.526-534
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    • 2022
  • The modular multilevel converter (MMC) has been widely applied to various industrial areas because of its various advantages and structural characteristics. Therefore, many methods for synthesizing the output voltage of MMC have been studied. Among these methods, phase-shifted pulse width modulation (PSPWM) is frequently used in MMC systems because it has diverse merits, such as excellent output qualities even with a small number of cells and uniform power distribution among cells. In this study, the total harmonic distortion (THD) of the output voltage is analyzed in accordance with the number of cells in one arm of a single-delta bridge cell MMC in order to compare PSPWM methods in terms of the THD of the output voltage. The physical characteristics of the triangle and sawtooth carrier waves used for the PSPWM and the mathematical modeling of output voltage are introduced. Then, the obtained results are verified through real-time simulation of a 1 MW single-delta bridge cell MMC system.