• Bulletin of the Korean Chemical Society
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• 제14권2호
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• pp.250-255
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• 1993

A dual capillary column system is described for the simultaneous analysis of a given sample and measurement of retention index (RI) and area ratio (AR) values of each peak on two capillary columns of different polarity, DB-5 & DB-1701 from a single injection. Both capillary columns were connected to either a splitless injector or an on-column injector via a deactivated fused-silica capillary tubing of 1 m length and a 'Y' splitter. Both injection modes allowed to measure RI and AR values with high reproducibility (<0.01% RSD) and high accuracy (<10% RE), respectively with the exception that the trace and high boiling solutes required the on-column mode for the accurate quantification and AR comparison. When the dual capillary column system in on-column injection mode was applied to the blind samples containing organic acids, each acid was positively indentified by the combined computer RI library search-AR comparison.

• 대한약학회:학술대회논문집
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• 대한약학회 2003년도 Proceedings of the Convention of the Pharmaceutical Society of Korea Vol.1
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• pp.169.2-169.2
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• 2003

A method using EI-GC-MS is described for the determination of amphetamines in hair. The method is applied to simultaneous quantify amphetamines (methamphetamine, amphetamine, MDMA and MDA). Drugs were extracted in 1 ％ HCl in methanol from hair. After derivertization with TFAA, the resulting drugs were separated on HP-5MS column during a 16 min program and identified by mass spectrometry with the SIM mode(EI-GC-MS). (omitted)

• Mass Spectrometry Letters
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• 제14권3호
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• pp.104-109
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• 2023

Anabolic-androgenic steroids (AAS) are used illegally to enhance muscle development and increase strength and power. In this study, a reliable, and sensitive quantitative method was developed and validated using heptafluorobutyric acid anhydride (HFPA) derivatives for the simultaneous detection of prohibited AAS (testosterone [TS], boldenone [BD], 5α-estrane-3β,17α-diol [EAD]) using gas chromatography-tandem mass spectrometry (GC-MS/MS). For processing the samples, solid phase extraction, methanolic hydrolysis, and liquid-liquid extraction were used. For detection using mass spectrometry, the multiple reaction monitoring (MRM) mode was used with the electron ionization (EI) positive mode. The method was evaluated for selectivity, linearity, lower limit of quantification, intra- and inter-day precision, accuracy, and stability. The results showed that the method was accurate and reproducible for the quantitation of the three steroids. The developed method was finally applied to the analysis of a suspect gelding urine sample received from the Asian Quality Assurance Program (AQAP).

• ETRI Journal
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• 제32권2호
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• pp.230-240
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• 2010

The IEEE802.16j standard uses non-transparent relay stations to extend coverage. There are two types of non-transparent relay modes, that is, the time-division transmit and receive (TTR) relay mode which can operate with one of two types of frame structures, a single-frame and multiframe structure, and the simultaneous transmit and receive (STR) relay mode. In this paper, we analyze the relay performance of TTR and STR relay modes in IEEE 802.16j MMR system. We also propose a fair resource allocation scheme for the downlink relay frame. Numerical results show that relay performance of the TTR with a single-frame or a multiframe structure and that of the STR relay modes are almost the same in a two-hop system. However, in a three-hop system, the TTR mode with a single-frame structure outperforms other relay modes.

• Advances in aircraft and spacecraft science
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• 제5권4호
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• pp.459-475
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• 2018

In the field of aerospace engineering, accurate control of a spacecraft's orientation is often very important to mission success. Therefore, attitude control is a technically plentiful and extensively studied subject in controls literature during recent decades. This investigation of spacecraft attitude control is assumed to address two important aspects of the problem solutions. One sliding mode anti-disturbance control for utilization of faulty actuator components and another one disturbance observer based control to improve the pointing accuracy in the absence of anti-vibration equipment for the elastic appendages like a solar panel. Simultaneous occurrence of vibration due to flexible appendages and reaction degradation due to failure in attitude actuators complicates this case. The advantage of this method is acquisition proper control by the combination of disturbance observer and sliding mode compensation that form a fault tolerant control for the concerned satellite attitude control system. Furthermore, the proposed composite method indicates that occurrence the failure in actuators and even elastic solar panel vibration effect may be handled directly without reconfiguring the control components or providing piezoelectric devices. It's noteworthy, attitude quaternion and angular velocity commands are robustly tracked via controllers to become inclined to zero.

• 제어로봇시스템학회논문지
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• 제19권9호
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• pp.813-821
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• 2013

In this paper, we present the development of P-SURO II hybrid AUV (Autonomous Underwater Vehicle) which can be operated in both of AUV and ROV (Remotely Operated Vehicle) modes. In its AUV mode, the vehicle is supposed to carry out some of underwater missions which are difficult to be achieved in ROV mode due to the tether cable. To accomplish its missions such as inspection and maintenance of complex underwater structures in AUV mode, the vehicle is required to have high level of autonomy including environmental recognition, obstacle avoidance, autonomous navigation, and so on. In addition to its systematic development issues, some of algorithmic issues are also discussed in this paper. Various experimental studies are also presented to demonstrate these developed autonomy algorithms.

• 대한기계학회논문집A
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• 제20권9호
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• pp.2744-2751
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• 1996

In case of limited power supply, a rotating shaft system may not reach its operating speed that is greater than its critical speed, but the speed oscillates with small ampllitude near critical speed. As a result, it is considered that the operating mode plays an important role in the smooth start of machines. In order to investigate the dynamic behaviors of the rotating shaft system at the beginning stage, one has derived the equations of motion whose degrees of freedom is three, two translations and one rotation. The simultaneous differential equations are numerically solved by using runge-Kutta method, and thus the small time step length could be required corresponding to the stability of solution. Three types of operating modes dependent upon the driving torque rate have been numerically investigated according to the maximum displacement of shaft center. The first type of relation is linear, the second type is composed of two linear curves recommended by machine manufacturer, and the last one is the proposed torque curve reflecting the frequency response curve of one degree of freedom system. For the second type of modes, it is found that the optimal range of intermediate speed to the critical speed lies between 0.8 and 0.9. In addition to that, the maximum displacement can be reduced more if the third type of mode is utilized.

• 대한조선학회지
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• 제20권1호
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• pp.21-27
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• 1983

The mode superposition method(MSM) for the forced transverse vibration analysis of structures subject to Timoshenko beam analogy, which had originally been developed by Ormondroyd and McGoldrick, is reviewed to formulate it in more general form taking account of rotary inertia, dampings in separate terms of internal and external ones, and simultaneous action of exciting forces and moments. To investigate some general features of the method in practical utilizations, resonant maximum amplitudes of 4 high speed ships under concentrated sinusoidal excitation at the stern are calculated by both MSM and the finite difference method(FDM). For the FDM the hulls are discretized into 40 equal segments, and in utilization of MSM contributions of the first six modes are summed up to obtain responses up to the six-nodes resonant mode. The numerical results show that MSM gives slightly higher values, $4{\sim}10%$, than those by FDM. Since there is always uncertainty in the damping estimation of actual systems, influences of the damping magnitude on resonant amplitudes and a practical method to estimate modal damping coefficients are discussed.

• 약학회지
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• 제55권2호
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• pp.145-153
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• 2011

A simultaneous detection and quantification method for determining the Phenylalkylamine derivatives, such as methamphetamine (MA), amphetamine (AM), 3,4-methylenedioxymethamphetamine (MDMA), 3,4-methylenedioxyamphetamine (MDA), ketamine (KT), norketamine (NKT), phentermine (PT), fenfluramine (FFA) and phenmetrazine (PM), in oral fluid was developed and validated according to international guidelines. The validated method was applied to actual oral fluid samples collected from drug abuse suspects. The recovery of phenylalkylamines from oral fluid collection devices was also assessed. Oral fluid specimens from 20 drug abuse suspects submitted by the police were collected using Salivette$^{TM}$, Quantisal$^{TM}$ or direct expectoration. The samples were screened using a biochip array analyzer. For confirmation, the samples were analyzed by GC-MS in selected-ion monitoring (SIM) mode after extraction using automated SPE with a mixed-mode cation exchange cartridge and derivatization with trifluoroacetic anhydride (TFAA). The results from the immunoassay were consistent with those from GC-MS. All the oral fluid samples gave positive results for MA, AM, PT and/or PM. The detection of phenylalkylamines in oral fluid can provide a better indication of recent use than urine or hair. Therefore, the oral fluid specimen was useful for demonstrating phenylalkylamines abuse in the driving under the influence of drug (DUID) as an alternative specimen for urine.

• 분석과학
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• 제33권6호
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• pp.274-284
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• 2020

액체시료 중 89Sr와 90Sr을 자동핵종분리장치를 이용하여 Sr-resin으로 분리-정제하고, 액체섬광계수기(LSC)로 동시 분석하는 방법을 연구하였다. 액체시료 0.5 kg 중 방사성스트론튬을 탄산염 형태로 농축하고, Sr-resin 2 mL (Bed volume)으로 분리하였다. 유량이 최대 1 mL min-1까지 가능한 중력법과, 유량 2 mL min-1, 4 mL min-1 조건에서, Sr과 방해이온들의 거동을 평가하였다. LSC를 이용해 섬광용액을 혼합하지 않은 Cerenkov mode와, 섬광용액을 혼합한 Scintillation mode에서 측정한 결과를 이용해 정제된 89Sr와 90Sr의 방사능을 동시에 분석하였다. 표준선원을 이용해 90Sr/89Sr의 방사능 비가 1:1, 1:2, 1:5 되도록 탈염수를 이용해 모의시료를 준비하였고, 89Sr 방사능은 0.5~10 Bq kg-1, 90Sr 방사능은 0.5~50 Bq kg-1의 범위이다. Sr의 회수율은 68~94 %이고, 89Sr의 상대편의는 -5~20 %, 90Sr 방사능의 상대편의는 -10~10 %로 나타났다.