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Emission Characteristics of Poly(3-alkylthiophene) with TPD Addition (TPD 첨가에 따른 poly(3-alkylthiophene)의 발광특성)

  • 서부완;김주승;구할본;이경섭;박복기;조재철
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2000.07a
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    • pp.308-311
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    • 2000
  • The organic electroluminescene (EL) device has gathered much interested because of its potential in materials and simple device fabrication. We fabricated EL device which have a mixed single emitting layer containing N,N'-diphenyl-N,N'-(3-methylphenyl)-1,1'-biphenyl-4,4'-diamine [TPD] and poly(3-hexylthiophene) [P3HT]. The molar ratio between P3HT and TPD chaged with 1:1, 3:1, 5:1, 3:2 and 5:2. EL intensity of ITO/P3HT+TPD/Mg:In devices is enhanced by addition of TPD into P3HT. This can be explained that the energy transfer occurs from TPD to P3HT. Recombination probability increases in emitting layer because that TPD as hole transport material plays a role more injection hole and Mg:In (3.7eV) electrode has low work function make easily electron injection. ITO/P3HT+TPD(5:2)/Mg:In devices emit orange-red light at 28V.

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The Use of Joint Hierarchical Generalized Linear Models: Application to Multivariate Longitudinal Data (결합 다단계 일반화 선형모형을 이용한 다변량 경시적 자료 분석)

  • Lee, Donghwan;Yoo, Jae Keun
    • The Korean Journal of Applied Statistics
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    • v.28 no.2
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    • pp.335-342
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    • 2015
  • Joint hierarchical generalized linear models proposed by Molas et al. (2013) extend the simple longitudinal model into multiple models fitted jointly. It can easily handle the correlation of multivariate longitudinal data. In this paper, we apply this method to analyze KoGES cohort dataset. Fixed unknown parameters, random effects and variance components are estimated based on a standard framework of h-likelihood theory. Furthermore, based on the conditional Akaike information criterion the correlated covariance structure of random-effect model is selected rather than an independent structure.

Fabrication of CIGS Thin Film Solar Cell by Non-Vacuum Nanoparticle Deposition Technique (비진공 나노입자 코팅법을 이용한 CIGS 박막 태양전지 제조)

  • Ahn, Se-Jin;Kim, Ki-Hyun;Yoon, Kyung-Hoon
    • 한국신재생에너지학회:학술대회논문집
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    • 2006.06a
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    • pp.222-224
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    • 2006
  • A non-vacuum process for $Cu(In,Ga)Se_2$ (CIGS) thin film solar cells from nanoparticle precursors was described in this work CIGS nanoparticle precursors was prepared by a low temperature colloidal route by reacting the starting materials $(CuI,\;InI_3,\;GaI_3\;and\;Na_2Se)$ in organic solvents, by which fine CIGS nanoparticles of about 20nm in diameter were obtained. The nanoparticle precursors were mixed with organic binder material for the rheology of the mixture to be adjusted for the doctor blade method. After depositing the mixture of CIGS with binder on Mo/glass substrate, the samples were preheated on the hot plate in air to evaporate remaining solvents ud to burn the organic binder material. Subsequently, the resultant (porous) CIGS/Mo/glass simple was selenized in a two-zone Rapid Thermal Process (RTP) furnace in order to get a solar ceil applicable dense CIGS absorber layer. Complete solar cell structure was obtained by depositing. The other layers including CdS buffer layer, ZnO window layer and Al electrodes by conventional methods. The resultant solar cell showed a conversion efficiency of 0.5%.

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A FINITE-VISCOELASTIC CONTINUUM MODEL FOR RUBBER AND ITS FINITE ELEMENT ANALYSIS

  • Kim, Seung-Jo;Kim, Kyeong-Su;Cho, Jin-Yeon
    • Journal of Theoretical and Applied Mechanics
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    • v.1 no.1
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    • pp.97-109
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    • 1995
  • In this paper, a finite viscoelastic continuum model for rubber and its finite element analysis are presented. This finite viscoelatic model based on continuum mechanics is an extended model of Johnson and Wuigley's 1-D model. In this extended model, continuum based kinematic measures are rigorously defied and by using this kinematic measures, elastic stage law and flow rule are introduced. In kinematics, three configuration are introduced. In kinematics, three configuration are introduced. They are reference, current and virtual visco configurations. In elastic state law, it is assumed that at a certain time, there exists an elastic potential which describes the recoverable elastic energy. From this elastic potential, elastic state law is derived. The proposed flow rule is based on phenomenological observation. The flow rule gives precise relaxation response. In finite element approximation, mixed Lagrangian description is used, where total and similar method of updated Lagrangian descriptions are used together. This approach reduces the numerical job and gives simple nonlinear syatem of equations. To satisfy the incompressible condition, penalty-type modified Mooney-Rivlin energy function is adopted. By this method nearly incompressible condition is obtain the virtual visco configuration. For verification, uniaxial stretch tests are simulated for various stretch rates. The simulated results show good agreement with experiments. As a practical experiments. As a preactical example, pressurized rubber plate is simulated. The result shows finite viscoelastic effects clearly.

Development of a Metal Cladding with Protective SiC Composites and the Characteristics on High temperature Oxidation (SiC 복합체 보호막 금속 피복관의 개발 및 고온산화 특성 분석)

  • Noh, Seonho;Lee, Dong-hee;Park, Kwangheon
    • Journal of Surface Science and Engineering
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    • v.48 no.5
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    • pp.218-226
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    • 2015
  • The goal of this study is to investigate a metal cladding that contains SiC composites as a protective layer and analysis the characteristics of the specimens on high temperature oxidation To make SiC composites, the current process needs a high temperature (about $1100^{\circ}C$) for the infiltration of fixing materials such as SiC. To improve this situation, we need a low temperature process. In this study, we developed a low temperature process for making SiC composites on the metal layer, and we have made two kinds: cladding with protective SiC composites made by polycarbosilane(PCS), and a PCS filling method using supercritical carbon dioxide. A corrosion test at $1200^{\circ}C$ in a mixed steam and Ar atmosphere was performed on these specimens. The result show that the cladding with protective SiC composites have excellent oxidation suprression rates. This study can be said to have developed new metal cladding with enhanced durability by using SiC composite as protective films of metal cladding instead of simple coating film.

Simultaneous Preconcentration and Determination of Trace Elements in Water Samples by Coprecipitation-Flotation with Lanthanum Hydroxide $[La(OH)_3]$

  • 김영상;김기찬
    • Bulletin of the Korean Chemical Society
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    • v.16 no.7
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    • pp.582-588
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    • 1995
  • The preconcentration and determination of trace Cd(Ⅱ), Cu(Ⅱ), Pb(Ⅱ), Mn(Ⅱ) and Zn(Ⅱ) in water samples were studied by the precipitate flotation using La(OH)3 as a coprecipitant. The analytes were quantitatively coprecipitated by adding 3.0 mL of 0.1 M La(Ⅲ) solution in a 1,000 mL water sample and adjusting the pH to 9.5 with NaOH solution. After the addition of the 1:8 mixed surfactant solution of each 0.1% sodium oleate and sodium lauryl sulfate, the solution was stirred with a magnetic stirrer for 10 minutes. The precipitates were floated to the surface by bubbling with nitrogen gas and collected in a small sampling bottle. The precipitates were dissolved in nitric acid and then the solutions were diluted to 25.00 mL with a deionized water. The analytes were determined by flame atomic absorption spectrometry. This procedure was applied to the waste water analysis. This technique was simple, convenient and especially rapid for the analysis of a large volume of sample. And also, from the recoveries of better than 92% which were obtained from real samples, this method could be judged to be applicable to the preconcentration and quantitative determination of trace elements in water samples.

A Study on the Reliability of Cooling Water Systems Using R436B (대체냉매 R436B를 적용한 정수기 냉각수 시스템 신뢰성 평가에 관한 연구)

  • Nam, Hyun-Kyu;Bai, Sangeun;Bai, Cheol-Ho;Ko, Jung-Su;Jin, Byung-Joo;Oh, Ju-Chul
    • Korean Journal of Air-Conditioning and Refrigeration Engineering
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    • v.25 no.8
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    • pp.438-442
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    • 2013
  • The alternative refrigerant R436B is applied, to assess the application feasibility for a commercial cooling water system. The characteristic stability was verified by Sealed glass tube test and Autoclave test. R436B is chemically stable with the compressor material. The Oil miscibility test shows the usual compressor oil mixed well with R436B. Through the life acceleration test, the cooling performance is maintained. Though slight changes in oil and capillary tube diameter were found, they were within the permitted range. R436B should be applied to commercial cooling water systems as a simple replacement for the usual refrigerant.

The Effect of Anthropomorphism Level of the Shopping Chatbot, Message Type, and Media Self-Efficacy on Purchase Intention (쇼핑 챗봇의 의인화 수준과 메시지 유형, 미디어 자기효능감이 구매의도에 미치는 영향)

  • Ha, Yu Jin;Hwang, Sun jin
    • Journal of Fashion Business
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    • v.25 no.4
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    • pp.79-91
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    • 2021
  • Currently, chatbot, a conversational platform based on artificial intelligence, is drawing attention as a new marketing channel. This study attempted to verify the effect of the anthropomorphism, message type, and media self-efficacy level on purchase intention. The experimental design of this study was a 2 (anthropomorphism level of shopping chatbot: low vs. high) × 2 (message type: factual vs. evaluative) × 2 (media self-efficacy: low vs. high) three-way mixed analysis of variance (ANOVA). This study conducted a survey by the convenience sampling method of 402 women in their 20s and 30s living in Seoul and the Gyeonggi area who were aware of chatbot services. For the final analysis, 388 questionnaires were used. Data were analyzed with the SPSS 23 program and three-way ANOVA. Simple main effects analysis was conducted. The results of this study were as follows. First, there were statistically significant differences in purchase intention according to anthropomorphism level, message type, and media self-efficacy. Second, message type and media self-efficacy showed statistically significant interaction effects on purchase intention. Lastly, anthropomorphism and the media self-efficacy level and the message type of the shopping chatbots showed significant three-way interaction effects on purchase intention.

Self-Supported NiSe/Ni Foam: An Efficient 3D Electrode for High-Performance Supercapacitors

  • Zhang, Jingtong;Zhao, Fuzhen;Du, Kun;Zhou, Yan
    • Nano
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    • v.13 no.11
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    • pp.1850136.1-1850136.12
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    • 2018
  • Three-dimensional (3D) mixed phases NiSe nanoparticles growing on the nickel foam were synthesized via a simple one-step hydrothermal method. A series of experiments were carried out to control the morphology by adjusting the amount of selenium in the synthetic reaction. Meanwhile, the as-prepared novel column-acicular structure NiSe exist three advantages including ideal electrical conductivity, high specific capacity and high cycling stability. It delivered a high capacitance of $10.8F\;cm^{-2}$ at a current density- of $5mA\;cm^{-2}$. An electrochemical capacitor device operating at 1.6 V was then constructed using NiSe/NF and activated carbon (AC) as positive and negative electrodes. Moreover, the device showed high energy density of $31W\;h\;kg^{-1}$ at a power density of $0.81kW\;kg^{-1}$, as well as good cycling stability (77% retention after 1500 cycles).

Fabrication of a solid catalyst using coal fly ash and its utilization for producing biodiesel

  • Go, Young Wook;Yeom, Sung Ho
    • Environmental Engineering Research
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    • v.24 no.2
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    • pp.324-330
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    • 2019
  • To recycle raw fly ash (RFA), a waste from thermal power plants, it was used to prepare solid catalysts which have many advantages compared with homogenous catalysts. When biodiesel was produced from soybean oil using RFA, only 1.2% of biodiesel conversion was obtained. A metal hydroxide, NaOH, KOH or $Ca(OH)_2$, was mixed with the acid-treated fly ash (ATFA), and the mixture was calcined at $700^{\circ}C$ for 3 h to prepare the solid catalyst. The solid catalyst prepared by mixing ATFA with NaOH, designated as SC-Na, showed a better performance than those prepared by mixing ATFA with KOH or $Ca(OH)_2$, respectively. The optimal mass ratio of ATFA with NaOH was 1:3, at which the proportion of $Na_2O$ increased to 60.2% in SC-Na, and 97.8% of biodiesel conversion was achieved under optimal reaction conditions (2 w% SC-Na relative to oil and 5 mL-methanol/g-oil at $50^{\circ}C$ for 4 h). Finally, a batch operation was repeatedly carried out to test the feasibility of reusing the solid catalyst, and more than 96% biodiesel conversion was stably achieved for the third round of operations. This study shows that RFA was successfully recycled to solid catalysts through a simple preparation method, and the solid catalyst was reused for the production of biodiesel with high conversion.