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Synthesis and Properties of Polyurethane/Clay Nanocomposites Containing Siloxane Segment (실록산 세그먼트를 가진 폴리우레탄/점토 나노복합체의 제조 및 물성에 관한 연구)

  • Lee Jung Eun;Kim Hyung Joong
    • Polymer(Korea)
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    • v.29 no.2
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    • pp.177-182
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    • 2005
  • Montmorillonite (MMT) modified with siloxane diamine was reacted with a reactant obtained from 4,4'-diphenyl methane diisocyanate (MDI) and polyester type polyol, $Nippollan4010(\bar{M}_n2000)$. Finally, polyurethane (PU)/MMT composites were prepared by using 1,4-butane diol as a chain extender in $25\;wt\%$ solution of N,N-dimethyl acetamide (DMAc). It was expected that these nanocomposites had superior exfoliation property to that of MMT dispersed polyurethanes produced by simple mixing due to insertion of siloxane main chain to the silicate interlayer of MMT. Extent of reaction and formation of final products were analysed by using FT-IR spectroscopy. Dispersion into the PU and intercalation of MMT were identified by applying X-ray diffraction (XRD) and transmission electron microscopy (TEM). Tensile data were acquired by universal test machine (UTM). Thermal stability and variation of surface energy were characterized by thermal gravimetric analysis (TGA) method and measurement of contact angle on the synthesized composites, respectively. As the results the organo-MMT modified with siloxane diamine in the PU composites has an intercalated structure relatively well-expanded rather than a completely exfoliated structure. The tensile strengths and the moduli for the PU/organo-MMT composites were drastically enhanced in comparison to those of $PU/Na^+-MMT$ composites.

Rapid Determination of Ginsenosides Rb1, Rf, and Rg1 in Korean Ginseng Using HPLC (HPLC를 이용한 고려인삼 중 진세노사이드 Rb1, Rf 및 Rg1의 신속분석 방법 개발)

  • Hong, Hee-Do;Choi, Sang-Yoon;Kim, Young-Chan;Lee, Young-Chul;Cho, Chang-Won
    • Journal of Ginseng Research
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    • v.33 no.1
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    • pp.8-12
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    • 2009
  • A simple gradient HPLC method for rapid determination of major ginsenosides ($Rg_1$ and $Rb_1$) and unique ginsenoside (Rf) of Korean ginseng (Panax ginseng C.A. Meyer) was developed. Within 50min, three ginsenosides have been separated and identified on $\mu$-Bondapak $C_{18}$ column ($3.9{\times}300\;mm$, $10{\mu}m$) with gradient elution using water and acetonitrile as a mobile phase. The method was validated in terms of linearity, accuracy, and precision. The correlation coefficients ($r^2$) for calibration curves of ginsenosides were over 0.9997. The developed HPLC method was successfully applied to the analysis of ginseng samples and the recoveries of ginsenosides were in the range of $101.1{\sim}115%$ with RSD<3.2%. The developed method could be used for rapid evaluation of the ginsenosides $Rg_1$, $Rb_1$, and Rf.

A Methodology for Making Military Surveillance System to be Intelligent Applied by AI Model (AI모델을 적용한 군 경계체계 지능화 방안)

  • Changhee Han;Halim Ku;Pokki Park
    • Journal of Internet Computing and Services
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    • v.24 no.4
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    • pp.57-64
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    • 2023
  • The ROK military faces a significant challenge in its vigilance mission due to demographic problems, particularly the current aging population and population cliff. This study demonstrates the crucial role of the 4th industrial revolution and its core artificial intelligence algorithm in maximizing work efficiency within the Command&Control room by mechanizing simple tasks. To achieve a fully developed military surveillance system, we have chosen multi-object tracking (MOT) technology as an essential artificial intelligence component, aligning with our goal of an intelligent and automated surveillance system. Additionally, we have prioritized data visualization and user interface to ensure system accessibility and efficiency. These complementary elements come together to form a cohesive software application. The CCTV video data for this study was collected from the CCTV cameras installed at the 1st and 2nd main gates of the 00 unit, with the cooperation by Command&Control room. Experimental results indicate that an intelligent and automated surveillance system enables the delivery of more information to the operators in the room. However, it is important to acknowledge the limitations of the developed software system in this study. By highlighting these limitations, we can present the future direction for the development of military surveillance systems.

Spirituality and Social Work Scholarship in Korea - A Content Analysis - (한국에서의 Spirituality와 사회사업에 대한 연구 동향과 전망)

  • Kim, Kyung-Mee;Canda, Edward R.
    • Korean Journal of Social Welfare Studies
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    • v.40 no.2
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    • pp.203-225
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    • 2009
  • There are emerging international trends in social work scholarship toward increasing attention to spirituality in research and publications. However, little has been published about this beyond the North American and European contexts. Therefore, this article explores the state of the art scholarly social work publications in an East Asian country, the Republic of Korea. First, a brief overview is given of the history and current situation of connections between spirituality and religions with social work in Korea. Then, results of a content analysis of Korean academic journal articles are presented to indicate the state of the art and implications for further work, including international collaborations. The content analysis revealed that there is relatively little empirical work in this area, although it has grown in recent years. Most of the empirical research is based on simple statistical methods while systematic qualitative studies are lacking. Conceptual work provides guidelines for various religious specific approaches to social work; development of approaches that are inclusive of diverse religious and nonreligious spiritual perspectives is just beginning. However, there are indications of the potential for a significant increase of scholarly work on spirituality and social work. International collaborations could facilitate this.

Studies on the Correlation between Heavy Metal Contents of Apple Orchard Lands and its'Leaves (사과 과수원토양(果樹園土壤)과 그 잎중(中)의 중금속(重金屬) 함량간(含量間)의 상관관계(相關關係)에 관한 연구(硏究))

  • Kim, Dong-Ho;Lim, Soo-Kil;Kwon, Oh-Kyeong
    • Korean Journal of Environmental Agriculture
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    • v.8 no.1
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    • pp.1-6
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    • 1989
  • This study was performed to reveal the heavy metal contents in apple leaves, and to estimate the correlation between contents of heavy metals of orchard lands and those of apple leaves. For this experiment, the apple leaves were collected from 58 apple orchards in Korea. The results were as follows ; 1. The average heavy metal contents in apple leaves were 26.44(6,23-182,85) ppm in Cu, 0.34 (0.07-0,61) ppm in Cd and 9.47 (0.00-225.50) ppm in Pb. 2. On the simple correlation coefficients between contents of heavy metals of orchard lands and those of apple leaves, all three copper cadmium and lead were positive but cadmium was insignificanfly, correlated. There was no difference among varieties (Ralls, Jonathan, etc) in these results. 3. The 0.1N HCl extraetion proved, was more suitable than the $IN-NH_4OAC$ extraction for describing the relation-Ship between heavy metal contents of apple leaves and those of orchard lands.

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Model on the Relationship between the Radius of Curvature and Central Angle -the Case of Divided-roads in Flat Traditional Villages- (평지 전통마을 갈림길의 중심각과 곡률반경에 관한 연구)

  • 김윤하;안계복
    • Journal of the Korean Institute of Landscape Architecture
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    • v.28 no.2
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    • pp.10-16
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    • 2000
  • The purpose of this study is to identify relationships between a central angle and a radius of curvature of divided roads in flat terrain of traditional villages, suggesting layout criteria for traditional villages: Nak-an, Sung-Eup, Ha-Whe. This study is sought to find the optimum model through the various SAS regression analyses. a regression analysis of this data was adopted to induce the relationship formula between a central angle of curve and a radius of curvature. Results of this study are as follows: 1) Most of the divided roads in traditional villages have a complex curve rather than a simple curve. 2) A central angle of curve has ranged from 11$^{\circ}$to 127$^{\circ}$, with a mean degree of 63.9. 3) In the lower level of central angle(11-40$^{\circ}$), the branch roads have distributed with a high frequency, but with a low frequency in the higher level of central angle(90-140$^{\circ}$). 4) A radius of curvature in the divided roads has ranged from 0.9m to 59.6, but half of the roads have concentrated on 1-6m of the curvature. 5) Compared to the result of hilly villages in previous study(Ahn, 1999), value of central angels in flat villages is lower than that of hilly villages, while a mean value of the curvature is higher than that of hilly villages. 6) A Non-linear regression analysis, resulting from the SAS application, was useful method to induce a relationship formula between a central angle and a radius of curvature in the branch roads. Our study's formula is as follow: R=100.3*EXP(-0.06*$\delta$)+3.91. 7) Our study model has less error than that of the Kishizuka's method, being applicable to a broader range of the branch roads. 8) A minimum radius of curvature in our study has showed 3.9m, suggesting to reconsider applications of the Kishizuka's(5.8m) in the footpass design, In the study for this presupposition model the efficiency and utility of it can be estimated to grow large according to how much and how far it includes both extremes of data. This study is for the application to a design in future through the numerical formula of divided roads of various traditional villages. The studies from now on will be about the quasi-hilly quasi-hilly village and hilly village supplementing these factors more.

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The Influence of Calling on School Organizational Commitment of School Health Nurses (보건교사의 소명의식이 학교조직몰입에 미치는 영향)

  • Kim, Hyo Soon;Lee, Yoonshin;Kim, Ok Sun;Sok, Sohyune
    • The Journal of the Korea Contents Association
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    • v.20 no.10
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    • pp.535-543
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    • 2020
  • With the emergence of new infectious diseases and changes in the educational environment, the health problems of school-age students are increasing. Accordingly, the role of school health teachers is expanding and becoming more important. The study was to examine the effect of calling on school organizational commitment of school health nurses. Samples were a total of 143 school health nurses working in elementary, middle, and high schools, Gyeonggi-do, South Korea who understood the purpose of this study and voluntarily participated in the study. Measures were Calling and Vocation Questionnaire-Korea (CVQ-K) and organization commitmen questionnaire. Data were analyzed using SPSS/WIN 23.0 program. The analyses showed that the prediction model for school organizational commitment of school health nurses was significant (F=16.142, p<.001). The value of the adjusted R2 was 0.307, which corresponds to the explanatory power of 30.7%. The factor that was found to have the most influence on school organizational commitment of school health nurses was purpose/meaning (β=.28, p=.011), followed by number of classes (β=-.20, p=.006). In order to improve the school organizational commitment of school health nurses, the purpose/meaning and the number of classes should be considered.

Gene Transfer Optimization via E. coli-driven Conjugation in Nocardiopsis Strain Isolated via Genome Screening (유전체 스크리닝으로 선별된 Nocardiopsis 균주의 대장균 접합을 통한 유전자 도입전략 최적화)

  • Jeon, Ho-Geun;Lee, Mi-Jin;Kim, Hyun-Bum;Han, Kyu-Boem;Kim, Eung-Soo
    • Microbiology and Biotechnology Letters
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    • v.39 no.2
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    • pp.104-110
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    • 2011
  • Actinomycetes, Gram positive soil bacteria, are valuable microorganisms which produce useful secondary metabolites including antibiotics, antiparasitic substances, anti-cancer drugs, and immunosuppressants. Although a major family of actinomycetes, known as streptomycetes, has been intensively investigated at the molecular level for several decades, a potentially valuable and only recently isolated non-streptomycetes rare actinomycetes (NSRA) family has been poorly characterized due to lack of proper genetic manipulation systems. Here we report that a PCR-based genome screening strategy was performed with approximately 180 independently isolated actinomycetes strains to isolate potentially valuable NSRA strains. Thanks to this simple PCR-based genome screening strategy we were able to identify only seven NSRA strains, followed by 16S rRNA sequencing for confirmation. Through further bioassays, one potentially valuable NSRA strain (tentatively named Nocardiopsis species MMBL010) was identified which possessed both antifungal and antibacterial activities, along with the presence of polyketide synthase and non-ribosomal peptide synthase genes. Moreover, Nocardiopsis species MMBL010, which was intrinsically recalcitrant to genetic manipulation, was successfully transformed via E. coli-driven conjugation. These results suggest that PCR-based genome screening, followed by the establishment of an E. coli-driven conjugation system, is an efficient strategy to maximize potentially valuable compounds and their biosynthetic genes from NSRA strains isolated from various environments.

Development of Simple Test Method using VOC Analyzer to Measure Volatile Organic Compounds Emission for Particleboards (VOC Analyzer를 이용한 파티클보드로부터 방산되는 휘발성유기화합물의 간이 측정방법 개발)

  • An, Jae-Yoon;Kim, Sumin;Kim, Jin-A;Kim, Hyun-Joong;Mun, Suck-Joong
    • Journal of the Korean Wood Science and Technology
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    • v.34 no.4
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    • pp.22-30
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    • 2006
  • The volatile organic compound (VOC) Analyzer is a portable device to measure the four main aromatic hydrocarbon gases: toluene, ethylbenzene, xylene and styrene. With the VOC Analyzer, a semiconductor gas sensor eliminates the need for the carrier gas which is required for conventional gas chromatographs. In addition, since the semiconductor gas sensor is supersensitive to gas components, it is not necessary to use a conventional gas concentrator or other complicated equipment. Compared with other measurement methods, the VOC analyzer is useful for measuring toluene, ethylbenzene, xylene and styrene in wood-based panel because of its ease in obtaining field results and repeating the test. The VOC Analyzer primarily measures four VOC in the air. In this study, we designed a test method of VOC measurement for particle board. A specimen was sealed in 3L polyester bag, after 96hours we could measure maximum VOC emission level that is a stabilized VOC Value. For easy, fast and economic testing of TVOC emission from wood-based panel, we developed the test method with the VOC Analyzer. The VOC Analyzer is expected to gain widespread use in the manufacturing field where a quick and easy test for VOC emission from wood-based panel is required. Furthermore, the VOC Analyzer promises to become an easier, faster and more economic technique than the currently used standard methods.

Relative Importance of Bottom-up vs. Top-down Controls on Size-structured Phytoplankton Dynamics in a Freshwater Ecosystem: II. Investigation of Controlling Factors using Statistical Modeling Analysis (담수성 식물플랑크톤의 크기별 동태에 대한 상향식, 하향식 조절간의 상대적 중요도 조사: II. 통계 모델링 분석을 이용한 조절인자 분석)

  • Song, Eun-Sook;Lim, Jang-Seob;Chang, Nam-Ik;Sin, Yong-Sik
    • Korean Journal of Ecology and Environment
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    • v.38 no.4 s.114
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    • pp.445-453
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    • 2005
  • Relative importance between bottom-up and top-down controls on phytoplankton dynamics was investigated in the Juam Reservoir, Chonnam based on the results from statistical analyses including regression and artificial neural network (ANN) modeling. Effects of nutrients on size-structured phytoplankton dynamics were explored by simple linear regression analysis and relative importance between bottom-up and top-down controls was estimated based on results from the artificial neural network analyses. Although there is a limitation in determining direct grazing effects since chlorophyll a : pheopigments ratios, indirect index for grazing activity rather than grazing rates or herbivores biomass were used, the results from regression analysis showed that nutrients especially orthophosphates were positively correlated with the phytoplankton biomass and chlorophyll a : pheopigments ratios were also positively correlated with the phytoplankton biomass at lower coefficient of determination ($r^2$) compared to orthophosphates. The simulation results from ANN suggested that the bottom-up mechanisms including water temperature and availability of nutrients, especially orthophosphates were more important than top-down mechanisms such as grazing in the phytoplankton dynamics.