• 제목/요약/키워드: silver

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The Silver Cycle and Fluxes in the Ocean

  • Ju, Se-Jong
    • Journal of the korean society of oceanography
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    • 제32권3호
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    • pp.156-161
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    • 1997
  • The biogeochemical cycle of silver has rarely been reviewed, even though the silver ion (Ag$^{\times}$) is extremly toxic to some organisms. Its concentration is still rising sharply because of increased anthropogenic activity, specifically the discharge from the film industry (mainly, silver thiosulfate: Ag (S$_2$O$_3$)${^3-}_2$). Recently, a number of researchers have quantified the major fluxes and reservoirs of silver in the open ocean, bays, and estuaries. A review of the available information for Ag cycling in the open ocean shows that the riverine input (from human activity and weathering processes: 7${\times}$10$^6$ kg/yr and 5${\times}$10$^6$ kg/yr, respectively) is the dominant source of Ag to estuarine and coastal regions. Most of the silver (90% of riverine input silver) is removed in coastal sediments by the physical-chemical character of silver due to its high partitioning with particulate matter. On the other hand, in the open ocean the atmospheric input (wet and dry deposition: 1.48${\times}$10$^6$ kg/yr and 1.94${\times}$ 10$^5$ kg/yr, respectively) becomes more important as a source of silver than riverine input. The residence time of silver calculated from available data is 1250 yrs in the deep ocean below 500 m, but only 3 yrs in the surface ocean.

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LTCC 전극공정부산물 침출 용액으로부터 은 회수 및 은 나노입자 제조 (Recovery and Synthesis of Silver Nanoparticles from Leaching Solution of LTCC Electrode By-Products)

  • 유주연;강유빈;박진주;류호진;윤진호;이근재
    • 한국분말재료학회지
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    • 제24권4호
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    • pp.315-320
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    • 2017
  • There has been much interest in recycling electronic wastes in order to mitigate environmental problems and to recover the large amount of constituent metals. Silver recovery from electronic waste is extensively studied because of environmental and economic benefits and the use of silver in fabricating nanodevices. Hydrometallurgical processing is often used for silver recovery because it has the advantages of low cost and ease of control. Research on synthesis recovered silver into nanoparticles is needed for application to transistors and solar cells. In this study, silver is selectively recovered from the by-product of electrodes. Silver precursors are prepared using the dissolution characteristics of the leaching solution. In the liquid reduction process, silver nanoparticles are synthesized under various surfactant conditions and then analyzed. The purity of the recovered silver is 99.24%, and the average particle size of the silver nanoparticles is 68 nm.

Selective Coordination of Silver Ions to Poly(styrene-b-(ethylene-co-butylene)-b-styrene) and its Influence on Morphology and Facilitated Olefin Transport

  • Lee, Dong-Hoon;Kang, Yong-Soo;Kim, Jong-Hak;Kang, Sang-Wook
    • Macromolecular Research
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    • 제16권8호
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    • pp.676-681
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    • 2008
  • The $\pi$-complex membranes of poly(styrene-b-(ethylene-co-butylene)-b-styrene) (SEBS) of two silver salts of $AgBF_4$ and $AgCF_3SO_3$ were prepared and tested for the separation of the propylene/propane mixtures. The Fourier-transform infrared (FT-IR) spectra of these complexes showed that the silver salts were dissolved in SEBS up to a silver mole fraction of 0.14, due to $\pi$-complexation between the aromatic C=C bonds of styrene blocks and silver ions. Above this solubility limit, ion pairs and high-order ionic aggregates began to form, so that silver salts were distributed unselectively in both the EB and PS blocks. The domain size of the PS blocks was enlarged up to this critical concentration with increasing silver concentration without structural transitions, as confirmed by small angle x-ray scattering (SAXS). These structural properties of the SEBS/silver salt complexes may explain the lower separation properties for propylene/propane mixtures compared to poly(styrene-b-butadiene-b-styrene)(SBS)/silver salt complex membranes.

사진폐액으로부터 용매추출에 의한 은의 제거 및 회수에 대한 기초연구 (Fundamental Studies for the Removal and Recovery of Silver from Waste Photo-Developing Solution by Solvent Extraction)

  • 이선화;김동수;이화영
    • 한국물환경학회지
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    • 제22권1호
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    • pp.122-127
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    • 2006
  • Fundamental studies were carried out for an effective removal and recovery of silver from waste photo-developing solution by solvent extraction. The organic solvents examined for silver-extraction were ALIQUAT 336, D2EHPA, KELEX 100, and TBP. ALIQUAT 336, which is an anionic exchanger, was found to be efficient for the extraction of silver and the reason for this was considered to be due to the chloride ion contained in its structure. The extent of silver extraction was examined to increase with the concentration of ALIQUAT 336 until it reached 0.6 M and no more extraction was observed above this concentration. The extraction of silver by ALIQUAT 336 was found to reach its pseudo-equilibrium within a few minutes after the reaction started and additional slight increase in silver extraction was observed until 30 minutes of reaction time. The observed differences in silver extraction for artificial and actual waste solutions were considered to be based upon the different ionic form of silver-containing species in these solutions.

충서지역 노인층과 예비노인층의 실버타운 선호 차이점에 대한 연구 -주택유형과 공간구성을 중심으로- (A Study on the Difference of Preferences about Silver Town between Elderly Group and Pre-Elderly Group in Chungseo Province - Focused on Housing Type and Space Composition -)

  • 류혜지
    • 한국디지털건축인테리어학회논문집
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    • 제7권2호
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    • pp.43-50
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    • 2007
  • The aged population increasing rapidly, the population rate of over 65 years old was over 7.5% in 2000 in Korea. It means that Korea is aging society. But, the aged welfare accommodation are still insufficient and more facilities accommodating the aged should be built. This situations made a new concept of silver town of the welfare facility for the aged. The purpose of this study was to find the difference of preferences about silver town between elderly group and pre-elderly group in Chungseo province. Focused on housing type and space composition of silver town, the results of this study will provide some useful information for the development of silver town and for further studies. It is very important to refer to the preference about silver town of elderly group and pre-elderly group for planing the silver town. Main results of this study showed that silver town was the most preferable elderly housing alternative for elderly group. And silver town should be provided health care center for elderly group.

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High Density Silver Nanowire Arrays using Self-ordered Anodic Aluminum Oxide(AAO) Membrane

  • Kim, Yong-Hyun;Han, Young-Hwan;Lee, Hyung-Jik;Lee, Hyung-Bock
    • 한국세라믹학회지
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    • 제45권4호
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    • pp.191-195
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    • 2008
  • Highly ordered silver nanowire with a diameter of 10 nm was arrayed by electroless deposition in a porous anodic aluminum oxide(AAO) membrane. The AAO membrane was fabricated electrochemically in an oxalic acid solution via a two-step anodization process, while growth of the silver nanowire was initiated by using electroless deposition at the long-range-ordered nanochannels of the AAO membrane followed by thermal reduction of a silver nitrate aqueous solution by increasing the temperature up to $350^{\circ}C$ for an hour. An additional electro-chemical procedure was applied after the two-step anodization to control the pore size and channel density of AAO, which enabled us to fabricate highly-ordered silver nanowire on a large scale. Electroless deposition of silver nitrate aqueous solution into the AAO membrane and thermal reduction of silver nanowires was performed by increasing the temperature up to $350^{\circ}C$ for 1 h. The morphologies of silver nanowires arrayed in the AAO membrane were investigated using SEM. The chemical composition and crystalline structure were confirmed by XRD and EDX. The electroless-deposited silver nanowires in AAO revealed a well-crystallized self-ordered array with a width of 10 nm.

은의 표면 부식 및 변색을 방지하기 위해 설치된 Al 희생양극의 전기화학적 특성에 미치는 황산 농도의 영향 (Effect of concentration of H2SO4 on electrochemical properties of equipped Al sacrificial anode to prevent the corrosion and discolor of silver surface)

  • 신병현;정원섭
    • 한국표면공학회지
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    • 제54권1호
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    • pp.12-17
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    • 2021
  • Among the various precious metals, silver is used in various fields because of its low price than other precious metals. However, the surface of silver remains after rain in the atmosphere containing sulfur ions and chlorine ions, causing silver corrosion and discoloration. Existing documents have developed a anode to prevent corrosion but that are concentrated on secondary batteries. This study tried to prevent corrosion and discoloration of silver by using an Al sacrificial anode. Sulfuric acid decreased the potential of silver and increased the current density at active polarization and OCP. The amount of corrosion of silver with the Al sacrificial anode was reduced from 0.5 % to 6.5%. When silver is used for decoration outside, corrosion and discoloration of silver can be suppressed by installing an Al anode.

Fabrication of All-Solution Processed Transparent Silver Nanowire Electrode Using a Direct Printing Process

  • 백장미;이린;성명모
    • 한국진공학회:학술대회논문집
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    • 한국진공학회 2013년도 제44회 동계 정기학술대회 초록집
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    • pp.641-641
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    • 2013
  • We report the transparentsilver nanowire electrode fabricated by a direct printing process, liquid-bridge-mediated nanotransfer molding. We fabricated silver nanowire arrays by liquidbridge- mediated nanotransfer molding using the silver nanoparticle ink and PEDOT:PSS polymer. Weinvestigated the formation of silver nanowire arrays by SEM and transmittance of the transparent silver nanowire electrode. We also measured the conductivity to confirm the potential of our approach.

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은 이온의 항균작용에 관한 연구 (Studies on the sterilizing effect of the silver ion.)

  • 김덕묵
    • 기술사
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    • 제20권3호
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    • pp.26-29
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    • 1987
  • The physical and chemical characteristics of bacteriostatic water filter media are compared to granular activated carbon upon which a silver impregnated. Silver ion that has been chemically impregnated the activated carbon was the bactericidal agent in water filter media. Also, silver Ion that has teen chemically impregnated onto the activated acetate resin was the bactericidal agent in ultrasonic humidifier. Silver impregnated active carbon and silver cartridge will be able to the bactericidal agents for statical water.

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