• Title/Summary/Keyword: silk

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The Structural Changes in Silk Fibroin Induced by Methanol and Dilute Hydrochloric Acid and Its Photo yellowing Reduction Effect (견의 황변억제에 관한 연구 - 메탄올 및 희박염산처리에 의한 견피브로인의 내부구조전이가 황변억제에 미치는 영향 -)

  • Jang, Jeong-Dae
    • Fashion & Textile Research Journal
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    • v.4 no.2
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    • pp.198-202
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    • 2002
  • Degummed silk from Bombyx mori was dissolved in 9.3M lithium bromide solution. The regenerated silk fibroin films were completely ${\alpha}$-randomcoil type as shown by x-ray diffraction and infrared spectroscopy. The structural changes in silk fibroin induced by immersion into methanol and dilute hydrochloric acid and its photo-yellowing effect was studied. The changes of crystallinity were measured by infrared spectrometer. Yellowness index caused by ultraviolet irradiation were observed as a function of the structural change on silk fibroin. On treatment with methanol, ${\alpha}$-randomcoil silk film is converted to the ${\beta}$-form structure. After the treatment of hydrochloric acid on ${\beta}$-form structure in silk induced by immersion into methanol, ${\beta}$-form in silk fibroin is partially decreased. Crystallization owing to ${\beta}$-form transition reduced the initial yellowness index by ultraviolet irradiation. A little ${\beta}$-form structure in silk fibroin increased the initial yellowness in comparison with more ${\beta}$-form structure.

A Study of Functional Jeolpyon Prepared with Silk Protein (Silk Protein을 첨가한 기능성 절편의 제조에 관한 연구)

  • 황영정;김경옥
    • Korean Journal of Human Ecology
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    • v.7 no.1
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    • pp.43-50
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    • 2004
  • The purpose of this study is to reach silk protein added in differing amounts to Jeolpyon, Korean traditional rice cake, using rice powder as its primary material, estimation of the micro organism quality, physicochemical property, sensory evaluation and the property of storage period (20${pm} 5 ^{\circ}C$). In the physicochemical property, the content of proximate composition of rice powder was measured as 38.11% of moisture, 56.62% of total sugar, 5.11% of crude protein, 0.52% of crude lipid, 0.25% of ash. And the raw material of silk protein was measured as 6.61% of moisture, 91.22% of crude protein, 6.41% of crude lipid and 0.75% of ash. The pH of raw material for rice powder and silk protein Jeolpyon showed mild acidity as 6.41 and 6.23, respectively. In rice powder and silk protein, total free sugar contents was 0.89% and 0.02%, and total amino acids contents was 4.28% and 52.21 %, respectively. For sensory evaluation. color, taste, softness and adhesiveness were significantly acceptable in control and adding 1 % silk protein. Control and samples added 1$\sim$3% silk protein had high sensory score color in overall acceptance. In conclusion. Jeolpyon can be manufactured with nutritious Jeolpyon by adding silk protein.

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Physical Characteristics of Silk Gayageum Strings on the Preparing Conditions (원사의 종류와 처리조건에 따른 가야금 현의 특성)

  • Kim Young Dae;Choi Tea Jin;Chung In Ma;Yi Ji-Yong
    • Journal of Sericultural and Entomological Science
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    • v.46 no.1
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    • pp.32-37
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    • 2004
  • Gayageum and Geomungo are the traditional stringed music instrument in Korea. These strings are usually made of raw silk. This study was carried out to investigate the optimum condition for silk string producing method using several kind of silk and setting temperature of silk string. If the ply of strings and twisting condition were same, tenacity and elongation of every silk strings were similar, in spite of silk strings prepared by physically different raw silk. On the other hand, in setting treatment of twisted string, it was disclosed that the proper setting temperature of silk strings were 11$0^{\circ}C$ for 20 min.

The Effect of Dissolution Condition on the Yield, Molecular Weight, and Wet- and Electro-spinnability of Regenerated Silk Fibroins Prepared by LiBr Aqueous Solution

  • Cho, Hee-Jung;Um, In-Chul
    • International Journal of Industrial Entomology and Biomaterials
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    • v.20 no.2
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    • pp.99-105
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    • 2010
  • In this paper, the regenerated silk fibroins were dissolved in LiBr aqueous solution with different dissolution temperature and time, and the effects of the dissolution condition on the regeneration yield, molecular weight, wet spinnability, and electrospinnability of regenerated silk fibroin were investigated. The regeneration yield, molecular weight distribution, and wet spinnability of regenerated silk fibroin were nearly affected by the dissolution temperature and time. However, the electrospinning performance of silk fibroin was influenced by the dissolution condition implying the electrospinning of silk fibroin is more sensitive process than the wet spinning in the range tested in this study. While $25^{\circ}C$ of dissolution temperature resulted in a good electrospinnability of regenerated silk fibroin, the electrospinnability was slightly deteriorated when silk fibroin was dissolved at $60^{\circ}C$ for 6 hours. Also, though the fiber diameters of electrospun silk fibroin produced by the dissolution at $25^{\circ}C$ for 6 hours and 24 hours were 443 and 451 nm, respectively, that at $60^{\circ}C$ for 5 min was reduced to 411 nm. The fiber diameter was more decreased to 393 nm when the dissolution time increased up to 6 hours at $60^{\circ}C$.

Biomedical Applications of Silk Protein

  • Kweon, Hae-Yong;Cho, Chong-Su
    • International Journal of Industrial Entomology and Biomaterials
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    • v.3 no.1
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    • pp.1-6
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    • 2001
  • Silk protein has been investigated by many researchers to apply to biomedical field. We reviewed biomedical applications of silk protein such as matrix of wound dressing and drug delivery system. Since silk fibroin/ poly (ethylene glycol) (PEG) semi-interpenetrating polymer networks showed good mechanical properties and wound healing phenomena, it can be used as wound dressing materials. Sericin nanoparticles pre- pared by conjugation with PEG and silk protein/ poloxamer mixture gel are expected to become a deliv- ery as matrix for hydrophobic drug.

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Graft Polymerization of vinyl monomers onto silk (Vinyl단량체의 silk graft중합)

  • 남중희;마석일;이양후
    • Journal of Sericultural and Entomological Science
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    • v.19 no.1
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    • pp.33-36
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    • 1977
  • Graft polymerization of vinyl monomers onto silk were carried out in aqueous medium using ceric salt as an initiator, and discussed about the mechanical properties of silk. The results obtained are summarized as follows: 1. Percent grafting is greatly enhanced by the increasing of the temperature. 2. Effect of percent grafting is in the order of methyl methacrylate, and vinyl acetate. 3. Strength is decreased in the high grafted silk, and elongation is increased in the low grafted silk.

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Membranes for the Guided Bone Regeneration

  • Lee, Sang-Woon;Kim, Seong-Gon
    • Maxillofacial Plastic and Reconstructive Surgery
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    • v.36 no.6
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    • pp.239-246
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    • 2014
  • Many kinds of membrane have been used for the guided bone regeneration (GBR) technique. However, most membranes do not fulfill all requirements for the ideal membrane for the GBR technique. Among them, collagen membrane has been most widely used. However, its high price and weak tensile strength in wet condition are limitations for wide clinical application. Synthetic polymers have also been used for the GBR technique. Recently, silk based membrane has been considered as a membrane for the GBR technique. Despite many promising preclinical data for use of a silk membrane, clinical data regarding the silk membrane has been limited. However, silk based material has been used clinically as vessel-tie material and an electrospun silk membrane was applied successfully to patients. No adverse effect related to the silk suture has been reported. Considering that silk membrane can be provided to patients at a cheap price, its clinical application should be encouraged.

A Study on the Dyeing Properties of Silk Fabrics Dyed with Impatiens balsamina extract (봉선화 추출액을 이용한 견직물 염색)

  • 장재철;김애순
    • Textile Coloration and Finishing
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    • v.15 no.1
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    • pp.1-7
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    • 2003
  • To study the dyeability(ΔE value) and color depth of silk fabrics dyed with Impatiens balsamina extracts. its flower, leaf and stem was extracted by water. This paper investigated some experiments under the various dyeing conditions such as dyeing temperature, dyeing time, repetition of dyeing, dyeing pH with silk fabrics dyed with Impatiens balsamina extracts. The results obtained were as follows 1. It was found that $\lambda_{max}$ of silk fabrics dyed with Impatiens balsamina extract was 260nm and its flower, leaf , stem and different colored flower(white, pint violet) had same $\lambda_{max}$ at 260nm. 2. $\Delta{E}$ values were increased when dyeing temperature, repetition of dyeing and time was higher, value of munsell of silk fabrics dyed with Impatiens balsamina extract was Yellow-Red. But dyeing temperature, repetition of dyeing and time was higher, shifted to longer wavelenth side. 3. Silk fabric dyed with Impatiens balsamina extracts at acidic pH was colored reddish Yellow-Red, alkali bath colored yellowish Yellow-Red in silk fabrics dyed with Impatiens balsamina extract.

Setting Properties of Disulfide-Crosslinked Silk Fiber (Disulfide 가교 견섬유의 Set 성)

  • ;;M. Sakamoto
    • Textile Coloration and Finishing
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    • v.1 no.1
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    • pp.1-6
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    • 1989
  • The reaction of silk with a disulfide-containing crosslinking agent, i.e. bis($\beta$-isocyanatoethyl)disulfide(BIED), was studied in an attempt to obtain disulfide-crosslinked silk. The setting properties of disulfide-crosslinked silk fibers were studied. The permanent set values of single fibers were evaluated after the set fibers were relaxed in boiling water. When single fibers were set in boiling water or in boiling alkaline solution, the permanent set values of BIED-treated silk fibers were less than those of untreated silk fibers. When the fibers were treated with 2% thioglycolic acid solution at $60^\circ{C}$ followed by oxidation, settability of BIED-treated silk was better than that of untreated silk. The rearrangement of secondary bonds faciliated by cleavage of crosslinks as well as the rearrangement of crosslinks itself seems to be an important role in the set stability.

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The Problem of the Conservation of the Paintings on the Silk - Lining paper - (견본회화 보존수리에 있어서의 문제점 - 배접지 -)

  • Park, Chi sun
    • Journal of Conservation Science
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    • v.5 no.2 s.6
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    • pp.57-64
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    • 1996
  • Korean Paintings have been drawn on in the main two types of support material - paper and silk. In these things, silk designates picture silk, that of a specially weaved textile for painting since CHO-SUN dynasty, different such as hemp, ramie have been started to use for support material In addition to picture silk. However the structure of hemp and ramie are so close and progue, They are not proper to express the technique of pigments on the back of the paintings. On the other hand, picture silk is efficacious in pigments on the back of the painting with its interval between the strands and translucent textile. As the result, paintings on the silk has many - sided techniques as compared with painting on the papers therfore various devices in conservation have to be considered to deal with the techniques. In this report the focus is on classifying the method of removing the Lining paper according to the several types of expression technique of paintings on the silk.

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