• Title/Summary/Keyword: silicone oils

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Relation between the Dipole Orientation and the Degree of Polymerization in Low Viscous Silicone Oils (저점도 실리콘유의 쌍극자 배향과 중합도의 관계)

  • Cho, Kyung-Soon;Kim, Kyung-Hwan;Kim, Wang-Kon;Hong, Jin-Woong
    • Proceedings of the KIEE Conference
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    • 1993.11a
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    • pp.234-236
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    • 1993
  • Dielectric properties of low viscous silicone oils have been investigated as a function of frequency and The increase of polymerization degree was attributed to presence of Si-O-Si bonds and their increased dissociation factor. The application of the Clausius-Mosotti equation on the low viscous silicone oils, it has been previously assumed that the oils were dilute solutions of polar molecules. In the silicone oil the Si-o and O-Si bonds give dipole polarization. Simple relations have been found which dipole moment and activation energy as a function of number of Si atoms in the low viscous silicone oils.

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The Electrical Conduction Characteristics of Silicone oils due to Viscosity Variation (점도변화에 따른 실리콘유의 전기전도특성)

  • 조경순;홍진웅;신종열;이충호;이수원
    • Electrical & Electronic Materials
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    • v.10 no.9
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    • pp.945-951
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    • 1997
  • Inorder to investigated electrical conduction characteristics of silicone oils due to viscosity variation we studied the electrical conduction properties at temperature range of 10~110[$^{\circ}C$] and electrical field from 1 to 1.33$\times$10$^4$[V/cm] The viscosity of used specimens was low viscous(1, 2, 5[cSt]) silicone oils. It was shown the ohmic conduction characteristics in low temperature and low field by Ion dipole and humidity included specimen. And we known the conduction mechanism due to electron injection by Schottky's effect in the high temperature an d high field region.

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Dielectric loss of silicone oils for insulation due to the increase of viscosity (점도증가에 따른 절연용 실리콘유의 유전손실)

  • 이용우;조경순;김왕곤;홍진웅
    • Electrical & Electronic Materials
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    • v.8 no.5
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    • pp.587-593
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    • 1995
  • Silicone oils used insulating substances exhibit the both of organic and inorganic properties, and it has many superior characteristics such as the high thermal resistance and low thermal oxidation level when compared to other insulation oils. In order to investigate the dielectric loss due to the increase of viscosity, silicone oils of viscosity 1, 2, 5[cSt] had been chosen as the specimen and experiment has been performed in the temperature range of -70[.deg. C] - 65[.deg. C] and frequency range of 30 - 1*10$\^$5/[Hz]. As a result, the linear decrease of loss at low frequency region in high temperature was due to the influence of applying frequency, whereas the increase of loss at high frequency region was contributed by electrode's resistance. And increasing viscosity, the activation energy increased from 3.77[kcal/mole] to 7.21[kcal/mole]. The dipole moment of specimen was become clear 1.48 - 2.26[debyel in high temperature region(5 - 65[.deg. C]) and 1.05 - 1.80[debye] in low temperature region (-70 - -25[.deg. C])respectively.

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Dielectric Properties of Low Viscosity Silicone Oils with Degree of Polymerization (중합도에 따른 저점도 실리콘유의 유전 특성)

  • Cho, Kyung-Soon
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.27 no.12
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    • pp.847-851
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    • 2014
  • The characteristics of dielectric constant and $tan{\delta}$ of low viscosity silicone oils with changing degree of polymerization were investigated. The result shows dipole loss mechanism at low temperature range. The dielectric loss in the range of low frequencies are predominantly of ionic nature with temperature increase. The peak of dielectric loss is the detrapping of the electrons which is were trapped in the localized level of the silicone oils at the frequency of 30 kHz. The increase of ionic conduction is attributed to the presence of ionizable oxidation products and their increased dissociation feature. The activation energy ${\Delta}H$ and dipole moment ${\mu}_d$ were increased whit increasing degree of polymerization.

Dielectric Characteristics due to BTA in Insulating Liquids for the Ignition Coil of Automobile (자동차 점화장치용 절연유의 BTA 함유에 따른 유전특성)

  • 신종열;조돈찬;조경순;이수원;홍진웅
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 1997.04a
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    • pp.253-256
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    • 1997
  • Recently, mixture insulating oils is widely used in respect that the physical and the electrical properties is more excellentthan mineral oils, such as alkylbenzene oils and silicone oils, and that cost is lower than alkylbenzene oils or silicone oils. Also, it is important to research for the additive BTA(Benzotriazole) as a study for the phenomena of streaming electrification of mineral oils. So, mixture insulating oils class 7-2, is selected as a specimen in this experiments, and the contents of BTA in specimen are 0.2[ppm], 10[ppm] and 30[ppm], respectively. Then, the physical and the electrical properties for each specimen is made researches.

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Effects of Added Silicone Oils on the Surface Hydrophobicity of Silicone Rubber (실리콘 고무의 소수성에 미치는 첨가된 실리콘 오일의 영향)

  • Han Dong-Hee;Cho Han-Goo;Kang Dong-Pll;Min Kyung-Eun
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.19 no.1
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    • pp.46-51
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    • 2006
  • This paper reports on the effects of silicone oils, used as processing agents, on the recovery of hydrophobicity of silicone rubber. The recovery of hydrophobicity was evaluated by the measuring the contact angle, the surface electrical resistance and SEM. Here, we formed artificial contamination on the surface of samples, which scratched by sand papers and alumina powders. There was small recovery of hydrophobicity on the surface of SIR-A that silicone oil was not added. In both oil-added samples, SIR-B and SIR-C, recovery of hydrophobicity was achieved greatly. The surface of SIR-C showed that a lot of silicone oil was observed due to migration of oil, relatively in comparison with SIR-B. The tendency of recovery of hydrophobicity expressed by contact angle was in a good agreement with electrical property as determined by surface resistivity.

Surface Characteristics of Silicone Rubber Processes by Corona Discharges (코로나 방전에 따른 실리콘 고무의 표면 특성)

  • 한동희;조한구;강동필;민경은
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.15 no.2
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    • pp.133-140
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    • 2002
  • This paper aims to investigate the effect of silicone oils as processing agent affecting the loss and recovery of hydrophobicity. The recovery of hydrophobicity was evaluated by the measurement of the surface electrical resistivity and the contact angle on the SIR surface. Two kinds of silicone oils (1 and 2) having different molecular weight were selected under a consideration of hydrophobicity and processability. SIR specimens were exposed to corona discharges in air and the specimens were analyzed with contact angle and surface resistance measurements. It was observed that the contact angle and the surface resistivity of SIR increase gradually with testing time. The fast recovery of hydrophobicity of SIR, expressed by the increment of contact angle and surface resistivity, was showed in SIR2 containing silicone oil 2.

A Study of the relationship between partition coefficients of oils and antimicrtobial effects (파라벤류에 대한 오일의 분배계수와 실제 방부력과의 상관관계 연구)

  • 한종섭;김종일
    • Journal of the Society of Cosmetic Scientists of Korea
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    • v.21 no.2
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    • pp.94-111
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    • 1995
  • In this study, the relationship between partition coefficients(Kw) of oils and antimicrobial effects Ivas investigated. The antimicrobial activity of paraben has been known to be controlled by the concentration of the paraben in the aqueous phase. The concentration of paraben in the aqueous phase was measured by the UV/VIS spectrophotometer at the wavelength of 256nm. It was found that the hydrocarbon oils and silicone oils had the lowest Kw value(<1.0) among the tested oils. Also, the emulsions which were made of oils having low Kw values had a good antimicrobial effects. Thus, the cosmetic safety against microorganisms could be improved by using the oils which have low Kw values.

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Storage Effectiveness of Deep-Fried Potato Chip Prepared with Canola Oil Fortified with TBHQ and Silicone (Potato Chip 제조시 TBHQ 와 Silicone 첨가유에 의한 저장 연장 효과)

  • Jung, Byoung-Doo;Rhee, Soon-Jae
    • Korean Journal of Food Science and Technology
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    • v.29 no.4
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    • pp.635-640
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    • 1997
  • The oxidative stability of the potato chip prepared with canola oil fortified with antioxidnats was studied to explore the possibility of substituting it for imported frying fats and oils. BHT, BHA, TBHQ and silicone were added to the oil at a level of 0.02% and 10 ppm, respectively. Potato chip samples were prepared in a commercial scale and stored at $25.0{\pm}0.5^{\circ}C$ for 5 months. The oxidative stability of the extracted oils from potato chips during storage was estimated on the basis of some their physico-chemical changes, such as acid values, peroxide values, iodine values, ansidine values, fatty acid composition of the oils. An organoleptic test for the flavor of the samples was also performed. The oxidative stability of the samlpes was estimated on the basis of the changes of the parameter values. The effectiveness of the antioxidants was in the order of canola oil+TBHQ (0.02%)+silicone (10 ppm) > canola oil+TBHQ (0.02%) > canola oil+BHA (0.02%)+silicone (10 ppm) > canola oil+BHT (0.02%)+silicone (10 ppm) > canola oil+BHA (0.02%) > canola oil+BHT (0.02%) > canola oil. The antioxidant effect of canola oil+TBHQ (0.02%)+silicone (10 ppm) was more salient than any other antioxidant used in the potato chip.

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Hydrophobicity and tracking resistance of SIR for outdoor Insulators (초고압 옥외용 실리콘 고무의 발수성 및 트래킹 특성)

  • Han, D.H.;Kang, D.P.;Park, H.Y.;Lee, K.H.;Lee, K.C.;Min, K.E.
    • Proceedings of the KIEE Conference
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    • 2000.07c
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    • pp.1560-1562
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    • 2000
  • The paper reports on a study of the influence of the silicone oils on the tracking and erosion resistance and hydrophobicity of SIR. Two silicone oils(A, B) having different chemical structure were selected in consideration of goof hydrophobicity and processability. Tracking and erosion resistance of SIR was investigated by the rotating wheel dip test (RWDT). In this test tracking and erosion areas due to glow and partial arc discharges cause an increase in the leakage current with an increase in time. Leakage current of SIR was decreased with increasing ratio of oil A/B. SIR was exposed to corona discharges in air and the specimens were analyzed with contact angle. It was observed that the contact angle of SIR was increased gradually in time. The recovery of hydrophobicity was increased with increasing ratio of oil A/B.

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