• Proceedings of the KIEE Conference
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• 1999.07d
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• pp.1602-1604
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• 1999

Crosslinked polyethylene/silane crosslinked polyethylene (XLPE/SXLPE) blends were prepared by a twin screw extruder and their water tree and crosslinking characteristics were investigated. The water tree characteristics of XLPE were improved by the addition of SXLPE, when samples were cross- linked only by the thermorolysis of DCP (dicumyl peroxide). However, steam curing process was not good for water tree characteristics. It was also found that the degree of crosslinking of XLPE/SXLPE blends were higher than that of XLPE.

• Elastomers and Composites
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• v.44 no.2
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• pp.134-142
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• 2009

Organo bifunctional silane (TESPD) is added into silica containing NR and its effects are investigated with respect to the vulcanization properties, the processability, and the physical properties. The addition of the TESPD into silica filled NR compound increases the degree of crosslinking by formation of a strong 3-dimensional network structure with silica surface via coupling reaction, which results in an improved mechanical property. It also improves the processabilities compared to the Control compound.

• Elastomers and Composites
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• v.44 no.3
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• pp.252-259
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• 2009

Bifunctional silane (TESPD) is added into silica filled SBR compound and its effects with respect to the vulcanization properties, the processability, and the physical properties are investigated. The addition of the TESPD into silica filled SBR compound increases the degree of crosslinking by formation of a strong 3-dimensional network structure with silica surface via coupling reaction, which results in an improved mechanical property. It also improves the processabilities compared to the Control compound.

• Elastomers and Composites
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• v.52 no.4
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• pp.280-286
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• 2017

The mechanical and dynamic properties according to the content of filler, plasticizer, and crosslinking agent of rubber composites for Lipseal were measured in this study. The mechanical properties of the composite including the silane coupling agent and silica were found to be superior to those of the composite containing carbon black. It was found that the rebound resilience characteristics were influenced by the crosslink density of sulfur rather than the filler or plasticizer. In the case of recovery, it was confirmed that the elastic restoring force improved in the compression deformation condition and recovery increased as the crosslinking density increased. The rubber composite for Lipseal of this study is expected to improve the manufacturing technology of the rubber composite which can implement the optimum function for recognizing the performance such as oil resistance, durability and compression set.

• Journal of the Korean Institute of Electrical and Electronic Material Engineers
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• v.13 no.5
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• pp.420-425
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• 2000

Crosslinked polyethlyene/silane crosslinked polyethylene(XLPE/SXLPE) blends were prepared by a twin screw extruder and their water tree growing electrical breakdown and crossinking characteristics were investigated. The water tree characteristics of XLPE were improved by the addition of SXLPE when samples were crosslinked only by the thermorolysis of DCP (dicumyl peroxide). However steam curing process was not good for water tree characteristics. It was also found that the rate of water tree growing of XLPE/SXLPE blend increased when the content of SXLPE was 50%. AC breadown strength slightly increaed by the addition of SXLPE to XLPE when samples were crosslinked only by the thermorolysis of DCP. It was also found that the degree of crosslinking of XLPE/SXLPE blends were higher than that of XLPE in the case of the content without steam crosslinking process.

• Elastomers and Composites
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• v.47 no.1
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• pp.23-29
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• 2012

The silica-silica interaction parameter (${\alpha}_F$) of the silane treated silica filled natural rubber (NR) compound was investigated. As silane (TESPT) concentration increased from 2 to 12% (2, 4, 6, 8, 10, 12%), the ${\alpha}_F$ value increased at the same silica concentration (10, 20, 30, and 40 phr). It seemed the sulfur atoms in TESPT acted as a crosslinking agent in the compound. As silica concentration increased from 10 to 40 phr, the ${\alpha}_F$ value increased at the same silane concentration due to increased silica-silica interaction.

• Polymer(Korea)
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• v.36 no.4
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• pp.525-530
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• 2012

In this study, silane-crosslinked organic/inorganic composite membranes were prepared by simultaneous irradiation grafting of binary monomer mixtures (styrene and 3-(trimethoxysilyl)propyl methacrylate (TMSPM)) with various compositions onto a poly(ethylene-alt-tetraethylene) (ETFE) film and followed by sol-gel processing and sulfonation to provide a silane-crosslinked structure and a proton conducting ability, respectively. The Fourier transform infrared spectroscopy (FTIR) and thermo gravimetric analysis (TGA) were utilized to confirm the crosslinking of ETFE-g-PS/PTMSPM films. The prepared membranes with similar ion exchange capacity but a different TMSPM content were selected and their membrane properties were compared. The ETFE-g-PSSA/PTMSPM membranes were characterized by water uptake, dimensional stability, and proton conductivity after sulfonation. The membrane electrode assemblies (MEA) of the prepared membranes were fabricated and their single cell performances were measured.

• Elastomers and Composites
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• v.22 no.3
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• pp.204-212
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• 1987

The purpose of this study is to investigate the reinforced effect between MGF treated silane coupling agents and rubber matrix under the configuration chemical bonds, also the effect of triazine thiol compounds. For this study, vulcanizates were prepared with fifteen different compounding formulas. Their vulcanization characteristics, physical properties were examined by means of the ODR(Oscillating Dist Rheometer), the tensile tester, the benzene swelling test. The results of this study obtained are as follows: 1. In the ODR test, the MA vulcanizate was the fastest one in terms of having reached to optimum cure time($t_{90}$) and, with the same formula, when MGF vulcanizates, the shortest optimum cure times has appeared. 2. The SA, SC vulcanizates were the best the other in the physical properties such as 100%modulus, 200%modulus, 300%modulus, tensile strength. The SB vulcanizate, with higher density of crosslinking than other vulcanizates. The vulcanizates, which were filled with MGF treated with silane coupling agents we were the higher density of crosslinking than vulcanizates filled with MGF only. 3. In aging properties, the silica vulcanizates appeared to be better than the other vulcanizates. The aging Properties of treated MGF vulcanizates were similar to the silica vulcanizates. The(CR+APS+silica) and(CR+APS+MCF) were easily crosslinked by exposure to the air, and the physical properties have been improved.

• Elastomers and Composites
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• v.46 no.1
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• pp.45-53
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• 2011

The effect of the silane coupling agent, bis(triethoxysilypropyl)tetrasulfide (TESPT), on mechanical properties of a silica-filled NBR compound for oilseal was investigated. Curing behavior and crosslinking density of the compounds were measured using ODR (oscillating disk rheometer) and swelling ratio in toluene. UTM (universal testing machine) and shore A hardness tester were used in order to study the characteristics of mechanical properties of original vulcanizates and aged ones with heated air and ASTM No. 3. oil. Recovery of elasticity which influences the performance and service life of oilseal was investigated by giving bending deformation to vulcanizates in aging condition. After bending aging test, recovery distance was measured and calculated angle of recovery from it. TR (temperature retraction) test was performed on these vulcanizates to determine the low temperature recovery behavior. Wear resistance was measured by Taber type abrasion tester. In addition, SEM was used to characterize the morphology of the worn surface of vulcanizates. The result showed that addition of TESPT into silica-filled compound improves not only compound flow-ability, interaction between NBR and silica and crosslinking density, but also hardness, 100% modulus, recovery of elasticity, wear resistance, heat resistance and ASTM No.3 oil resistance of vulcanizates.

• Polymer(Korea)
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• v.36 no.6
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• pp.816-821
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• 2012

In this study, silane-crosslinked proton exchange membranes were prepared by step-wise radiation grafting of styrene and 3-(trimethoxysilyl)propyl methacrylate (TMSPM) onto an poly(ethylene-co-tetrafluoroethylene) (ETFE) film and followed by sol-gel processing and sulfonation. The sequentially grafted films with styrene to provide the proton conductivity and TMSPM to form the crosslinked structure were prepared by different grafting order. The structural changes and thermal properties of the prepared films were investigated by FTIR and TGA, respectively. After the introduction of sulfonic acid functional groups, the distributions of sulfonic acid group and silicon atoms at the inside of the sulfonated membranes were analyzed by SEM-EDX.