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http://dx.doi.org/10.7473/EC.2012.47.1.023

Effects of Silane Concentration on the Silica-Silica Interaction Parameter (αF) of the Silica / Natural Rubber Compound  

Kim, Sung-Min (Dong Ah Tire & Rubber Co., Ltd.)
Jang, Mi-Kyeong (Department of Polymer Science and Engineering, Sunchon National University)
Choi, Chang-Yong (Department of Polymer Science and Engineering, Sunchon National University)
Nah, Jae-Woon (Department of Polymer Science and Engineering, Sunchon National University)
Kim, Kwang-Jea (Dong Ah Tire & Rubber Co., Ltd.)
Publication Information
Elastomers and Composites / v.47, no.1, 2012 , pp. 23-29 More about this Journal
Abstract
The silica-silica interaction parameter (${\alpha}_F$) of the silane treated silica filled natural rubber (NR) compound was investigated. As silane (TESPT) concentration increased from 2 to 12% (2, 4, 6, 8, 10, 12%), the ${\alpha}_F$ value increased at the same silica concentration (10, 20, 30, and 40 phr). It seemed the sulfur atoms in TESPT acted as a crosslinking agent in the compound. As silica concentration increased from 10 to 40 phr, the ${\alpha}_F$ value increased at the same silane concentration due to increased silica-silica interaction.
Keywords
${\alpha}_F$(measure of the in-rubber structure of the filler); silica / silane; silica structure; Wolff's theory; natural rubber(NR);
Citations & Related Records
Times Cited By KSCI : 5  (Citation Analysis)
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1 E. P. Plueddemann, "Silane Coupling Agents", 2nd Ed., Plenum Press, New York, 1982.
2 K. J. Kim and J. VanderKooi, "TESPT and Treated Silica Compounds on TESPT Rheological Property and Silica Break Down in Natural Rubber", Kautsch. Gummi Kunstst., 55, 518 (2002).
3 R. K. Gupta, E. Kennal, and K. J. Kim, "Polymer Nanocomposites Handbook", CRC Press, Boca Raton, 2009.
4 K. J. Kim and J. L. White, "TESPT and Different Aliphatic Silane Treated Silica Compounds Effects on Silica Agglomerate Dispersion and on Processability During Mixing in EPDM", J. Ind. Eng. Chem., 7, 50 (2001).   과학기술학회마을
5 L. P. Ziemansky, C. A. Pageno, and M. W. Ranney, Rubber World, 163, 53 (1970).
6 M. W. Ranney and C. A. Pagano, "Silane Coupling Agent Effects in Ethylene Propylene Diene Terpolymers", Rubber Chem. Technol., 44, 1080 (1971).   DOI
7 M. W. Ranney, G. M. Cameron, and B. W. Lipinsky, Kautsch. Gummi. Kunstst., 26, 405 (1973).
8 G. M. Cameron, M. W. Ranney, and K. J. Sollman, Eur. Rubber J., 56, 37 (1974).
9 F. Thurn and S. Wolff, "Neue Organosilane fur die Reifenindustrie", Kautsch Gummi Kunstst., 28, 733 (1975).
10 S. Wolff, "Reinforcing and Vulcanization Effects of Silane Si 69 in Silica-Filled Compounds", Kautsch. Gummi Kunstst., 34, 280 (1981).
11 S. Wolff, Kautsch. Gummi. Kunstst., 22, 367 (1969).
12 S. Wolff, Kautsch. Gummi. Kunstst., 23, 7 (1970).
13 A. R. Payne and R. E. Whittaker, "Low Strain Dynamic Properties of Filled Rubbers", Rubber Chem. Technol., 44, 440 (1971).   DOI
14 A. R. Payne, Rubber Plast. Age, 42, 963 (1961).
15 S. Lee and N. C. Park, "The Study on Physical Properties of Rubber Compounds with Silica Doped Carbon Black", Elastomer, 33, 44 (1998).   과학기술학회마을
16 H. M. Costa, L. L. Y. Visconte, R. C. R. Nines, and C. R. G. Furtado, "Rice-Husk-Ash-Filled Natural Rubber. II. Partial Replacement of Commercial Fillers and the Effect on the Vulcanization Process", J. Appl. Polym. Sci., 87, 1405 (2003).   DOI   ScienceOn
17 S. Wolff, "Chemical Aspects of Rubber Reinforcement by Fillers", Rubber Chem. Technol., 69, 325 (1996).   DOI
18 A. N. Gent, "Engineering with rubber: how to design rubber components", 2nd Ed., Hanser, Munich, 2001.
19 S. Wolff, Kautsch. Gummi Kunstst., 36, 969 (1983).
20 S. Wolff and M. J. Wang, "Filler-Elastomer Interactions. Part IV. The Effect of the Surface Energies of Fillers on Elastomer Reinforcement", Rubber Chem. Technol., 65, 329 (1992).   DOI
21 A. Hunsche, U. Gorl, A. Muller, M. Knaack, and Th. Gobel, "Investigations Concerning the Reaction Silica/Organosilane and Organosilane/Polymer, Part 1: Reaction Mechanism and Reaction Model for Silica / Organosilane", Kautsch. Gummi Kunstst., 50, 881 (1997).
22 K. J. Kim, "Amino Silane, Vinyl Silane, TESPD, ZS(TESPD/ Zinc Complex) Effects on Carbon Black/Clay Filled Chlorobutyl Rubber(CIIR) Compounds Part II: Effects on Soft Clay/Carbon Black Filled Compounds", Carbon Letters, 10, 109 (2009).   과학기술학회마을   DOI   ScienceOn
23 K. J. Kim and J. VanderKooi, "Zinc surfactant Effects on Processability and Mechanical Properties of Silica Filled Natural Rubber Compounds", J. Ind. Eng. Chem., 10, 772 (2004).   과학기술학회마을
24 K. J. Kim and J. VanderKooi, "Moisture Effects on TESPDsilica/ CB/SBR Compounds", Rubber Chem. Technol., 78, 84 (2005).   DOI
25 S. M. Kim, C. S. Nam, and K. J. Kim, "TMTD, MBTS, and CBS Accelerator Effects on Silica Filled Natural Rubber Compound upon Vulcanization Properties", Appl. Chem. Eng., 22, 144 (2011).
26 C. Y. Choi, S. M. Kim, Y. H. Park, M. K. Jang, J. W. Nah, and K. J. Kim, "Thiuram, Thiazole, and Sulfenamide Accelerators Effects on Silica Filled Natural Rubber Compound upon Vulcanization and Mechanical Properties", Appl. Chem. Eng., 22, 411 (2011).
27 J. L. White and K. J. Kim, "Thermoplastic and Rubber Compounds: Technology and Physical Chemistry", Hanser Publisher, Munich, 2008.
28 S. M. Kim and K. J. Kim, "Thiazole Type Accelerator Effects on Silane/Silica Filled Natural Rubber Compound upon Vulcanization and Mechanical Properties", Polymer(Korea), 36 (2011).   과학기술학회마을   DOI   ScienceOn
29 R. K. Iler, "The Chemistry of Silica", John Wiley & Sons, New York, 1979.