• Title/Summary/Keyword: side chain length distribution

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Molecular Structure of Sorghum and Waxy Sorghum Starches

  • Han, Young-Joo;Park, Jong-Tae;Le, Quang Tri;Shim, Jae-Hoon;Nguyen, Van Dao;Kim, Yong-Ro;Park, Kwan-Hwa
    • Food Science and Biotechnology
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    • v.17 no.1
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    • pp.176-179
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    • 2008
  • Amylose contents and amylopectin chain architecture of sorghmn and waxy sorghum starches were determined and compared with those of other common cereal and tuber starches. Also, in vitro digestibility of sorghum starch was estimated using a novel methodology. The absolute amylose content of sorghum starch was similar to that of com and wheat starches. The side chain length distribution patterns for sorghum and waxy sorghum amylopectin were very similar to those of com and waxy com, respectively. The $k_{cat}/K_m$ values for sorghum and potato amylopectin did not show a significant difference. The kinetic parameters could be used as novel indicators for starch digestibility.

Structural Analysis of Conductive Polypyrroles Synthesized in an Ionic Liquid

  • Song, Eun-Ah;Jung, Woo-Gwang;Ihm, Dae-Woo;Kim, Jin-Yeol
    • Bulletin of the Korean Chemical Society
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    • v.30 no.5
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    • pp.1009-1011
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    • 2009
  • Nano-structured conducting polypyrroles were synthesized in the ionic liquids (ILs) based on 1-alkyl-3-methylimidazolium family with tetrachloroferrate as an anion ($C_n\;mim\;[FeCl_4]\;with\;n\;=\;4,\;8,\;and\;12$). The polypyrrole nanostructures synthesized in ILs were formed as spherical shapes. For ionic liquids with alkyl side chain length $C_4,\;C_4\;mim\;[FeCl_4]$, the size of particles was ranged around 60-nm with a relatively narrow size distribution. As the length of alkyl chain increases, the particle sizes become larger and their distributions become wider. The self-assembled local structures in the solvent ionic liquids are likely to serve as templates of highly organized nano-structured polymers. The length of the alkyl chain in ionic liquids seems to affect these local structures.

Glycogen Metabolism in Vibrio vulnificus Affected by malP and malQ

  • Han, Ah-Reum;Lee, Yeon-Ju;Wang, Tianshi;Kim, Jung-Wan
    • Microbiology and Biotechnology Letters
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    • v.46 no.1
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    • pp.29-39
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    • 2018
  • Vibrio vulnificus needs various responsive mechanisms to survive and transmit successfully in alternative niches of human and marine environments, and to ensure the acquisition of steady energy supply to facilitate such unique life style. The bacterium had genetic constitution very different from that of Escherichia coli regarding metabolism of glycogen, a major energy reserve. V. vulnificus accumulated more glycogen than other bacteria and at various levels according to culture medium and carbon source supplied in excess. Glycogen was accumulated to the highest level in Luria-Bertani (3.08 mg/mg protein) and heart infusion (4.30 mg/mg protein) complex media supplemented with 1% (w/v) maltodextrin at 3 h into the stationary phase. Regarding effect of carbon source, more glycogen was accumulated when maltodextrin (2.34 mg/mg protein) was added than when glucose or maltose (0.78.1-14 mg/mg protein) was added as an excessive carbon source to M9 minimal medium, suggesting that maltodextrin metabolism might affect glycogen metabolism very closely. These results were supported by the analysis using the malP (encoding a maltodextrin phosphorylase) and malQ (encoding a 4-${\alpha}$-glucanotransferase) mutants, which accumulated much less glycogen than wild type when either glucose or maltodextrin was supplied as an excessive carbon source, but at different levels (3.1-80.3% of wild type glycogen). Therefore, multiple pathways for glycogen metabolism were likely to function in V. vulnificus and that responding to maltodextrin might be more efficient in synthesizing glycogen. All of the glycogen samples from 3 V. vulnificus strains under various conditions showed a narrow side chain length distribution with short chains (G4-G6) as major ones. Not only the comparatively large accumulation volume but also the structure of glycogen in V. vulnificus, compared to other bacteria, may explain durability of the bacterium in external environment.

Physical Properties of Water-Based Acrylic Adhesives According to Main Monomers with Different Side Chain Types (서로 다른 측쇄 종류를 가진 주 단량체에 따른 수성 아크릴계 점착제의 물리적 특성)

  • Shin, Hye-rin;Kim, Yu-ri;Kim, Kyung-sil;Park, Jong-kwon
    • Journal of the Korean Applied Science and Technology
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    • v.37 no.6
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    • pp.1627-1634
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    • 2020
  • In this study, water-based acrylic adhesives as copolymers with acrylic acid, 2-hydroxyethyl acrylate were synthesized using ethyl acrylate, 2-ethylhexyl acrylate, and lauryl methacrylate as the main monomers. Prepared water-based acrylic adhesive was compared to physical properties such as solid content, average particle size distribution, initial adhesive force, maximum adhesive force, peel strength, and heat resistance.

A Study about the Relation of Product Environment and Supply Chain Structure (환경과 공급체인 구조와의 관계에 관한 연구)

  • 문성암;곽신영;박성훈
    • Journal of Distribution Research
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    • v.7 no.1
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    • pp.41-59
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    • 2002
  • Analysis about supply chain structure was achieved in product unit that is not 'business' dimension that is existent discussion target in surrounding and supply chain structure as that this study analyzes positively how supply chain structure according to business surroundings of product changes. This can do that analysis of product unit in synthetic supply chain management is essential when recognize the importance that supply chain management must consist by product special quality according to corporation's each product. Sort product environment and studied relation with supply chain structure to achieve study purpose hereupon. Structure variable of supply chain drew through existent literature study here. Executed question investigation for supply chain by product for study that is actual proof enemy, and figure method used analysis of variance (ANOVA) mainly. If summarize result of study, result that analyze relation between business environment of product and supply chain structure, according to business environment of product, showed that supply chain structure changes. Certified that relation of two group (environment group of uncertain product and environment group of stable product) of business environment of product and structure variable (that is number of participant of supply chain, lead time of supply chain, about administration's independence, response points of supply chain) of supply chain is significant relation all from all structure variables except number of participant of supply chain. Variable that express length of supply chain from structure Variable of supply chain is number of participant of supply chain and lead time of supply chain, and variable that display monitoring or trust aspect for supply chain is administration's independence degree and response points of supply chain. As analysis result, product that environment is uncertain is appearing more shortly than product that length of supply chain stabilizes, and also, monitoring or trust aspect for supply chain was proved that is consisting abuzzer than product that stabilize. Therefore, showed that put essential point in administration of 'hierarchy'putting first than 'market' when business environment designs supply chain structure in case of uncertain product, and proved that the other side business environment is focusing in administration way of 'market' putting first in case of stable product.

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