• Bulletin of the Korean Chemical Society
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• 제21권12호
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• pp.1239-1244
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• 2000

A study of K addition to the catalyst of CoMo/ ${\gamma}-Al_2O_3$ was studied. The catalyst with 10 at% of K to Mo atoms in 3C10M, the catalyst added 3 wt% CoO to 10 wt% $MoO_3/{\gamma}-Al_2O_3$, showed the highest activity for water gas shift reaction. The addition of K retarded the reducibility of cobalt-molybdenum catalysts. It gave, however, good dispersion and large BET surface area to the catalysts which were attributed to the disappearance of polymolybdate clustyer such as $Mo_7O_{24}^{6-}$ and the formation of small Mo$O_4^{2-}$ cluster. It was confirmed by the analyses of pore size distribution, activation energy, Raman spectroscopy, and electron diffraction. The activation energies and the frequency factors of the catalysts 3C10M and 5KC10M (the catalyst added 5 at% K for Mo to the catalyst 3C10M) were 43.1 and 47.8 kJ/mole, and 4,297 and 13,505 $sec^{-1}$, respectively. These values were also well correlated with our suggestion. These phenomena were attributed to the direct interaction between K and CoMo oxides irrelevant to the support.

• Bulletin of the Korean Chemical Society
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• 제9권5호
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• pp.317-322
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• 1988

Premicellar precipitation, resolubilization and luminescing behaviors of $RuL_3^{2+}$ (L = bpy, phen, $Me_2bpy$) in aqueous alkylsulfate and sulfonate solutions were studied. Addition of the anionic surfactants to $RuL_3\;^{2+}$ solutions caused initial precipitation which was redissolved by further addition of the surfactants. The apparent solubility products $K_{sp}$'s of the precipitates were evaluated assuming 1:2 salt formation. The values were smaller as the ligand is more hydrophobic and the length of hydrocarbon chain of the surfactant is longer. The $K_{sp}$ values for L = bpy were constant over wide surfactant concentration range. However, those for L = $Me_2bpy$ and also for phen, but to less extent, increased with the surfactant concentration. The resolubilization of 1:2 salts was followed by red-shift of emission band and extensive emission quenching above critical concentration of the surfactants. The critical concentration was lower for more hydrophobic surfactant. For L = $Me_2bpy$, the blue-shifted emission band with enhanced emission intensity was observed in intermediate surfactant concentration region. The high ionic strength of media prevented the precipitate formation, but facilitated the red-shift of the emission bands. The results support that the precipitate is dissolved by accretion of surfactant anions to the salts to form water-soluble surfactant-rich $RuL_3$-surfactant anionic species. These species appeared to aggregate cooperatively to produce large clusters which exhibited the red-shifted emission.

• 한국신재생에너지학회:학술대회논문집
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• 한국신재생에너지학회 2010년도 춘계학술대회 초록집
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• pp.230.1-230.1
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• 2010

조촉매(Promotor)인 Na은 수성가스전이(Water Gas Shift, WGS) 반응 시 생성된 포름산염의 C-H결합을 쉽게 분해하는 역할을 한다. 본 연구에서는 $Pt/CeO_2$ 촉매의 성능 향상을 위해 Na의 담지량을 변화시켜 촉매적 활성을 비교하여 보았다. 제조된 담체는 침전법(Precipitation)을 사용하여 제조하였으며 $500^{\circ}C$에서 6시간 소성하였다. Pt 담지량은 1wt%로 고정하였고 Na 담지량은 1 wt%~5 wt%로 변화를 주어 동시(공)-함침법(Co-incipient wetness method)으로 담지 시켰다. 반응 실험은 공간속도(Gas Hourly Space Velocity, GHSV) $45,385h^{-1}$에서 수행하였다. WGS 반응 결과 3 wt%의 Na이 담지된 $Pt/CeO_2$ 촉매의 경우를 제외하고 나머지 Na이 담지된 촉매들은 비교적 높은 CO의 전환율을 나타내었다. 특히 2 wt%의 Na이 담지된 $Pt/CeO_2$ 촉매는 가장 높은 CO의 전환율을 나타내었다. 따라서 Na 담지량의 변화가 포름산염의 C-H결합 분해에 영향을 미친다는 것을 알 수 있다.

• Journal of Positioning, Navigation, and Timing
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• 제6권2호
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• pp.71-78
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• 2017

The sidereal day of a Global Positioning System (GPS) satellite was intended to equal one half of a sidereal day of the Earth. However, the sidereal day of GPS satellites has become unequal to one half of a sidereal day of the Earth. This is fundamentally caused by the non-sphericity of the Earth and the gravity of the Moon. The difference between sidereal days of GPS satellites and the Earth is known as a sidereal shift. The details surrounding sidereal shifts and their origins have yet to be fully understood. We calculated the periodicity of sidereal shifts for GPS satellites using broadcast ephemeris data. To conduct a periodic analysis of the sidereal shift, we employ the Lomb-Scargle periodogram method. It shows that the orbit periods of GPS satellites have small-amplitude perturbations with a 13.6-day period. In addition, we compare the GPS satellite orbit periods with the periodicity of geomagnetic indices and the solar wind parameters to identify the cause of the perturbations. Our results suggest that the solar wind stream might also affect the 13.6-day period of the sidereal shifts.

• Journal of Information Display
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• 제6권1호
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• pp.28-32
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• 2005

The electronic structures of Al/RbF/tris-(8-hydroxyquinoline)aluminium ($Alq_3$) and $Al/CaF_2/Alq_3$interfaces were investigated using x-ray photoelectron spectroscopy (XPS) and ultraviolet photoelectron spectroscopy (UPS). For both systems, the UPS showed a significant valence band shift following the deposition of the thin fluoride layers on $Alq_3$. However, the formation of gap state in valence region and the extra peak N 1s core level spectra showed different trends, suggesting that the alkali fluoride and alkali-earth fluoride interlayer have different reaction mechanisms at the interface between Al cathode and $Alq_3$. In addition, the deposition of Al has considerably less effect on the valence band shift compared to the deposition of both RbF and $CaF_2$. These results suggest that the charge transfer across the interface and the resulting gap state formation may have lesser effect on the enhancement of organic light-emitting device performance than the observed valence band shift, which is thought to lower the electron injection barrier.

• 한국수소및신에너지학회논문집
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• 제23권2호
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• pp.111-116
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• 2012

Na promoted Pt/$CeO_2$ catalysts with various Na amounts (1, 2, and 3wt%) have been applied to water gas shift reaction (WGS) at a gas hourly space velocity (GHSV) of 45515 $h^{-1}$. 1wt%Pt-2wt%Na/$CeO_2$ catalyst exhibited the highest WGS activity at $240^{\circ}C$ among the catalysts prepared in this study. In addition, 1wt%Pt-2wt%Na/$CeO_2$ catalyst showed relatively stable activity with time on stream. The high activity/stability of 1wt%Pt-2wt%Na/$CeO_2$ catalyst was correlated to its easier reducibility and higher oxygen storage capacity (OSC). As a result, 2wt% Na promoted Pt/$CeO_2$ can be a promising candidate catalyst for the single stage WGS, which requires high intrinsic activity at very high GHSV.

• 전기학회논문지P
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• 제67권2호
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• pp.82-89
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• 2018

This paper presents a novel prototype of dual mode control based phase shift ZVS PWM high frequency load resonant inverter with lossless snubber capacitors in addition to a single active auxiliary resonant snubber for electromagnetic induction heating(IH) foam metal based consumer fluid dual packs(DPA) heater. The operating principle in steady state and unique features of this voltage source soft switching high frequency inverter circuit topology are described in this paper. The lossless snubber and auxiliary active resonant snubber assisted constant frequency phase shift ZVS PWM high frequency load resonant inverter employing IGBT power modules actually is capable of achieving zero voltage soft commutation over a widely specified power regulation range from full power to low power. The steady state operating performances of this dual mode phase shift PWM series load resonant high frequency inverter are evaluated and discussed on the basis of simulation and experimental results for induction heated foam metal heater which is designed for compact and high efficient moving fluid heating appliance in the consumer pipeline systems.

• 한국진공학회:학술대회논문집
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• 한국진공학회 2011년도 제40회 동계학술대회 초록집
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• pp.257-257
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• 2011

The amorphous indium-gallium-zinc-oxide (a-IGZO) materials for use in high performance display research fields are strongly investigated due to its good performance, such as high mobility and better transparency. However, the stability of a-IGZO materials is increasingly becoming one of critical issues due to the sub-gap electron trap sites induced by rough interfaces during deposition processing. It is well-known that the threshold voltage shift is related to interface roughness and oxygen vacancy formed by breaking weak chemical bonds. Here, we report the better properties of transparent oxide transistors by reducing the threshold voltage shift with an external rf plasma supported magnetron sputtering system. Mainly, our sputtering method causes the surface of sample to be sleek, so that it prevents the formation of various defects, such as shallow electron trap sites in the interface. External rf power was applied from 0 to 50W during RF sputtering process to enhance the stability of our oxide transistor without having a large voltage shift. To observe the effects of external rf-plasma source on the properties of our devices, Scanning Electron Microscopy (SEM), Atomic Force Microscopy (AFM), Transmission Electron Microscopy (TEM) are carried out to observe surface roughness and morphology of sputtered thin film. In addition, typical electrical properties, such as I-V characteristics are analyzed.

• 한국광학회지
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• 제27권3호
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• pp.101-105
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• 2016

본 논문에서는 푸리에 변환의 위상천이 특성을 이용하여 기존의 계산방법보다 처리 속도가 빠르고, 이상적인 CGH의 재생이미지와의 차이가 크지 않은 Phase-only CGH의 새로운 최적화 계산방법을 제시한다. 기존의 수치적인 해를 얻는 접근과는 다르게 푸리에 변환 자체의 위상천이 특성을 이용하여 노이즈를 선택적으로 필터링하는 방법으로 Phase-only CGH를 얻기 때문에 계산속도를 현저하게 줄일 수 있다. 이상적인 CGH와 기존의 방법, 그리고 새로운 계산방법을 통한 CGH를 시뮬레이션을 통하여 각각 SLM에 저장하여 수렴렌즈를 이용한 푸리에 홀로그램 방식으로 이미지를 재생하였다. 그리고 시뮬레이션 재생 이미지를 비교하여 본 연구의 타당성을 살펴보았다. 기존의 방법과 비교하였을 때, 이미지 물체의 질감과 예리도가 이상적인 CGH와 비슷한 정도의 수준으로 향상되었고, 계산속도 또한 크게 줄었음을 알 수 있다.

• 한국통신학회논문지
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• 제25권6B호
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• pp.1100-1105
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• 2000

현대의 레이더 펄스 압축기술로 가장 널리 사용되고 있는 방식은 바커코드를 사용하여 matched filter로 레이더 신호를 처리하는 상관처리(correlation processing)이다. 그러나 이 방식의 경우 탐지 감도를 높여 주는 장점이 있지만, 환경에 따라서 range-sidelobe가 발생하여 레이더의 성능을 낮추게 된다. 본 논문에서는 상관처리방식에 추가적인 처리로 sidelobe를 제거하는 최적처리 방법을 제안하고 Doppler shift가 존재할 때의 성능을 평가한다. 그리고 제안된 알고리즘 환경에서 최적의 이진 코드를 개발하고 이를 Barker 코드를 사용한 전통적인 상관처리방식의 경우와 비교.분석한다. 도플러 변이가 존재할 때, 최적 코드를 사용하여 최적 처리하는 방식이 바커코드를 사용한 전통적인 처리방법보다 레이더의 성능을 향상시킴을 보여줄 것이다.