• 한국결정성장학회지
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• 제30권3호
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• pp.110-116
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• 2020

MLCC(Multi-Layer Ceramic Capacitor)의 유전체 층에 사용되는 BaTiO₃ 입자는 안정한 TCC(Temperature Characteristics of Capacitance) 거동을 갖기 위해 core/shell 구조를 갖는다. 지금까지 shell의 특성은 core/shell 구조의 전체 특성에서 유추해 왔다. 이는 core/shell 구조가 겨우 수 ㎛의 작은 크기로 shell 특성만 구별해서 측정하기가 어렵기 때문이다. 본 실험에서는 micro-contact법을 이용하여 확산쌍 시편의 계면에 형성된 확대된 core/shell 구조에 Pt 전극을 증착하여 35~135℃ 에서 shell 영역의 독립적인 TCC 거동을 측정하였다. 그 결과, 65℃에서 최대 유전율 값을 갖는 완만한 피크의 확산 상전이(Diffusion Phase Transition) 거동인 core의 특성과 구별되는 거동을 관찰하였으며, 이는 core/shell 구조의 온도-유전거동을 묘사하는 모델링에서 실험 자료로 활용될 것으로 본다.

• 한국소음진동공학회논문집
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• 제21권10호
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• pp.905-915
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• 2011

The free flexural vibration of a hanged clamped-free cylindrical shell partially submerged in water with gap from bottom is investigated. The fluid is assumed to be inviscid and irrotational. The cylindrical shell is modeled by using the Rayleigh-Ritz method based on the Sanders shell theory. The kinetic energy of the fluid is derived by solving the boundary-value problem related to the fluid motion. The natural vibration characteristics of the partially submerged cylindrical shell are discussed with respect to the added virtual mass approach. In this study, experiments were carried out to confirm theoretical results. It was found that theoretical prediction is in good agreement with experimental results.

• 한국소음진동공학회:학술대회논문집
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• 한국소음진동공학회 2003년도 춘계학술대회논문집
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• pp.153-156
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• 2003

Many researchers have tried to develop the piezoelectric shell element and verified them with the benchmarking problem of the piezoelectric bimorph beam since there is no experimental result for the control of shell structure with piezoelectric sensor/actuator. In this paper, the experiments are designed and performed to verify the control Performance of piezoelectric sensor/actuator on the shell structure. PVDF is easy to be attached on the surface of a shell structure but makes weak control forces. On the contrary, PZT makes control forces large enough to control the structure, but it is not easy to make a PZT element with curvature. To use PVDF as an actuator, the structure should be designed as flexible as possible and the voltage amplifier could make high control voltage. PVDF actuator powered by a voltage amplifier that generates output voltage from -200 to +200 volts, shows little control performance to control the vibration of an arch type shell structure. The performance of sensor looks good and the negative velocity feedback control works perfectly. The actuator voltage seems to be too small to verify the control effect Quantitatively. An experiment with high voltage amplifier is scheduled to verify the control effect Quantitatively.

• Korean Chemical Engineering Research
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• 제46권3호
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• pp.529-534
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• 2008

생체복합재료인 참굴 (Crassostrea gigas) 패각은 생성되는 형태에 따라 정상패각과 재생패각으로 구분되었다. 산과 알칼리를 이용한 탈 석회화과정 및 단백질제거반응을 통해 재생패각 내에서 얻어진 유기막이 키틴 특성을 가지고 있음을 FT-IR (Fourier transform infrared spectrometer)과 XRD (X-ray Diffractometer)를 통해 확인하였다. 불용성단백질의 함량은 정상패각이 재생패각과 비교하여 두배 이상 이었던 반면 수용성단백질 2차구조는 재생패각의 경우 random과 같은 불규칙구조가 많은 부분을 차지하고 있음을 확인할 수 있었다. 수용성단백질의 아미노산 조성과 단백질 2차구조분석을 통해 재생패각의 탄산칼슘 합성전략을 분자수준에서 논의하였고 재생패각 형성과 관련된 생광물화 전략이 패각의 재료학적 특성에 미치는 결과로써 해석되었다.

• 한국응용과학기술학회지
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• 제26권1호
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• pp.74-79
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• 2009

The inorganic-organic composite particles with core-shell structure were polymerized by using styrene and potassium persulfate (KPS) as a shell monomer and an initiator, respectively. We studied the effect of surfactants on the core-shell structure of silicone dioxide/styrene composite particles polymerized in the presence of sodium dodecyl sulfate(SDS), polyoxyethylene alkylether sulfate (EU-S133D), and at none surfactant condition. We found that $SiO_2$ core / polystyrene(PS) shell structure was formed when polymerization of styrene was conducted on the surface of $SiO_2$ particles, and the concentration SDS and EU-Sl33D was $8.34{\times}10^{-2}mole/L$. The core-shell structure was confirmed by measuring the thermal decomposition of the polymer composite using thermogravimetric analyzer (TGA), and the morphology of the composite particles was characterized by transmission electron microscope (TEM).

• 한국소음진동공학회:학술대회논문집
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• 한국소음진동공학회 2004년도 추계학술대회논문집
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• pp.954-957
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• 2004

Based on the authors' previous work, where a geometric constraint handling technique for stiffener layout optimization problem using geometry algorithms was proposed, stiffener layout optimization to maximize natural frequencies of a curved three-dimensional shell structure was performed with a projection method. The original geometry of the shell structure was first projected on a two-dimensional plane, and then the whole optimization process was performed with the projected geometry of the shell except that the original shell structure was used for the eigenproblem solving. The projection method can be applied to baseline structures with a one-to-one correspondence between original and projected geometries such as automobile hoods and roofs.

• 한국세라믹학회지
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• 제45권11호
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• pp.750-754
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• 2008

The artificial aggregates with dense surface layer (shell) was fabricated and the dependence of water emission rate upon the shell structures was studied. The EAF dust containing many flux components and waste white clay with ignition loss of above 48% were used as for liquid phase and gas forming agents during a sintering process respectively. In addition, the shell structure was modified with various processes and the modification effect on water emission rate was analyzed. The pores under $10{\mu}m$ were found in the sintered artificial light aggregates and disappeared by incorporating to a bigger pore during re-sintering. The water emission rate in an initial step depended on a void content of aggregates filled in a bottle rather than a shell structure. But, after 7 days where the water emission of the aggregate with a shell is above 40%, the shell of aggregates suppressed the water emission. The core of aggregates was exposed and most shell was lost when crushed to smaller size so, the ability for suppressing water emission of the crushed aggregates decreased. The activation energy for the water emission was $3.46{\pm}0.25{\times}10^{-1}$J/mol for the most specimens showing that the activation energy is irrelevant to the pore size distribution and shell structure.

• 한국세라믹학회지
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• 제40권9호
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• pp.902-908
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• 2003

Au/TiO$_2$ core-shell 구조 나노 미립자가 졸-겔법에 의해서 제조되었고, TiO$_2$ shell의 형상과 결정성이 TEM과 UV-Vis. absorption spectrometer에 의해서 조사되었다. Au/TiO$_2$ core-shell 나노 미립자는 Au 콜로이드 에탄올 수용액 중에서 TOAA(Titanium Oxide Acethylacetonate)의 가수분해에 의해 합성될 수 있었다. Au 나노 미립자의 표면에 형성된 TiO$_2$ shell의 두께는 약 1 nm이었다. TiO$_2$ shell의 결정성을 조사하기 위하여. TiO$_2$가 피복된 Au 콜로이드 에탄올 용액에 254 nm의 자외선과 $^{60}$Co의 방사선을 조사하였다. Au 나노 미립자의 surface plasmon 현상은 방사선이 조사되었을 때만 나타났고, 이 결과로부터 TiO$_2$ shell은 비정질 상태임을 알 수 있었으며, Au의 분산성 향상을 위해 표면에 처리된 MUA(Mercaptoundecanoic Acid)층은 전자의 이동을 방해하는 장애물로 작용하지 않음을 확인할 수 있었다.

• 한국소음진동공학회:학술대회논문집
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• 한국소음진동공학회 2002년도 추계학술대회논문집
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• pp.529-534
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• 2002

The receptance method was applied for the analysis of a cylindrical shell with a curvaturated plate attached at the top of the shell. The boundary conditions of the shell considered here were clamped at the bottom and free at the top of the shell. Before the analysis of the shell/plate combined structure, the natural frequencies of the plate and the shell were calculated separately and then they were used in the calculation of the frequencies of the combined structure by the receptance method. The frequency equation of the combined structure was derived from the continuity condition at the junction of the shell and the plate. The frequencies for various curvature factors of the plate were presented and compared with those from ANSYS to show its validity of the present method.

• International Journal of Aeronautical and Space Sciences
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• 제7권1호
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• pp.106-117
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• 2006

The active vibration control of composite shell structure has been performed with the optimized sensor/actuator system. For the design of sensor/actuator system, a method based on finite element technique is developed. The nine-node Mindlin shell element has been used for modeling the integrated system of laminated composite shell with PVDF sensor/actuator. The distributed selective modal sensor/actuator system is established to prevent the effect of spillover. Electrode patterns and lamination angles of sensor/actuator are optimized using genetic algorithm. Continuous electrode patterns are discretized according to finite element mesh, and orientation angle is encoded into discrete values using binary string. Sensor is designed to minimize the observation spillover, and actuator is designed to minimize the system energy of the control modes under a given initial condition. Modal sensor/actuator for the first and the second mode vibration control of singly curved cantilevered composite shell structure are designed with the method developed on the finite element method and optimization. For verification, the experimental test of the active vibration control is performed for the composite shell structure. Discrete LQG method is used as a control law.