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Chemical Washing of PAH-Contaminated Soil with Cyclodextrins as a Main Surfactant: A Labscale Study (사이클로덱스트린을 이용한 PAH오염토양의 화학적 세정)

  • Sung Hyun Kwon;Daechul Cho
    • Journal of the Korea Academia-Industrial cooperation Society
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    • v.3 no.4
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    • pp.295-302
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    • 2002
  • PAHs (polycyclic aromatic hydrocarbons) deposited in soil are one of serious problems against sustainable land use. In this paper, chemical soil flushing in a packed sandy soil matrix using a natural surfactant, $\beta$-cyclodextrin (CD) was studied via a fluorescence spectroscopy and a dye labelling. The contaminants are lipophilic ring compounds- phenanthrene and naphthalene. Sand type and flushing intensity (rate and concentration) are chosen as important investigation variables. The removal efficiencies were proportional to flow rate, concentration, temperature of the flushing solution and voidity of the sand column. Initial sorption of the surfactant onto the soil matrix was found to be a key step while flow shear was more crucial in the latter steps. The residual portion of the surfactant, which was most likely to be due to the initial sorption, would not be so influential on this type of soil washing for long times. These results will be useful in future for pilot scale in situ washing and for establishing better soil washing strategy.

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Prediction of the flexural overstrength factor for steel beams using artificial neural network

  • Guneyisi, Esra Mete;D'niell, Mario;Landolfo, Raffaele;Mermerdas, Kasim
    • Steel and Composite Structures
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    • v.17 no.3
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    • pp.215-236
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    • 2014
  • The flexural behaviour of steel beams significantly affects the structural performance of the steel frame structures. In particular, the flexural overstrength (namely the ratio between the maximum bending moment and the plastic bending strength) that steel beams may experience is the key parameter affecting the seismic design of non-dissipative members in moment resisting frames. The aim of this study is to present a new formulation of flexural overstrength factor for steel beams by means of artificial neural network (NN). To achieve this purpose, a total of 141 experimental data samples from available literature have been collected in order to cover different cross-sectional typologies, namely I-H sections, rectangular and square hollow sections (RHS-SHS). Thus, two different data sets for I-H and RHS-SHS steel beams were formed. Nine critical prediction parameters were selected for the former while eight parameters were considered for the latter. These input variables used for the development of the prediction models are representative of the geometric properties of the sections, the mechanical properties of the material and the shear length of the steel beams. The prediction performance of the proposed NN model was also compared with the results obtained using an existing formulation derived from the gene expression modeling. The analysis of the results indicated that the proposed formulation provided a more reliable and accurate prediction capability of beam overstrength.

Production of Rosmarinic Acid, Lithospermic Acid B, and Tanshinones by Suspension Cultures of Ti-Transformed Salvia miltiorrhiza Cells in Bioreactors

  • Zhong, Jian-Jiang;Hui Chen;Feng Chen
    • Journal of Plant Biotechnology
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    • v.3 no.2
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    • pp.107-112
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    • 2001
  • The kinetics of Ti-transformed Salvia miltiorrhiza cell cultures was studied in 250-$m\ell$ shake flasks by using B5 medium with addition of 30 gfL of sucrose. In the cell cultures, the maximum cell mass obtained was 11.5 g DW/L on day 15. The highest amount of phenolic compounds - rosmarinic acid (RA) and lithospermic acid B (LAB) reached 871.3 mg/L (day 15) and 121.3 mg/L (day 13), respectively. The total tanshinone production, i.e., intracellular plus extracellular cryptotanshinone, tanshinone 1, and tanshinone IIA, was 5.3 mg/L on day 13. For the cultivations in 2.4-L stirred bioreactors, the residual sugar level and medium conductivity were a little higher in a small turbine impeller reactor ($T_s$) than those in a large turbine impeller reactor ($T_L$), while a higher cell density was obtained in the $T_L$. For the production of tanshinones and phenolics, better results were obtained in the $T_L$ than in the $T_s$. In the $T_L$, similar or even a little higher production titers of tanshinones and phenolic compounds were achieved compared to those in the flasks. The results suggest that the shake flask results could be successfully scaled up to the $T_L$ reactor. Such a large impeller reactor like $T_L$ may be better than a small impeller one for the large-scale production of the valuable metabolites by the suspension cultures of Ti transformed S.miltiorrhiza cells. This is considered due to the beneficial culture environment in the $T_L$, such as low shear rates as estimated theoretically.

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Nonlinear Dynamic Behaviors of Laminated Composite Structures Containing Central Cutouts (중앙개구부를 갖는 복합신소재 적층 구조의 비선형 동적 거동)

  • Ji, Hyo-Seon;Lee, Sang-Youl
    • Journal of Korean Society of Steel Construction
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    • v.23 no.5
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    • pp.607-614
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    • 2011
  • This study deals with thegeometrical nonlinear dynamic behavior of laminated plates made of advanced composite materials (ACMs), which contain central cutouts. Based on the first-order shear deformation plate theory (FSDT), the Newmark method and Newton-Raphson iteration wereused for the nonlinear dynamic solution. The effects of the cutout sizes and lay-up sequences on the nonlinear dynamic response for various parameters werestudied using a nonlinear dynamic finite element program that was developed for this study. The several numerical results agreed well with those reported by other investigators for square composite plates with or without central cutouts, and the new results reported in this paper showed significant interactions between the cutout and the layup sequence in the laminate. Key observation points are discussed and a brief design guide for laminates with central cutouts is given.

Numerical investigations on stability evaluation of a jointed rock slope during excavation using an optimized DDARF method

  • Li, Yong;Zhou, Hao;Dong, Zhenxing;Zhu, Weishen;Li, Shucai;Wang, Shugang
    • Geomechanics and Engineering
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    • v.14 no.3
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    • pp.271-281
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    • 2018
  • A jointed rock slope stability evaluation was simulated by a discontinuous deformation analysis numerical method to investigate the process and safety factors for different crack distributions and different overloading situations. An optimized method using Discontinuous Deformation Analysis for Rock Failure (DDARF) is presented to perform numerical investigations on the jointed rock slope stability evaluation of the Dagangshan hydropower station. During the pre-processing of establishing the numerical model, an integrated software system including AutoCAD, Screen Capture, and Excel is adopted to facilitate the implementation of the numerical model with random joint network. These optimizations during the pre-processing stage of DDARF can remarkably improve the simulation efficiency, making it possible for complex model calculation. In the numerical investigations on the jointed rock slope stability evaluations using the optimized DDARF, three calculation schemes have been taken into account in the numerical model: (I) no joint; (II) two sets of regular parallel joints; and (III) multiple sets of random joints. This model is capable of replicating the entire processes including crack initiation, propagation, formation of shear zones, and local failures, and thus is able to provide constructive suggestions to supporting schemes for the slope. Meanwhile, the overloading numerical simulations under the same three schemes have also been performed. Overloading safety factors of the three schemes are 5.68, 2.42 and 1.39, respectively, which are obtained by analyzing the displacement evolutions of key monitoring points during overloading.

Finite element dynamic analysis of laminated composite shell structures considering geometric nonlinear effects (기하학적 비선형 효과를 고려한 복합재료 적층 쉘 구조의 유한요소 동적 해석)

  • Lee, Sang-Youl
    • Journal of the Korea Academia-Industrial cooperation Society
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    • v.14 no.11
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    • pp.5979-5986
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    • 2013
  • This study carried out a geometrical nonlinear dynamic analysis of laminated composite shell structures. Based on the first-order shear deformation shell theory and nonlinear formulation of Sanders, the Newmark method and Newton-Raphson iteration are used for dynamic solution considering nonlinear effects. The effects of radius, fiber angles, and layup sequences on the nonlinear dynamic response for various parameters are studied using a nonlinear dynamic finite element program developed for this study. The several numerical results were in good agreement with those reported by other investigators for square composite plates, and the new results reported in this paper show the significant interactions between the radius, fiber angles and layup sequence in the laminate. Key observation points are discussed and a brief design guideline of laminated composite shells is given.

Estimation of earthquake induced story hysteretic energy of multi-Story buildings

  • Wang, Feng;Zhang, Ning;Huang, Zhiyu
    • Earthquakes and Structures
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    • v.11 no.1
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    • pp.165-178
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    • 2016
  • The goal of energy-based seismic design is to obtain a structural design with a higher energy dissipation capacity than the energy dissipation demands incurred under earthquake motions. Accurate estimation of the story hysteretic energy demand of a multi-story structure is the key to meeting this goal. Based on the assumption of a mode-equivalent single-degree-of-freedom system, the energy equilibrium relationship of a multi-story structure under seismic action is transformed into that of a multi-mode analysis of several single degree-of-freedom systems. A simplified equation for the estimation of the story seismic hysteretic energy demand was then derived according to the story shear force and deformation of multi-story buildings, and the deformation and energy relationships between the mode-equivalent single-degree-of-freedom system and the original structure. Sites were categorized into three types based on soil hardness, namely, hard soil, intermediate hard (soft) soil, and soft soil. For each site type, a 5-story and 10-story reinforced concrete frame structure were designed and employed as calculation examples. Fifty-six earthquake acceleration records were used as horizontal excitations to validate the accuracy of the proposed method. The results verify the following. (1) The distribution of seismic hysteretic energy along the stories demonstrate a degree of regularity. (2) For the low rise buildings, use of only the first mode shape provides reasonably accurate results, whereas, for the medium or high rise buildings, several mode shapes should be included and superposed to achieve high precision. (3) The estimated hysteretic energy distribution of bottom stories tends to be underestimated, which should be modified in actual applications.

An Assessment of a Resilient Modulus Model by Comparing Predicted and Measured Elastic Deformation of Railway Trackbeds (철도노반의 탄성변위 예측 및 측정을 통한 회복탄성계수 모델 평가)

  • Park, Chul-Soo;Kim, Eun-Jung;Oh, Sang-Hoon;Kim, Hak-Sung;Mok, Young-Jin
    • Proceedings of the Korean Geotechical Society Conference
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    • 2008.10a
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    • pp.1404-1414
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    • 2008
  • In the mechanistic-empirical trackbed design of railways, the resilient modulus is the key input parameter. This study focused on the resilient modulus prediction model, which is the functions of mean effective principal stress and axial strain, for three types of railroad trackbed materials such as crushed stone, weathered soil, and crushed-rock soil mixture. The model is composed with the maximum Young's modulus and nonlinear values for higher strain in parallel with dynamic shear modulus. The maximum values is modeled by model parameters, $A_E$ and the power of mean effective principal stress, $n_E$. The nonlinear portion is represented by modified hyperbolic model, with the model parameters of reference strain, ${\varepsilon}_r$ and curvature coefficient, a. To assess the performance of the prediction models proposed herein, the elastic response of a test trackbed near PyeongTaek, Korea was evaluated using a 3-D nonlinear elastic computer program (GEOTRACK) and compared with measured elastic vertical displacement during the passages of freight and passenger trains. The material types of sub-ballasts are crushed stone and weathered granite soil, respectively. The calculated vertical displacements within the sub-ballasts are within the order of 0.6mm, and agree well with measured values with the reasonable margin. The prediction models are thus concluded to work properly in the preliminary investigation.

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Physical and Hand Properties of the Knitted Fabrics From Machine Knitting Fancy Yarns (기계편용 장식사 니트소재의 물성 및 감성 평가)

  • Park, Key-Yoon;Park, Myung-Ja
    • Journal of the Korea Fashion and Costume Design Association
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    • v.10 no.2
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    • pp.125-138
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    • 2008
  • For physical and hand property evaluation of fabrics, the knitted fabrics from 11 types of machines knitting fancy yarns, boucle (M1), knot (M2), snarl (M3), and slub (M4), tamtam (M5), tubular (M6), fur 1 (M7), bead (M8), fur 2 (M9), fur 3 (M10), and ladder (M11) yarns, were prepared with 7-10 G plain stitch. Washing test and pilling test had also been carried out. For hand properties by objective sensibility evaluation, 17 items of sir mechanical properties using KES-FB (Kawabata Evaluation System) had been measured. Then hand values of knitted fabrics were calculated with a calculation formula, namely KN-402-KT. Finally the total hand values were obtained through KN-301-WINTER. As a result of physical properties and objective evaluation for machines knitting fancy fabrics, most of them shrank in the direction of wale and course after the washing test, in which their shrinkage rate had a maximum of 3.5%. Therefore, the washing test indicated that the shrinkage ratio of knitted fabrics had a minor change. The results of the pilling test are mostly 4-5th grade, and all of the machines knitting fancy fabrics showed good results in the pilling resistance. In hand properties and objective sensibility evaluation, twisted fancy yarns, such as boucle (M1), knot (M2), snarl (M3), and slub (M4), were superior to bonding rigidity (B) and shear rigidity (G). The surface property between course and wale differs in all samples and course direction is tougher than wale direction. FUKURAMI (fullness and softness) of all samples have high values, besides NUMERI (smoothness) of tamtam (M5) and boucle (M1), which were rather good. Most samples except fur 1 (M7) had low KOSHI (stiffness) value. The total hand value (THV) of twisted yarns was low. This study proves that manufacturers, who plan knitting yarn products and knit fashion, can apply these data to develop machines knitting yarns and knits that fit the consumers' demands.

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Ultimate Strength Analysis of Connections of Floating Pendulum Wave Energy Converter (부유식 진자형 파력발전장치의 연결부 최종강도해석)

  • Sohn, Jung Min;Cheon, Ho Jeong;Shin, Seung Ho;Hong, Key Yong
    • Journal of the Korean Society for Marine Environment & Energy
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    • v.17 no.1
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    • pp.36-41
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    • 2014
  • A floating offshore structure has high tendency to occur the buckling when compressive, bending and shear loads applied. When the buckling is occurred, in-plane stiffness of structure is remarkably decreased. And it has a harmful effect on the local structural strength as well as global structural strength. In the present study, it has been investigated the ultimate strength of tubular members which is located between a floater and a damping plate of the floating pendulum wave energy converter. Nonlinear finite element method is conducted using the initial imperfection according to 1st buckling mode which is obtained from the elastic buckling analysis. It is also noted the ultimate bending strength characteristic varying with a diameter, thickness and stiffeners of the tubular member.