• Title/Summary/Keyword: shear viscosities

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Structure-property relationship of melt intercalated maleated polyethylene nanocomposites

  • Reddy, M.M.;Gupta, Rahul K.;Bhattacharya, S.N.;Parthasarathy, R.
    • Korea-Australia Rheology Journal
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    • v.19 no.3
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    • pp.133-139
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    • 2007
  • Low density polyethylene nanocomposites were prepared by melt intercalating maleic anhydride grafted polyethylene and montmorillonite clay. It has been found that maleic anhydride has promoted strong interactions between polyethylene and montmorillonite, leading to the homogeneous dispersion of clay layers. Rheological experiments revealed that prepared nanocomposites exhibited shear thinning behaviour. Polyethylene nanocomposites exhibited an increase in steady shear viscosities compared to virgin polyethylene owing to strong polymer clay interactions. The tensile strength of nanocomposites was improved but elongation at break decreased considerably. Also, barrier properties improved significantly with montmorillonite content.

A Study on Fluid Flow of Various Viscosities in Coronary Artery (관상동맥 분지관에서 점도에 따른 유체의 유동현상 연구)

  • An, Gi-Yeong;Lee, Hyeon-Seop
    • Proceeding of EDISON Challenge
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    • 2013.04a
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    • pp.403-408
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    • 2013
  • 본 논문은 EDISON_CFD를 이용하여 관상동맥 분지관에서 점도에 따른 유체의 유동현상에 관하여 연구를 하였다. 뉴턴유체인 물의 점성계수 일때와 비뉴턴유체인 혈액의 Carreau model에서의 영전단율 점성계수(${\eta}_0$)와 무한전단율 점성계수(${\eta}_{\infty}$)일 때의 유동현상을 살펴보았다. 그 결과 점도가 증가할수록 재순환 영역에서 유체의 속도가 감소하였고 CF 및 CP값이 감소하는 구간의 수가 증가하여 벽면의 저전단응력으로 인해 생기는 재순환영역의 수가 증가하는 것으로 나타났다.

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A phenomenological approach to suspensions with viscoelastic matrices

  • Tanner Roger I.;Qi Fuzhong
    • Korea-Australia Rheology Journal
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    • v.17 no.4
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    • pp.149-156
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    • 2005
  • A simple constitutive model for viscoelastic suspensions is discussed in this paper. The model can be used to predict the rheological properties (relative viscosity and all stresses) for viscoelastic suspensions in shear and elongational flow, and the constitutive equations combine a 'viscoelastic' behaviour component and a 'Newtonian' behaviour component. As expected, the model gives a prediction of positive first normal stress difference and negative second normal stress difference; the dimensionless first normal stress difference strongly depends on the shear rate and decreases with the volume fraction of solid phase, but the dimensionless second normal stress difference (in magnitude) is nearly independent of the shear rate and increases with the volume fraction. The relative viscosities and all the stresses have been tested against available experimental measurements.

Measuring rheological properties using a slotted plate device

  • Kee, Daniel-De;Kim, Young-Dae;Nguyen, Q. Dzuy
    • Korea-Australia Rheology Journal
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    • v.19 no.2
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    • pp.75-80
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    • 2007
  • The slotted plate technique has previously been shown to be a successful method for directly measuring the static yield stress of suspensions. In this study, we further establish the usefulness of the slotted plate device as a rheometer especially at low shear rates, taking advantage of the extremely low speeds of the slotted plate technique. Newtonian fluids, a shear thinning fluid, and yield stress fluids were tested using the slotted plate device and the results were compared with those from a commercial rheometer using different standard flow geometries. The relationship between the stress on the plate and the viscosity for the slotted plate device obtained by dimensional analysis (drag) predicts a linear relationship between the force at the plate and the plate speed, consistent with the experimental data. The slotted plate device can measure viscosities at very low shear rates. The apparent viscosity - shear-rate data obtained from the slotted plate device are complementary to those obtained using a commercial rheometer. That is : the slotted plate can measure viscosity in the shear rate range $10^{-7}<\dot{\gamma}<10^{-3}\;s^{-1}$, while the commercial rheometer measures viscosity at shear rates higher than $10^{-3}\;s^{-1}$.

Rheological Properties and Particle Size Distribution of Northeast Mixed Hardwood for Enzymatic Saccharification Processing with High Substrates Loading

  • Um, Byung-Hwan
    • Journal of the Korean Wood Science and Technology
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    • v.36 no.5
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    • pp.56-65
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    • 2008
  • In this paper experimental results are presented for the rheological behavior of high-solids saccharification of mixed northeast hardwood as a model feedstock. The experimental determination of the viscosity, shear stress, and shear rate relationships of the 10 to 20 percent slurry concentrations with constant enzyme concentrations were performed under variable rotational speed of a viscometer (2.0 to 200 RPM) at combined temperatures (50 to $30^{\circ}C$) for the initial four hours. The viscosities of saccharification slurries observed were in the ranges of 0.024 to 0.028, 0.401 to 0.058, and 0.840 to 0.087 Pa s for shear rates up to 100 reciprocal seconds at 10, 15, and 20 percent initial solids (w/v) respectively. The fluid behavior of the suspensions was modeled using the power-law, the Herschel-Bulkley, the Casson, and the Bingham model. The results showed that broth slurries were pseudoplastic with a yield stress. The model slope increased and the model intercept decreased with increasing fermentation time at shear rates normal for the fermentor. The broth slurries exhibited Newtonian behavior at high and low shear rates during initial saccharification process. The solid particle size ranged from 57.8 to $70.0{\mu}m$ for $40^{\circ}C$ and from 44.0 to 57.5 11m for combined temperatures at 10, 15, and 20 percent initial solids (w/v) respectively.

In-vitro Study on Hemorheological Behaviors of Blood Flow Through a Micro Tube (미세튜브 내부를 흐르는 혈액유동의 유변학적 특성에 대한 in-vitro 연구)

  • Kang, Myung-Jin;Ji, Ho-Seong
    • Journal of Biomedical Engineering Research
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    • v.31 no.2
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    • pp.99-105
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    • 2010
  • In order to obtain velocity profile of blood flow with high spatial resolution, a micro PIV technique consisted of a fluorescent microscope, double-pulsed YAG laser, cooled CCD camera was applied to in-vitro blood flow experiment through a micro round tube of a diameter $100{\mu}m$. Velocity distributions of blood flow for rabbit were obtained. The viscosity profiles for shear rate were found at flowing condition. To provide hemorheological characteristics of blood flow, the viscosities for shear rate were evaluated. The viscosity of blood also steeply increase by decreasing shear rate resulting in Non-Newtonian flow, especially in low shear rate region caused by RBC rheological properties. The results show typical characteristics of Non-Newtonian characteristics from the results of velocity profile and viscosity for blood flow. From the inflection points, cell free layer and two-phase flow consisted with plasma and suspensions including RBCs can be separated.

Equilibrium and Non-equilibrium Molecular Dynamics Simulations of Thermal Transport Coefficients of Liquid Argon

  • Chang Bae Moon;Gyeong Keun Moon;Song Hi Lee
    • Bulletin of the Korean Chemical Society
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    • v.12 no.3
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    • pp.309-315
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    • 1991
  • The thermal transport coefficients-the self-diffusion coefficient, shear viscosity, and thermal conductivity-of liquid argon at 94.4 K and 1 atm are calculated by non-equilibrium molecular dynamics (NEMD) simulations of a Lennard-Jones potential and compared with those obtained from Green-Kubo relations using equilibrium molecular dynamics (EMD) simulations and with experimental data. The time-correlation functions-the velocity, pressure, and heat flux auto-correlation functions-of liquid argon obtained from the EMD simulations show well-behaved smooth curves which are not oscillating and decaying fast around 1.5 ps. The calculated self-diffusion coefficient from our NEMD simulation is found to be approximately 40% higher than the experimental result. The Lagrange extrapolated shear viscosity is in good agreement with the experimental result and the asymptotic formula of the calculated shear viscosities seems to be an exponential form rather than the square-root form predicted by other NEMD studies of shear viscosity. The agreement for thermal conductivity between the simulation results (NEMD and EMD) and the experimental result is within statistical error. In conclusion, through our NEMD and EMD simulations, the overall agreement is quite good, which means that the Green-Kubo relations and the NEMD algorithms of thermal transport coefficients for simple liquids are valid.

A Study on the Knite line for press Molding of Long Fiber Reinforced polymeric (장섬유강화 고분자 복합판의 프레스 성형에 있어서 니트라인에 관한 연구)

  • 조선형;이국웅;안종윤;윤성윤
    • Transactions of the Korean Society of Machine Tool Engineers
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    • v.10 no.2
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    • pp.115-123
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    • 2001
  • In recent years, compression molding of long fiber-reinforced thermoplastics has been increased in commercial aspects. In the process of compression molding of composites, the flow analysis must be developed in order to accurately predict the finished part properties as a function of the molding process parameters. In this model FRTP is assumed to be nonisothermal fluid, which has different viscosities in extensional and in shear. For verification of the model, the formation of a knit line in the L-shaped parts is compared with that of experiments results. In this paper we will discuss the effects of extensional & shear viscosity ratio and slip parameter $\alpha$ on the other modle fill-ing parameters.

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The Effect of Oil Rheology on Film Thickness in Engine Journal Bearing (윤활유의 유동특성이 기관 저어널 베어링의 유막두께에 미치는 영향)

  • 이동호;장병주
    • Transactions of the Korean Society of Automotive Engineers
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    • v.2 no.4
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    • pp.9-17
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    • 1994
  • Effect of Newtonian and non-Newtonian oils on minimum ol film thickness in engine journal bearing were investigated at various oil viscosities. The influence of oil viscosity and engine operating conditions on minimum oil film thickness of main bearing and con-rod bearing was examined. Minimum oil film thickness for Newtonian oils increased uniformly with kinematic viscosity. But the correlation between kinematic viscosity and minimum oil film thickness was very poor for non-Newtonian oils. According to the straight-line regression analysis for non-Newtonian oils, high temperature high shear viscosity at 1 $1{\times}10^6Sec^{-1}$, $150^{\circ}C$ increase the coefficient of determination from 0.41 to 0.77. Con-rod bearing showed better correlation between minimum oil film thickness and engine operating conditions than main bearing.

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Carrageenan as a Rheology Agent for Mild Cleansing Applications.

  • Lynch, Gerard
    • Proceedings of the SCSK Conference
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    • 2003.09b
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    • pp.369-369
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    • 2003
  • Viscarin is a tradename given to viscosifying carrageenans manufactured by FMC BioPolymer. The suitability of Vis car ins as rheology agents in mild cleansing applications has been investigated. Rheological properties, foam volume and clarity were measured to determine the impact of including 1 % Viscarin on 10% solutions of the following surfactants: acylglutamate, cocoamidopropyl betaine, PEG-80 laurate, sodium lauryl sulphate and sodium lauryol sarcosinate. Viscosity, pseudoplasticity and thixotropy of Viscarin/surfactant solutions varied with surfactant type. In all cases, the addition of Viscarin substantially increased viscosity. For example, at a shear rate of 1 sol, all surfactant solutions had viscosities <0.1 Pa s while viscosities of Viscarin/surfactant solutions ranged from 10 to 60 Pa s. By comparison, a solution of 1 % Viscarin had a viscosity of 0.3 Pa s. Clarity of surfactant solutions decreased in all cases on the addition of Viscarin. However, it was found that by including a mild solubilizing surfactant, such as PEG 40 hydrogenated castor oil, crystal clarity could be maintained in Viscarin/surfactant solutions. Viscarin increased the foam volume of sodium lauryolsarcosinate solutions from 10 ml to 220 ml and had no impact on the foam volume of the other surfactants tested. These results were used to formulate a clear, ultra-mild foaming cleansing gel based on sodium lauryol sarcosinate and Viscarin without the need for a secondary, foam-boasting surfactant. A mild shampoo was also formulated. Both products have excellent skin-feel and are capable of suspending bubbles and solid inclusions.

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