• Korea-Australia Rheology Journal
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• 제12권3_4호
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• pp.143-149
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• 2000

In this article, we considered shear-induced microstructure and rheological behavior of micellar solutions of cationic surfactant, cetylpyridinium chloride (CPC) in the presence of a structure-forming additive, sodium salicylate (NaSal). Shear viscosity, shear moduli and flow birefringence were measured as functions of the surfactant and additive concentrations. In the presence of NaSal, the micellar solution exhibited the non-linear rheological behavior due to the formation of supramolecular structures when the molar ratio of NaSal to CPC exceeded a certain threshold value. Flow birefringence probed the change in micelle alignment under shear flow. At low shear rates, the flow birefringence increased as the shear rate increased. On the other hand, fluctuation of flow birefringence appeared from the shear rate near the onset of shear thickening, which was caused by shear-induced coagulation or aggregation. These results were confirmed by the SEM images of in situ gelified micelle structure through sol-gel route.

• Korea-Australia Rheology Journal
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• 제14권4호
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• pp.203-207
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• 2002

Particle-particle interaction is of great importance in the study of suspension rheology. In this research we have investigated the hydrodynamic interaction between two identical cylinders in viscoelastic fluids numerically as a model problem for the study of viscoelastic suspension. We confine two neutrally buoyant cylinders between two parallel plates and impose a shear flow. We determine the migration velocity of two cylinders. The result shows that cylinders move toward or away from each other depending upon the initial distance between them and that there is an equilibrium distance between two cylinders in viscoelastic fluids regardless of the initial distance. In the case of Newtonian fluid, there is no relative movement as expected. The results partly explain the chaining phenomena of spherical particles in shear flows of viscoelastic fluids.

• Korea-Australia Rheology Journal
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• 제15권3호
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• pp.151-156
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• 2003

In this research, experimental studies were performed to examine the rheological behavior of equimolar solutions of cetylpyridinium chloride (CPyCl) and sodium salicylate (NaSal) solutions with concentration. The surfactant solutions were prepared by dissolving 2 mM/2 mM - 80 mM/80 mM of surfactant/counterion in double-distilled water. It has been observed that the zero shear viscosity shows abrupt changes at two critical values of C^*$ and C^{**}$. These changes are caused by the switching of relaxation mechanism with concentration of CPyCl/NaSal solutions at those concentrations. The wall slip velocities of dilute and semidilute CPyCl/NaSal solutions show a dramatic increase with shear rate where the shear viscosity exhibits shear thickening behavior for dilute solutions and shear thinning behavior for semi-dilute solutions, respectively. Considering that the dramatic increase in wall slip velocity should be related to the formation of shear-induced structure (SIS) in the surfactant solution, the shear thickening behavior of semi-dilute solutions is caused by elastic instability unlike the case of dilute solutions.

• Korea-Australia Rheology Journal
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• 제18권4호
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• pp.191-197
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• 2006

The measurement of the compressional rheological parameters for an aggregated particulate suspension is described. The parameters include the compressive yield stress and hindered settling function, describing the extent and rate of dewatering respectively. The variation of these parameters with shear rate and time of shear is also considered in the light of their sensitivity to low shear rates, with particular reference to the case of flocculated particulate suspensions. The latter is seen to be important in the future development of a comprehensive understanding of compressive rheology of aggregated particulate suspensions in industrial applications such as thickening, filtration and centrifugation.

• 펄프종이기술
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• 제43권3호
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• pp.121-127
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• 2011

This study used two types of rheology modifiers including an alkali-swellable emulsion (ASE) and an surface-adhesion emulsion (SAE) to elucidate their effects on high shear viscosity and dynamic penetration behavior among the flow properties of high solids coating. Since rheology under high shear and dynamic penetration behavior significantly affect the quality of coated paper in case of high solids coating, it is very important to examine the variations in rheology of high solids coating color by rheology modifier. It was found that the high solids coating color prepared with the SAE type showed superior dynamic penetration behavior and high shear viscosity than that with the ASE type rheology modifier.

• 한국유변학회:학술대회논문집
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• 한국유변학회 2002년도 춘계 학술발표회 논문집
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• pp.85-88
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• 2002

• Korea-Australia Rheology Journal
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• 제19권3호
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• pp.133-139
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• 2007

Low density polyethylene nanocomposites were prepared by melt intercalating maleic anhydride grafted polyethylene and montmorillonite clay. It has been found that maleic anhydride has promoted strong interactions between polyethylene and montmorillonite, leading to the homogeneous dispersion of clay layers. Rheological experiments revealed that prepared nanocomposites exhibited shear thinning behaviour. Polyethylene nanocomposites exhibited an increase in steady shear viscosities compared to virgin polyethylene owing to strong polymer clay interactions. The tensile strength of nanocomposites was improved but elongation at break decreased considerably. Also, barrier properties improved significantly with montmorillonite content.

• 한국유변학회:학술대회논문집
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• 한국유변학회 2002년도 추계학술발표회 논문집
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• pp.127-130
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• 2002

• 한국유변학회:학술대회논문집
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• 한국유변학회 2001년도 Australian-Korean Rheology Conference 2001
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• pp.162.3-162
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• 2001

• 한국세라믹학회지
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• 제45권2호
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• pp.99-104
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• 2008

Zeta potential, sedimentation bulk density and rheology in the dispersion system have been studied in terms of solid loading (40-55 vol%), and types of additives. Ammonium polymethacrylate, glycerol, ethoxylated acetylenic diol, and polyvinyl alcohol have been used as the dispersant, cryo-protectant, surfactant, and binder, respectively. Sedimentation density greatly increased upon adding dispersant; the effect was more pronounced with ionic alumina suspension compared with covalent silicon carbide. With further addition of cryo-protectant and surfactant to dispersant, the sedimentation density increased somewhat. The suspension viscosity generally behaviored in an opposite manner to the sedimentation density, i.e., high sedimentation gave low high-shear viscosity, indicative of low order structure formation in the suspended particles. Shear rate rheology in shear rate of $2-300\;sec^{-1}$ showed a shear thinning and its onset began at similar shear rate (${\sim}100\;sce^{-1}$), regardless of solid loading.