• Bulletin of the Korean Chemical Society
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• v.16 no.5
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• pp.410-416
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• 1995

The proton transfer energies of gas phase glycine and alanine and those of hydrated glycine and alanine were calculated both with Hartree-Fock and $M{\Phi}ller-Plesset$ ab initio molecular orbital (MO) calculations with 6-31G** basis set. The transition states of the proton transfer of gas phase glycine was also investigated. For zwitterions, both for glycine and alanine, the water bound to -NH3+ site stabilize the complex more compared with the water bound to -CO2-. The proton transfer energy, ΔEpt, of glycine, alanine, mono-hydrated glycine, mono-hydrated alanine, di-hydrated glycine and di-hydrated alanine were obtained as 30.78 (MP2: 22.57), 31.43, 23.99 (MP2: 17.00), 24.98, 22.87, and 25.63 kcal/mol, respectively. The activation energy for proton transfer from neutral (Nt) glycine to zwitterion (Zw) glycine, Ea, was obtained as 16.13 kcal/mol and that for reverse process, Ear, was obtained as 0.85 kcal/mol. Since the transition state of the proton transfer of gas phase glycine locate near the glycine zwitterion on the potential energy surface and the shape of the potential well of the zwitterion is shallow, the zwitterion easily changed to neutral glycine through the proton transfer.

• Journal of the Korean Geotechnical Society
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• v.17 no.6
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• pp.69-83
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• 2001

In order to make use of finished municipal landfill as a construction site, it is necessary to consider environmental and geotechnical aspects for the ground improvement and application of waste landfill. In environmental aspect, methods for management of landfill gas and leachate have to be established, and in geotechnical aspect, it is necessary to investigate available method for constructing structure foundation. In this study, the finished landfill was selected for pilot test. Investigation about the environmental characteristics of the waste landfill was performed to establish the methods far management of landfill gas according to monitoring the gas quantity and to investigate economical efficiency according to utilizing landfill gas. Investigation about cases of utilizing the waste landfill in Korea and abroad as construction site was performed and pilot tests were performed to analyze the improvement effects of methods such as dynamic compaction method and PG pile method available to waste landfill. The results of this study showed that economical profits could be gained by utilizing landfill gas and improved waste landfill, besides, dynamic compaction method was effective in case of improvement depth being shallow, and PG pile method was effective in case of improvement depth being deep.

• The Sea:JOURNAL OF THE KOREAN SOCIETY OF OCEANOGRAPHY
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• v.6 no.4
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• pp.242-248
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• 2001

A high resolution Chirp seismic profile and a multichannel seismic reflection profile were analysed to study the possibility of gas hydrate presence in the southwestern upper slope of the Ulleung Basin. The Chirp profile shows acoustic turbidity, acoustic void, and pockmarks, suggesting the presence of shallow gas in the sediments .Slope failures appear to have occurred in association with decomposition of gas hydrated sediments. A bottom-simulating reflector (BSR) is seen in subbottom depths of 60 to 110 m below the seafloor at water depths of 750 to 1130 m. The sediments above BSR are characterized by acoustic blanking probably due to amplitude reduction caused by a mixture of gas hydrate with sediments. The interval velocity above the BSR is 1,650 m/sec and it drops abruptly to 1,080 m/sec below the BSR. The sediment column between seafloor and the BSR thins with increasing water depth, which is very closely related to increasing geothermal gradient with increasing water depth in the Ulleung Basin.

• Journal of The Korean Society of Clinical Toxicology
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• v.15 no.1
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• pp.56-59
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• 2017

Pneumatosis cystoides intestinalis and portomesenteric venous gas are uncommon radiological findings, but are found commonly in cases of bowel ischemia, or as a result of various non-ischemic conditions. A 72-year-old man visited an emergency center with altered mental status 2 hours after ingestion of an unknown pesticide. On physical examination, he showed the characteristic hydrocarbon or garlic-like odor, miotic pupils with no response to light, rhinorrhea, shallow respiration, bronchorrhea, and sweating over his face, chest and abdomen. Laboratory results revealed decreased serum cholinesterase, as well as elevated amylase and lipase level. We made the clinical diagnosis of organophosphate poisoning in this patient based on the clinical features, duration of symptoms and signs, and level of serum cholinesterase. Activated charcoal, fluid, and antidotes were administered after gastric lavage. A computerized tomography scan of the abdomen with intravenous contrast showed acute pancreatitis, poor enhancement of the small bowel, pneumatosis cystoides intestinalis, portomesenteric venous gas and ascites. Emergent laparotomy could not be performed because of his poor physical condition and refusal of treatment by his family. The possible mechanisms were believed to be direct intestinal mucosal damage by pancreatic enzymes and secondary mucosal disruption due to bowel ischemia caused by shock and the use of inotropics. Physicians should be warned about the possibility of pneumatosis cystoides intestinalis and portomesenteric venous gas as a complication of pancreatitis following anticholinesterase poisoning.

• 한국신재생에너지학회:학술대회논문집
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• 2005.06a
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• pp.663-666
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• 2005

Gas hydrates are ice-like compounds that form at the low temperature and high pressure conditions common in shallow marine sediments at water depths greater than 300-500 m when concentrations of methane and other hydrocarbon gases exceed saturation. Estimates of the total mass of methane carbon that resides in this reservoir vary widely. While there is general agreement that gas hydrate is a significant component of the global near-surface carbon budget, there is considerable controversy about whether it has the potential to be a major source of fossil fuel in the future and whether periods of global climate change in the past can be attributed to destabilization of this reservoir. Also essentially unknown is the interaction between gas hydrate and the subsurface biosphere. ODP Leg 204 was designed to address these questions by determining the distribution, amount and rate of formation of gas hydrate within an accretionary ridge and adjacent basin and the sources of gas for forming hydrate. Additional objectives included identification of geologic proxies for past gas hydrate occurrence and calibration of remote sensing techniques to quantify the in situ amount of gas hydrate that can be used to improve estimates where no boreholes exist. Leg 204 also provided an opportunity to test several new techniques for sampling, preserving and measuring gas hydrates. During ODP Leg 204, nine sites were drilled and cored on southern Hydrate Ridge, a topographic high in the accretionary complex of the Cascadia subduction zone, located approximately 80km west of Newport, Oregon. Previous studies of southern Hydrate Ridge had documented the presence of seafloor gas vents, outcrops of massive gas hydrate, and a pinnacle' of authigenic carbonate near the summit. Deep-towed sidescan data show an approximately $300\times500m$ area of relatively high acoustic backscatter that indicates the extent of seafloor venting. Elsewhere on southern Hydrate Ridge, the seafloor is covered with low reflectivity sediment, but the presence of a regional bottom-simulating seismic reflection (BSR) suggests that gas hydrate is widespread. The sites that were drilled and cored during ODP Leg 204 can be grouped into three end-member environments basedon the seismic data. Sites 1244 through 1247 characterize the flanks of southern Hydrate Ridge. Sites 1248-1250 characterize the summit in the region of active seafloor venting. Sites 1251 and 1252 characterize the slope basin east of Hydrate Ridge, which is a region of rapid sedimentation, in contrast to the erosional environment of Hydrate Ridge. Site 1252 was located on the flank of a secondary anticline and is the only site where no BSR is observed.

• Geophysics and Geophysical Exploration
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• v.26 no.3
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• pp.138-149
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• 2023

In geoscience and engineering the geological characteristics of sediment strata is crucial and possible if reliable borehole logging and seismic data are available. To investigate the characteristics of the shallow strata in the Korea Strait, laboratory sonic logs were obtained from deep borehole data and seismic section. In this study, we integrated and analyzed the sonic log data obtained from the drilling core (down to a depth of 200 m below the seabed) and multichannel seismic section. The correlation value was increased from 15% to 45% through time-depth conversion. An initial model of P-wave impedance was set, and the results were compared by performing model-based, band-limited, and sparse-spike inversions. The derived P-impedance distributions exhibited differences between sediment-dominant and unconsolidated layers. The P-impedance inversion process can be used as a framework for an integrated analysis of additional core logs and seismic data in the future. Furthermore, the derived P-impedance can be used to detect shallow gas-saturated regions or faults in the shallow sediment. As domestic deep drilling is being performed continuously for identifying the characteristics of carbon dioxide storage candidates and evaluating resources, the applicability of the integrated inversion will increase in the future.

• Geophysics and Geophysical Exploration
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• v.17 no.4
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• pp.216-230
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• 2014

Based on the interpretation of 3D seismic profiles acquired in the northwestern area of the Ulleung Basin, East Sea, the shallow sediments consist of five seismic units separated by regional reflectors. An anticline is present in the study area that documents activity of many faults. Bottom simulating reflectors are characterized by high RMS amplitude. Acoustic blanking with low RMS amplitude is distinctively recognized in the gas hydrate stability zone. Seismic attribute analysis shows that if gas hydrates are underlain by free gas, the high reflection strength and the low instantaneous frequency are displayed below the boundary between them. Whereas, if not, the reflection strength is low and instantaneous frequency is high continuously below the gas hydrate zone. Based on the spectral decomposition of the bottom simulating reflector, the high envelope at the specific high frequency range indicates the generation of the tuning effect due to the lower free gas content. Four models for the occurrence of the gas hydrate are suggested considering the slope of sedimentary layers as well as the presence of gas hydrate or free gas.

• Journal of the Korean Society of Groundwater Environment
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• v.7 no.1
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• pp.32-46
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• 2000

Hydrogeochemical and isotope ($\delta$$^{18}$ O, $\delta$D, $^3$H, $\delta$$^{13}$ C, $\delta$$^{34}$ S, $^{87}$ Sr/$^{86}$ Sr) studies of various kinds of waters (thermal groundwater, deep groundwater, shallow groundwater, and surface water) from the Yusung area were carried out in order to elucidate their geochemical characteristics such as distribution and behaviour of major/minor elements, geochemical evolution, reservoir temperature, and water-rock interaction of the thermal groundwater. Thermal groundwater of the Yusung area is formed by heating at depth during deep circlulation of groundwater and is evolved into Na-HCO$_3$type water by hydrolysis of silicate minerals with calcite precipitation and mixing of shallow groundwater. High NO$_3$contents of many thermal and deep groundwater samples indicate that the thermal or deep groundwaters were mixed with contaminated shallow groundwater and/or surface water. $\delta$$^{18}$ O and $\delta$D are plotted around the global meteoric water line and there are no differences between the various types of water. Tritium contents of shallow groundwater, deep groundwater and thermal groundwater are quite different, but show that the thermal groundwater was mixed with surface water and/or shallow groundwater during uprising to surface after being heated at depths. $\delta$$^{13}$ C values of all water samples are very low (average -16.3$\textperthousand$%o). Such low $\delta$$^{13}$ C values indicate that the source of carbon is organic material and all waters from the Yusung area were affected by $CO_2$ gas originated from near surface environment. $\delta$$^{34}$ S values show mixing properties of thermal groundwater and shallow groundwater. Based on $^{87}$ Sr/$^{86}$ Sr values, Ca is thought to be originated from the dissolution of plagioclase. Reservoir temperature at depth is estimated to be 100~1$25^{\circ}C$ by calculation of equilibrium method of multiphase system. Therefore, the thermal groundwaters from the Yusung area were formed by heating at depths and evolved by water-rock interaction and mixing with shallow groundwater.

• Journal of the Semiconductor & Display Technology
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• v.9 no.1
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• pp.35-40
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• 2010

We have investigated the effects of hydrogen injection via in-situ gas addition ($O_2$, $H_2$, or $O_2$ + $H_2$ gas) and plasma post-treatment (Ar or Ar + H plasma) on material properties of ZnO that is considered to be as a channel layer in transparent thin film transistors. The variations in the electrical resistivity, optical transmittance and bandgap energy, and crystal quality of ZnO thin films were characterized in terms of the methods and conditions used in hydrogen injection. The resistivity was significantly decreased by injection of hydrogen; approximately $10^6\;{\Omega}cm$ for as-grown, $1.2\;{\times}\;10^2\;{\Omega}cm$ for in-situ with $O_2/H_2\;=\;2/3$ addition, and $0.1\;{\Omega}cm$ after Ar + H plasma treatment of 90 min. The average transmittance of ZnO films measured at a wavelength of 400-700 nm was gradually increased by increasing the post-treatment time in Ar + H plasma. The optical bandgap energy of ZnO films was almost monotonically increased by decreasing the $O_2/H_2$ ratio in in-situ gas addition or by increasing the post-treatment time in Ar + H plasma, while the post-treatment using Ar plasma hardly affected the bandgap energy. The role of hydrogen in ZnO was discussed by considering the creation and annihilation of oxygen vacancies as well as the formation of shallow donors by hydrogen.

• Journal of Welding and Joining
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• v.21 no.2
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• pp.57-63
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• 2003

Since new types of vehicles or structures made from thin aluminum alloy are under rapid development and some products are already on the market, welding of aluminium sheet is increasing. MIG(Metal Inert Gas), MIG-Pulse, TIG(Tungsten Inert Gas) welding are the typical Ai welding. MIG welding has the advantage of high speed, but it is difficult to apply to the thin plate, because of bum-through by the high heat input and spatter. MIG-Pulse welding can weld without spatter and burn-through, but when the gap exists at the welding joint, there is quite a possibility of bum-through. TIG welding is difficult to weld at a high speed. AC Pulse welding alternates between DCEP(Direct Current Electrode Positive) and DCEN(Direct Current Electrode Negative). DCEN is higher wire melting rate than DCEP, while lower temperature of droplet than DCEP. In AC Pulse welding, far fixed welding current, wire melting rate increases as the EN ratio increases. For fixed wire feed rate, welding current decreases as the EN ratio increases. Because of these features, the temperature of droplet, the depth of penetration, the width of bead decrease and the reinforcement height increases as EN ratio increases, and these are able to weld at a high speed, lower heat input. It is the purpose of this study that design of AC pulse current waveform for MIG welding of Al sheet and estimation of output characteristic.