• Title/Summary/Keyword: serpentine structure

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Serpentine Pretreatment Using Electrolyzed Reduced Water for Mineral Carbonation Materials (전해환원수를 이용한 탄산염 광물화 원료용 사문석의 전처리)

  • Choi, Weon-Kyung
    • Transactions of the Korean hydrogen and new energy society
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    • v.20 no.5
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    • pp.447-454
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    • 2009
  • Electrolyzed reduced water was known as an alkaline solvent than piped water, natural water and mineral water etc. By means of reduction property, electrolyzed reduced water could dissolve a solute than other kinds of water without chemicals. In this study, serpentine dissolution in electrolyzed reduced water was investigated as a novel pre-treatment of serpentine which was a minerals for carbon dioxide sequestration. The elements (Ca, Si, Mg etc.) of serpentine were dissolved rapidly at early in the dissolvation then after some minutes the solubilities of serpentine elements showed stable state without abrupt changes. In spite of serpentine elements dissolution, chemical bondings and crystallographic structure of serpentine were not changed. It was explained that the dissolution mechanism of serpentine occurred from surface in electrolyzed reduced water and bulk structure sustained without collapse.

Exploring precise deposition and influence mechanism for micro-scale serpentine structure fiber

  • Wang, Han;Ou, Weicheng;Zhong, Huiyu;He, Jingfan;Wang, Zuyong;Cai, Nian;Chen, XinDu;Xue, Zengxi;Liao, Jianxiang;Zhan, Daohua;Yao, Jingsong;Wu, Peixuan
    • Advances in nano research
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    • v.12 no.2
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    • pp.151-165
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    • 2022
  • Micro-scale serpentine structure fibers are widely used as flexible sensor in the manufacturing of micro-nano flexible electronic devices because of their outstanding non-linear mechanical properties and organizational flexibility. The use of melt electrowriting (MEW) technology, combined with the axial bending effect of the Taylor cone jet in the process, can achieve the micro-scale serpentine structure fibers. Due to the interference of the process parameters, it is still challenging to achieve the precise deposition of micro-scale and high-consistency serpentine structure fibers. In this paper, the micro-scale serpentine structure fiber is produced by MEW combined with axial bending effect. Based on the controlled deposition of MEW, applied voltage, collector speed, nozzle height and nozzle diameter are adjusted to achieve the precise deposition of micro-scale serpentine structure fibers with different morphologies in a single motion dimension. Finally, the influence mechanism of the above four parameters on the precise deposition of micro-scale serpentine fibers is explored.

Characterization of Aqueous Solution Pretreatment for Serpentine Used Carbondioxide Sequestration Material (이산화탄소 포획 원료용 사문석의 수용액 전처리 평가)

  • Choi, Weon-Kyung
    • Transactions of the Korean hydrogen and new energy society
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    • v.19 no.4
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    • pp.340-347
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    • 2008
  • Dissolution process of serpentine in distilled water was systematically investigated for study on pre-treatment of serpentine which was a candidate material for carbon dioxide sequestration. The metallic ions(Ca, Si, Mg etc.) were dissolved in distilled water at ambient condition and their concentrations were changed with dissolution time. The precise evaluation of dissolution process for serpentine dissolved solvent was performed by ion conductivity and pH measurement. Serpentine dissolution in distilled water was evaluated as a stable pre-treatment process without changes of crystallographic structure and chemical structure changes.

Design, Fabrication and Characterization of Lateral PZT actuator using Stiffness Control (강성제어 구조물을 이용한 수평구동형 박막 PZT 엑츄에이터의 설계, 제작 및 특성평가)

  • 서영호;최두선;이준형;이택민;제태진;황경현
    • Proceedings of the Korean Society of Precision Engineering Conference
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    • 2004.10a
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    • pp.756-759
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    • 2004
  • We present a piezoelectric actuator using stiffness control and stroke amplification mechanism in order to make large lateral displacement. In this work, we suggest stiffness control approach that generates lateral displacement by increasing the vertical stiffness and reducing the lateral stiffness using additional structure. In addition, an additional structure of a serpentine spring amplifies the lateral displacement like leverage structure. The suggested lateral PZT actuator (bellows actuator) consists of serpentine spring and PZT/electrode layer which is located at the edge of the serpentine spring. The edge of the serpentine spring prevents the vertical motion of PZT layer, while the other edge of the serpentine spring makes stroke amplification like leverage structure. We have determined dimensions of the bellows actuator using ANSYS simulation. Length, width and thickness of PZT layer are 135$\mu$m, 20$\mu$m and 0.4$\mu$m, respectively. Dimensions of the silicon serpentine spring are thickness of 25$\mu$m, length of 300$\mu$m, and width of 5$\mu$m. The bellows actuator has been fabricated by SOI wafer with 25$\mu$m-top silicon and 1$\mu$m-buried oxide layer. The bellows actuator shows the maximum 3.93$\pm$0.2$\mu$m lateral displacement at 16V with 1Hz sinusoidal voltage input. In the frequency response test, the fabricated bellows actuator showed consistent displacement from 1Hz to 1kHz at 10V. From experimental study, we found the bellows actuator using thin film PZT and silicon serpentine spring generated mainly laterally displacement not vertical displacement at 16V, and serpentine spring played role of stroke amplification.

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Hybrid-type stretchable interconnects with double-layered liquid metal-on-polyimide serpentine structure

  • Yim, Doo Ri;Park, Chan Woo
    • ETRI Journal
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    • v.44 no.1
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    • pp.147-154
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    • 2022
  • We demonstrate a new double-layer structure for stretchable interconnects, where the top surface of a serpentine polyimide support is coated with a thin eutectic gallium-indium liquid metal layer. Because the liquid metal layer is constantly fixed on the solid serpentine body in this liquid-on-solid structure, the overall stretching is accomplished by widening the solid frame itself, with little variation in the total length and cross-sectional area of the current path. Therefore, we can achieve both invariant resistance and infinite fatigue life by combining the stretchable configuration of the underlying body with the freely deformable nature of the top liquid conductor. Further, we fabricated various types of double-layer interconnects as narrow as 10 ㎛ using the roll-painting and lift-off patterning technique based on conventional photolithography and quantitatively validated their beneficial properties. The new interconnecting structure is expected to be widely used in applications requiring high-performance and high-density stretchable circuits owing to its superior reliability and capability to be monolithically integrated with thin-film devices.

A Study on the Bypass Flow Penetrating Through a Gas Diffusion Layer in a PEM Fuel Cell with Serpentine Flow Channels (사행유로를 갖는 고분자연료전지내부에서 가스확산층을 통과하는 반응가스 우회유동에 대한 연구)

  • Cho, Choong-Won;Ahn, Eun-Jin;Lee, Seung-Bo;Yoon, Young-Gi;Lee, Won-Yong
    • Transactions of the Korean Society of Mechanical Engineers B
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    • v.33 no.4
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    • pp.288-297
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    • 2009
  • A serpentine channel geometry often used in a fuel cell has a strong pressure gradient between adjacent channels in specific regions. The pressure gradient helps some amount of reactant gas penetrate through a gas diffusion layer(GDL). As a result, the overall serpentine flow structure is slightly different from the intention of a designer. The purpose of this paper is to examine the effect of serpentine flow structure on current density distribution. By using a commercial code, STAR-CD, a numerical simulation is performed to analyze the fuel cell with high aspect ratio of active area. To increase the accuracy of the numerical simulation, GDL permeabilities are measured with various compressive forces. Three-dimensional flow field and current density distribution are calculated. For the verification of the numerical simulation results, water condensation process in the cathode channel is observed through a transparent bipolar plate. The result of this study shows that the region of relatively low current density corresponds that of dropwise condensation in cathode channels.

The Effect of a Bypass Flow Penetrating through a Gas Diffusion Layer on Performance of a PEM Fuel Cell (가스확산층을 통과하는 반응가스 우회유동이 고분자 연로전지의 성능에 미치는 영향)

  • Cho, Choong-Won;Ahn, Eun-Jin;Lee, Seung-Bo;Lee, Won-Yong
    • 한국신재생에너지학회:학술대회논문집
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    • 2007.11a
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    • pp.147-151
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    • 2007
  • A serpentine channel geometry often used in a polymer electrolyte membrane fuel cell has a strong pressure gradient between adjacent channels in specific regions. The pressure gradient helps some amount of reactant gas penetrate through a gas diffusion layer(GDL). As a result, the overall serpentine flow structure is slightly different from intention of a designer. The purpose of this paper is to examine the effect of serpentine flow structure on current density distribution. By using a commercial code, STAR-CD, a numerical simulation is performed to analyze the fuel cell with relatively high aspect ratio active area. To increase the accuracy of the numerical simulation, GDL permeabilities are measured with various compression conditions. Three-dimensional flow field and current density distribution are calculated. For the verification of the numerical simulation results, water condensation process in the cathode channel is observed through a transparent bipolar plate. The result of this study shows that the region of relatively low current density corresponds to that of dropwise condensation in cathode channels.

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Physical Properties Change of Serpentine and Talc by Planetary Ball Mill (유성밀 분쇄에 의한 사문석과 활석의 물리적 특성변화)

  • Kim, Dong-Jin;Jeong, Heon-Saeng;Lee, Jae-Cheon;Lee, Ja-Hyeon
    • Korean Journal of Materials Research
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    • v.9 no.8
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    • pp.810-816
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    • 1999
  • The variations of crystalline structures and physical proerties of serpentine and talc mineral which was treated in a planetary ball mill, wre investigated by means of X-ray diffraction, FT-IR, DSC-TG, particle size analysis and SEM observation. The crystalline peaks of serpentine and talc in the XRD patterns were gradually reduced with the increase of grinding time and after 120 minutes turned into the amorphous phase, which is attributed to the disordering of the local structure around magnesium. The endothermic peaks for the ground serpentine and talc sample are observed at a considerably lower temperatures than that for the starting sample. A morphological change from the originally flat and irregular shape to spherically agglomerated particles was clearly observed.

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Occurrence and Mineralogy of Serpentine Minerals in the Calc-silicate Rock Sheets from the Bonghwa Area, Kyungsangbuk-do (경북 봉화지역의 석회규산염층에서 산출되는 사문석광물의 산상 및 광물학적 특성)

  • Bae, Sung-Woo;Hwang, Jin-Yeon;Lee, Son-Kap;Kwack, Kyu-Won;Yoon, Ji-Hae;Cho, Sung-Hwi
    • Journal of the Mineralogical Society of Korea
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    • v.21 no.1
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    • pp.85-98
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    • 2008
  • Calc-silicate rock sheet occurs within the Precambrian metasedimentary rocks in Bonghwa area, Kyungsangbuk-do, Korea. The calc-silicate rock runs parallel to bedding plane with $14{\sim}18$ meters in width. Calcite, dolomite, serpentine and tremolite are occurred as major minerals and talc is occurred as a miner mineral. Serpentine mainly occurs in the upper part and tremolite occurs in lower part of calc-silicate rock sheet. Colors of calc-silicate rock change to deeper green with increasing amounts of serpentine mineral. XRD, FT-IR analyses indicates that serpentine mineral is antigorite. Platy structure of antigorite is well observed by SEM analysis. EPMA data indicates that chemical composition of antigorite is very close to ideal ($SiO_2$: 44.3 wt% and MgO: 40.8 wt%). The chemical formula of antigorite is calculated as $Mg_{2.82}Al_{0.04}Fe^{3+}_{0.04}Si_{2.05}O_5(OH)_4$. From careful study by comparing mineralogical analysis data and occurrence, calc-silicate rock sheet was formed by metamorphism of calcareous sedimentary rocks having different mineralogical and chemical compositions. It is considered that the host rock of serpentine enriched upper part was more Mg-rich rocks than the host rocks of tremolite enriched lower part.

Self-pressurization Effect and PEMFC Performance Improvement Using Metal Foam Compression (금속 폼 압축에 의한 자가 가압 효과 및 PEMFC 성능 개선)

  • Kim, Hyeonwoo;Kim, Junbom
    • Applied Chemistry for Engineering
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    • v.33 no.6
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    • pp.618-623
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    • 2022
  • The bipolar plate is a key component of the polymer electrolyte membrane fuel cell (PEMFC) that transfers reactants and electrons, discharges water and heat as by-products, and serves as a mechanical support for the membrane electrode assembly (MEA). Therefore, the flow field structure of the bipolar plate plays an important role in improving fuel cell performance. In this study, PEMFC performance was investigated with copper foams with different compressibility ratios applied to cathode bipolar plates using a 25 cm2 unit cell. The total resistance decreased as the compressibility ratio of the metal foams increased, and, in particular, the charge transfer and mass transfer resistance were significantly improved compared to the serpentine flow field, lowering voltage loss in medium and high current density region. In the case of pressurized air reactant flow with serpentine structure, fuel cell performance was similar to that of a compressed metal foam flow field (S3) up to the medium current density region, but low performance appeared in the high current density region due to flow field structure limitations.