• 제목/요약/키워드: separation techniques

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Porous polymer membranes used for wastewater treatment

  • Melita, Larisa;Gumrah, Fevzi;Amareanu, Marin
    • Membrane and Water Treatment
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    • v.5 no.2
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    • pp.147-170
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    • 2014
  • This paper focuses on the study of the most recent ultra-filtration techniques, based on porous polymer membranes, used for the treatment of wastewater from oil, mine and hydrometallurgical industries. The performance of porous membranes used in separation and recovery of oil and heavy metals from wastewater, was evaluated by the polymer composition and by the membrane characteristics, as it follows: hydrophobicity or hydrophilicity, porosity, carrier (composition and concentration), selectivity, fouling, durability, separation efficiency and operating conditions. The oil/water efficient separation was observed on ultra-filtration (UF) techniques, with porous membranes, whereas heavy metals recovery from wastewater was observed using porous membranes with carrier. It can be concluded, that in the ultra-filtration wastewater treatments, a hybrid system, with porous polymer membranes with or without carrier, can be used for these two applications: oil/water separation and heavy metals recovery.

A Comprehensive Review of Recent Advances in the Enrichment and Mass Spectrometric Analysis of Glycoproteins and Glycopeptides in Complex Biological Matrices

  • Mohamed A. Gab-Allah;Jeongkwon Kim
    • Mass Spectrometry Letters
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    • v.15 no.1
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    • pp.1-25
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    • 2024
  • Protein glycosylation, a highly significant and ubiquitous post-translational modification (PTM) in eukaryotic cells, has attracted considerable research interest due to its pivotal role in a wide array of essential biological processes. Conducting a comprehensive analysis of glycoproteins is imperative for understanding glycoprotein bio-functions and identifying glycosylated biomarkers. However, the complexity and heterogeneity of glycan structures, coupled with the low abundance and poor ionization efficiencies of glycopeptides have all contributed to making the analysis and subsequent identification of glycans and glycopeptides much more challenging than any other biopolymers. Nevertheless, the significant advancements in enrichment techniques, chromatographic separation, and mass spectrometric methodologies represent promising avenues for mitigating these challenges. Numerous substrates and multifunctional materials are being designed for glycopeptide enrichment, proving valuable in glycomics and glycoproteomics. Mass spectrometry (MS) is pivotal for probing protein glycosylation, offering sensitivity and structural insight into glycopeptides and glycans. Additionally, enhanced MS-based glycopeptide characterization employs various separation techniques like liquid chromatography, capillary electrophoresis, and ion mobility. In this review, we highlight recent advances in enrichment methods and MS-based separation techniques for analyzing different types of protein glycosylation. This review also discusses various approaches employed for glycan release that facilitate the investigation of the glycosylation sites of the identified glycoproteins. Furthermore, numerous bioinformatics tools aiding in accurately characterizing glycan and glycopeptides are covered.

Speech Recognition in Noise Environment by Independent Component Analysis and Spectral Enhancement (독립 성분 분석과 스펙트럼 향상에 의한 잡음 환경에서의 음성인식)

  • Choi Seung-Ho
    • MALSORI
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    • no.48
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    • pp.81-91
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    • 2003
  • In this paper, we propose a speech recognition method based on independent component analysis (ICA) and spectral enhancement techniques. While ICA tris to separate speech signal from noisy speech using multiple channels, some noise remains by its algorithmic limitations. Spectral enhancement techniques can compensate for lack of ICA's signal separation ability. From the speech recognition experiments with instantaneous and convolved mixing environments, we show that the proposed approach gives much improved recognition accuracies than conventional methods.

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Simultaneous Spectrometric Determination of Caffeic Acid, Gallic Acid, and Quercetin in Some Aromatic Herbs, Using Chemometric Tools

  • Kachbi, Abdelmalek;Abdelfettah-Kara, Dalila;Benamor, Mohamed;Senhadji-Kebiche, Ounissa
    • Journal of the Korean Chemical Society
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    • v.65 no.4
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    • pp.254-259
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    • 2021
  • The purpose of this work is the development of a method for an effective, less expensive, rapid, and simultaneous determination of three phenolic compounds (caffeic acid, gallic acid, and quercetin) widely present in food resources and known for their antioxidant powers. The method relies on partial least squares (PLS) calibration of UV-visible spectroscopic data. This model was applied to simultaneously determine, the concentrations of caffeic acid (CA), gallic acid (GA), and quercetin (Q) in six herb infusion extracts: basil, chive, laurel, mint, parsley, and thyme. A wavelength range (250-400) nm, and an experimental calibration matrix with 21 samples of ternary mixtures composed of CA (6.0-21.0 mg/L), GA (10.0-35.2 mg/L), and Q (6.4-17.5 mg/L) were chosen. Spectroscopic data were mean-centered before calibration. Two latent variables were determined using the contiguous block cross-validation procedure after calculating the root mean square error cross-validation RMSECV. Other statistic parameters: RMSEP, R2, and Recovery (%) were used to determine the predictive ability of the model. The results obtained demonstrated that UV-visible spectrometry and PLS regression were successfully applied to simultaneously quantify the three phenolic compounds in synthetic ternary mixtures. Moreover, the concentrations of CA, GA and Q in herb infusion extracts were easily predicted and found to be 3.918-18.055, 9.014-23.825, and 9.040-13.350 mg/g of dry sample, respectively.

Advanced separation techniques for treatment of soil contaminated with heavy metals (중금속 오염 토양의 고도 선별 정화(복원)기술)

  • Lee, Hyo-Suk;Chae, Yeong-Bae
    • Journal of the Korean Professional Engineers Association
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    • v.41 no.3
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    • pp.24-29
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    • 2008
  • Recently, the serious problems have been occurred due to the contaminated sites with heavy metals are increasing. There are several remediation technologies of the metal contaminated soil such as physical separation, washing with water or acid, biologically, electrically. Pytoremediation, ultrasonic etc. Among these technologies the physical separation can be put in a good option to solve the metal contaminated soil economically and environmental friendly. Because this technology has been already commercially certificated in the mineral processing field for a long time.

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COAL DESULFURIZATION BY MAGNETIC SEPARATION METHODS (자력선별법에 의한 선탄의 탈황)

  • Jeon, Ho-Seok;Lee, Jae-Jang
    • Journal of Industrial Technology
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    • v.15
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    • pp.175-185
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    • 1995
  • Under the new environmental regulations announced by the government, utilities will have to cut their sulfur dioxide emissions by 60% from 1991 levels by the year of 1999. Sulfur dioxide emissions can be reduced prior to combustion by physical, chemical or biological coal cleaning. The new technology of high gradient magnetic separation (HGMS) offers the potential of economic separatoins of a variety of fine, weakly magnetic minerals including inorganic sulfur and many ash-forming minerals from coals. In the present paper, magnetic separation tests have been conducted on Korean anthracite and high-sulfur Chinese coal to investigate the feasibility of these techniques for reducing sulfur content from coals. In wet magnetic separation, the studied operating parameters include particle size, pH, matrix types, feed solids content, feed rate, number of cleaning stages and etc. The results shows that for wet separation, 60~70% of total sulfur was removed from coals with over 80% combustible recovery, on the other hand, for dry separation, 47.6% of total sulfur was removed from coals with 75% recovery.

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Bioseparations in Lab-On-A-Chip (랩온어칩에서의 생물분리기술)

  • Chang Woo-Jin;Koo Yoon-Mo
    • KSBB Journal
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    • v.20 no.3
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    • pp.197-204
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    • 2005
  • Lab-on-a-chip is a miniaturized analytical device in which all of the procedures for the analysis of molecules are carried out, such as pretreatment, reaction, separation, detection, etc. Lab-on-a-chip has increasing concern as a device not only for rapid detection of molecules but also for high throughput screening and point of care, because conventional laborious and time consuming analytical procedures can be substituted. Thus, a lot of microfabrication and analytical techniques for lab-on-a-chip have been developed with microstructures smaller than a few hundreds of micrometers. Separation of the molecules is one of the most important components of lab-on-a-chip, because effective separation method can simplify the design and can provide better sensitivity. The electrokinetic separation based on capillary electrophoresis is most widely employed technique in lab-on-a-chip for the control of fluids and the separation of molecules. In this article, bioseparation techniques and its applications realized in lab-on-a-chip are reviewed.

Performance of an acidic extractant (D2EHPA) incorporated in IM used for extraction and separation of Methylene Blue and Rhodamin B

  • Aitali, S.;Kebiche-Senhadji, O.;Benamor, M.
    • Membrane and Water Treatment
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    • v.7 no.6
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    • pp.521-537
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    • 2016
  • Laboratory-scale experiments were carried out to investigate the adsorption equilibrium, the adsorption kinetics and facilitated transport of two cationic dyes (Methylene Blue (MB) and Rhodamine B (RB)) on Polymer Inclusion Membrane (D2EHPA-PIM). Different adsorption isotherms (Freundlich, Langmuir and Temkin models) as well as kinetics models indicated that the adsorption process is spontaneous and exothermic. Under the optimal conditions, the adsorption removal efficiencies reach about 93% and 97% for MB and RB respectively. Different extraction values by D2EHPA-PIM were obtained for the two cationic dyes: MB is weakly extracted at pH 2.0 (E% = 18.7%) whilst E% = 82.4% was observed for RB at the same pH. This difference was exploited in a mixture containg both the 2 cationic dyes for the selective extraction of RB at pH 2. Desorption of both dyes was achieved from the membrane by using acidic aqueous solutions and desorption ratio up to 90% was obtained. The formulas of the extracted complexes by the PIMs were, determined by the method of slopes. The dyes transport was elucidated using mass transfer analysis where in it found relatively high values of the initial flux ($J_0$) as 41.57 and $18.74{\mu}mol.m^2.s^{-1}$ for MB and RB respectively.

A Study on the Separation of Support and Infill of KICT Experimental Open Housing (오픈 하우징의 Support와 Infill 분리에 관한 연구 - KICT 실험주택의 SI분리 수법을 중심으로 -)

  • Kim, Soo-Am;Lee, Seoung-Ok;Lee, Bo-Ra;Hwang, Eun-Kyung
    • Proceeding of Spring/Autumn Annual Conference of KHA
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    • 2004.11a
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    • pp.301-306
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    • 2004
  • The purpose of this study is to supply basic data for distinction of Support and Infill in Open Housing. This study is based on archive survey and actual investigation through visiting four sites in Japan, which are experimental SI(skeleton & infill) housings. We found a lot of distinction techniques and methods applied to the SI housings, and findings are applicable to the planning and designing works of apartment housings. Based on the theoretical Studies concerning the distinction and separation of SI housing, this study made out interface map for separation and distinction of housing components and examined a design method of separation accordingly.

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Synthesis and Characterization of Zeolite Composite Membranes (II): Synthesis and $CO_2$ Separation Efficiency of ZSM-5 Zeolite Composite Membranes (제올라이트 복합 분리막의 합성 및 특성화(II): ZSM-5 제올라이트 복합막의 합성 및 $CO_2$ 분리 효율)

  • 현상훈;송재권;김준학
    • Journal of the Korean Ceramic Society
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    • v.34 no.7
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    • pp.747-757
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    • 1997
  • ZSM-5 zeolite composite membranes have been synthesized from a silica sol solution containing TPABr as an organic template by the dip-coating and the pressurized-coating hydrothermal treatment techniques. The CO2 separation efficiency of synthesized composite membranes was also investigated. The permeation mechanism of CO2 through ZSM-5 membranses was the surface diffusion, and that of N2, O2, and He gases was Knudsen diffusion or activated diffusion depending on the synthetic method of membranes and the measurement temperature. The CO2/N2 separation factor of the membrane prepared by the dip-coating hydrothermal treatment was 2.5 at about 12$0^{\circ}C$, while the ZSM-5 composite membrane synthesized by the pressurized-coating hydrothermal treatment technique showed the CO2/N2 separation factor of 9.0 at room temperature higher than that ever reported in the literature.

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