• Title/Summary/Keyword: separation of mixture

Search Result 642, Processing Time 0.041 seconds

Characteristics of Non-premixed Edge Flames in a Counterflow Slot Burner

  • Cha, Min-Suk;Ronney, Paul D.
    • Journal of the Korean Society of Combustion
    • /
    • v.10 no.4
    • /
    • pp.33-40
    • /
    • 2005
  • The propagation rates of advancing and retreating non-premixed edge flames in a slot-jet counterflow were measured as a function of strain rate for varying jet spacing, mixture strength, stoichiometric mixture fractions $(Z_{st})$ and Lewis numbers (Le). Methane and propane fuels were tested and nitrogen and carbon dioxide were used as inerts. As results, we could identify igniting fronts, retreating fronts, two total extinction limits, and short-length edge flames. A burner separation affected to a low extinction limit only. Regimes for advancing and retreating edges together with total extinction were mapped in terms of normalized flame thickness and heat loss factor for $CH_4/O_2/N_2$ mixtures. Edge flames for $Z_{st}$ > 0.5 behaved like a stronger mixture while for $Z_{st}$ < 0.5 showed deteriorated feature, because of relative locations of a non-premixed flame and intermediate species such as CO and $H_2$. Furthermore, due to the relative importance of heat loss, propagating speeds of edge flames were significantly enhanced in $CH_4/O_2/CO_2$ mixtures (Le < 1) demonstrating increasing stability limits. However $C_3H_8/O_2/N_2$ mixtures (Le > 1) showed opposite result.

  • PDF

Preparation of Silicone Rubber Membrane and its Porosity (Silicone Rubber Membrane의 제조 및 기공특성)

  • Lee, Seung-Bum;Kim, Hyung-Jin;Hong, In-Kwon
    • Elastomers and Composites
    • /
    • v.30 no.3
    • /
    • pp.185-194
    • /
    • 1995
  • Membrane process has been employed to separate a specific substance from gas or liquid mixture, and treat wastewater. This is due to the fact that the substance of mixture can be permeated and separated selectively by membrane. Since Initial equipment and operation costs are not expensive, membrane process has been adopted in various fields such as petroleum Industry, chemistry, polymer, electronics, foods, biochemical industry and wastewater treatment. In this study, $CaCO_3$ particles impregnated in silicone rubber network were extracted by using supercritical carbon dioxide and pore distribution of silicone $rubber-CaCO_3$ was investigated with varying amount of extract. Silicone rubber has excellent mechanical properties such as heat-resistance, cold-resistance etc. and $CaCO_3$ has microporous structure. It is possible to make silicone $rubber-CaCO_3$ composite sheets via work-intensive kneading processes. In so doing $CaCO_3$ particles become distributed and impregnated in silicone rubber network. Supercritical carbon dioxide diffuse through composite sample, then sample is swollen. $CaCO_3$ in silicone rubber network Is dissolved in supercritical carbon dioxide, and its sites become pores. Pore distribution, pore shape and surface area are observed by SEM(scanning electron microscope) micrograph and BET surface area analyzer examination respectively. Pore characteristics of membrane suggest the possibilities that the membrane can be used for process of mixture separation and wastewater treatment.

  • PDF

Numerical Study of Regular Start and Unstart Process of Superdetonative Speed Ram Accelerator (초폭굉속도 램 가속기의 정상발진 및 불발과정의 수치적 연구)

  • Moon, G.W.;Jeung, I.S.;Choi, J.Y.
    • Journal of the Korean Society of Combustion
    • /
    • v.5 no.1
    • /
    • pp.31-41
    • /
    • 2000
  • A numerical study was conducted to investigate the combustion phenomena of regular start and unstart processes based on ISL#s RAMAC 30 experiments with different diluent amounts in a ram accelerator. The initial projectile launching speed was 1800m/s which corresponded to the superdetonative speed of the stoichiometric $H_2/O_2$ mixture diluted with $5CO_2\;or\;4CO_2$. In this study, it was found that neither shock nor viscous heating was sufficient to ignite the mixture at a low speed of 1800m/s, as was found in the experiments using a steel-covered projectile. However, we could succeed in igniting the mixtures by imposing a minimal amount of additional heat to the combustor section and simulate the regular start and unstart processes found in the experiments with an aluminum-covered projectile. The numerical results matched almost exactly to the experimental results. As a result, it was found that the regular start and unstart processes depended on the strength of gas mixture, development of shock-induced combustion wave stabilized by the first separation bubble, and its size and location.

  • PDF

Chiral Separation of Non-Steroidal Inflammatory Drugs as Dual Diastereomeric Derivatives with (R)-and (S)-Phenylethylamines

  • Lee, Yoon-Suk;Paik, Man-Jeong;Kim, Kyoung-Rae
    • Proceedings of the PSK Conference
    • /
    • 2003.04a
    • /
    • pp.282.2-283
    • /
    • 2003
  • The carboxylated acidic non-steroidal antiinflammatory drugs (NSAIDs) constitute the principal class of agents for controlling the pain and inflammation of the rheumatic diseases. It is mostly administered as a racemic mixture like most other drugs with asymmetric carbon atoms. However enantiomers of many racemic drug substances have been shown to posses different pharmacological toxicological properties. (omitted)

  • PDF

Separation of Organic Liquid Mixtures using Plasma Membrane (플라즈마 멤브레인을 이용한 유기용매 혼합을 분리)

  • 김성오;박복기;김두석;박진교;이덕출
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
    • /
    • 1999.05a
    • /
    • pp.642-644
    • /
    • 1999
  • We have prepared the plasma-polymerized membrane for pervaporation of organic-liquid mixtures by the plasma polymerization technique. Plasma polymerization techniques were utilized in the development of hydrophilic composite membranes having high hydrogen ion permeability and excellent dimensional stability. To develop an organic liquid permselective Membrane, suppressing membrane swearing as well as enhancing the solubility difference is impotant. the objectives of the present study are to disign a suitable membrane for an organic-mixture system by the control of the plasma-polymer solubility.

  • PDF

Multidimensional Gas Chromatography-A Powerful Tool for the Analysis of Multicomponent Mixtures

  • Kim, Kyoung-Su
    • Preventive Nutrition and Food Science
    • /
    • v.1 no.1
    • /
    • pp.127-133
    • /
    • 1996
  • The development of high resolution capillary columns and a large variety of different detectors led to a strong position of gas chromatography in instrumental analysis. Every effort has been made to solve sophisticated separation problems by column switching. Nowadays, several systems are commercially available for this purpose. The principle and the capabilities of multidimensional gas chromatography(MDGC) are illustrated by different applications in the field of modern flavor and essential oil research.

  • PDF

Synergistic Extraction of Palladium(Ⅱ) with Thenoyltrifloroacetone and Tri-n-octylphosphine Oxide

  • 이상호;정구순
    • Bulletin of the Korean Chemical Society
    • /
    • v.16 no.6
    • /
    • pp.479-483
    • /
    • 1995
  • The synergistic extraction of palladium(Ⅱ) was studied with 1,2-dichloroethane containing thenoyltrifluoroacetone (TTA; HA) and tri-n-octylphosphine oxide (TOPO; S). The main composition of synergistic adduct extracted into 1,2-dichloroethane phase was found to be PdA2S2. The equilibrium constants of the synergistic reaction were calculated. The application of this method to synthetic mixture for the separation of Pd from Pt was developed.

A Study on Curing Behaviors and Structures of Chiral Liquid Crystal-Polymer composite films (키랄네마틱액정-고분자 복합막의 경화거동과 내부구조에 관한 연구)

  • 남수용;김종원;김용욱
    • Journal of the Korean Graphic Arts Communication Society
    • /
    • v.16 no.3
    • /
    • pp.15-27
    • /
    • 1998
  • Several aspects of polymer dispersed liquid crystal(PDLC) film properties make them interesting for display application. Most versions of PDLC materials are able to modulate light without the use of polarizers, which offers advantages in optical throughput(brightness) and viewing angle compared to polarizer-based display. In this papers, we attemped to doe minimum of remaining liquid crystals at polymer network for the liquid crystal-polymer composite (LCPC) films. In results, best phase separation behaviors turned out liquid crystal/monomer/oligomer mixture system.

  • PDF

Separation of Hydrogen-Nitrogen Gas Mixture by PTMSP-Silica-PEI Composite Membranes

  • Lee, Hyun-Kyung;Kang, Tae-Beom
    • Proceedings of the Membrane Society of Korea Conference
    • /
    • 2004.05a
    • /
    • pp.144-147
    • /
    • 2004
  • Organosilicon polymers have long paid attention as functional polymers [1,2]. Among others, poly- (1-trimethylsilyl-1-propyne) [PTMSP] is a polymer, which forms a gas separating membrane with extraordinary high gas permeability. In particular, composite membranes that constituted two different matrices (inorganic and organic) have been recently developed in order to improve the permeation characteristics.(omitted)

  • PDF

Heterogeneous Suzuki Cross-Coupling Reaction Catalyzed by Magnetically Recyclable Nanocatalyst

  • Choi, Kwang-Hyun;Shokouhimehr, Mohammadreza;Sung, Yung-Eun
    • Bulletin of the Korean Chemical Society
    • /
    • v.34 no.5
    • /
    • pp.1477-1480
    • /
    • 2013
  • The Suzuki cross-coupling reactions proceeded in excellent yields when it was catalyzed by magnetically recyclable nanocatalyst. This nanocatalyst provided very high catalytic activity with low loading level (1 mol %), because the palladium nanoparticles were so small in size (~2 nm) and located on the surface of the nanocomposite. It was also easily recovered from the reaction mixture using a magnet and reused for six consecutive cycles.