• Title/Summary/Keyword: separated optimization

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Determination of Fluorescent Whitening Agents in Paper Materials by Ion-Pair Reversed-Phase High-Performance Liquid Chromatography

  • Kim, Jeong Soo;Kim, Do Hwan;Kim, Keon
    • Bulletin of the Korean Chemical Society
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    • v.33 no.12
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    • pp.3971-3976
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    • 2012
  • A simple method was developed for the analysis of seven stilbene-type fluorescent whitening agents (FWAs) in paper materials by ion-pair reversed-phase high-performance liquid chromatography with fluorescence detection. These stilbene-type FWAs included two disulfonate, two tetrasulfonate, and three hexasulfonate compounds. After optimization of chromatographic conditions, the FWAs were satisfactorily separated using a reversed-phase column (RP-18) with the following isocratic mobile phase: methanol-water (60:40) containing 17.5 mM TBABr and 10 mM citrate buffer (pH = 7.0). The calibration plot was linear in the range from 5 to 500 ng/mL for two disulfo-FWAs and from 1 to 500 ng/mL for the other five FWAs. Precision levels of the calibration curve as indicated by RSD of response factors were 1.2 and 8.1%. Limits of quantitation (LOQ) ranged from 1.2 to 11 ng/mL.

The Analysis of Free Amino Acids in Tobacco (잎담배 중 유리 아미노산 분석)

  • Lee, Jeong-Min;Min, Hey-Jung;Jang, Gi-Chul;Hwang, Keon-Joong
    • Journal of the Korean Society of Tobacco Science
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    • v.32 no.2
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    • pp.70-76
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    • 2010
  • A simple and sensitive automatic amino acid analyzer method for the determination of free amino acids in tobacco was described. Sample preparation consisted of a single step of extraction with 0.1 mol HCl at ambient temperature in 60 min by sonication, followed by filtration of an aliquot. Automated amino acid analyzer was used to construct a post-column ninhydrin reaction unit to monitor amino acids separated by liquid chromatography using a series of eluting buffers. By optimization of sample preparation, separation of 19 amino acids was achieved. Limits of quantitation was 0.01 mg/g, coefficients of variation ranged from 0.5 % to 8.9 % and recoveries range from 85 % to 106 %. The method was applied to the analysis of amino acids contents of tobacco leaves in different varieties.

Optimization of Wave Forms for Pulsed Amperometric Detection of Cyanide and Sulfide with Silver-Working Electrode

  • Park, Seong U;Hong, Seong Uk;Yu, Jae Hun
    • Bulletin of the Korean Chemical Society
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    • v.17 no.2
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    • pp.143-146
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    • 1996
  • A continuous potential pulse is applied to a silver-working electrode on a pulsed amperometric detector (PAD) for detection of free cyanide and sulfide. The moving phase is 0.1 M sodium hydroxide, 0.5 M sodium acetate and 5% (v/v) ethylenediamine mixture, and the flow rate is 0.7 mL/min. Optimized pulse conditions include a -200 mV (vs. Ag/AgCl reference electrode) detection potential(Ed) for 60 msec and 50 mV cleaning potential (Ec) for 120 msec. The silver working electrode surface is not poisoned by cyanide or sulfide, and the PAD maintains long-term stability without loss of sensitivity and reproducibility at these pulse conditions. The detection limit of cyanide and sulfide separated by ion chromatography using an anion exchange column is 0.1 ppm and 0.05 ppm, respectively.

A Study on the Preliminary Ship Design Method using Deterministic Approach and Probabilistic Approach (확정론적 기법 및 확률론적 기법을 적용한 선박 초기 설계 방법에 관한 연구)

  • 양영순;박창규;유원선
    • Journal of the Society of Naval Architects of Korea
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    • v.41 no.3
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    • pp.49-59
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    • 2004
  • The paper describes the preliminary ship design method using deterministic approach and probabilistic approach. In deterministic approach, there are computational aspects to applying not only the integration concurrently of principal dimension decisions and hull form variations but also hydrostatic coefficients that applied to optimization iterative process. Therefore, this paper developed that actual design concept at the preliminary ship design more than sequential design which separated in principal dimension decisions and hull form variations. Furthermore, a probabilistic approach at the preliminary ship design is applied to efficiently solve design information uncertainty that compared to deterministic approach.

Optimal Scheduling of Level 5 Electric Vehicle Chargers Based on Voltage Level

  • Sung-Kook Jeon;Dongho Lee
    • Journal of the Korean Society of Industry Convergence
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    • v.26 no.6_1
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    • pp.985-991
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    • 2023
  • This study proposes a solution to the voltage drop in electric vehicle chargers, due to the parasitic resistance and inductance of power cables when the chargers are separated by large distances. A method using multi-level electric vehicle chargers that can output power in stages, without installing an additional energy supply source such as a reactive power compensator or an energy storage system, is proposed. The voltage drop over the power cables, to optimize the charging scheduling, is derived. The obtained voltage drop equation is used to formulate the constraints of the optimization process. To validate the effectiveness of the obtained results, an optimal charging scheduling is performed for each period in a case study based on the assumed charging demands of three connected chargers. From the calculations, the proposed method was found to generate an annual profit of $20,800 for a $12,500 increase in installation costs.

Development of Technology for Recovering Valuable Metals in Detoxified Waste Asbestos-Containing Waste (무해화된 폐석면에 함유된 유가금속 회수 기술 개발)

  • Kim, Dong Nyeon;Yang, Dong Hyeon;Kim, Seok Chan
    • Applied Chemistry for Engineering
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    • v.31 no.4
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    • pp.438-442
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    • 2020
  • Studies on the recovery conditions and optimization process for valuable metal recovery through chemical treatment from detoxified asbestos-containing waste composed of calcium silicate, larnite, merwinite, and akermanite were conducted. The main components, Si, Ca, and Mg, of detoxified asbestos-containing waste (DACW) were separated and recovered in the form of SiO2, CaSO4, and Mg(OH)2 compounds, respectively. Each separated component was confirmed through X-ray diffraction (XRD) and inductively coupled plasma spectrometer (ICP) analysis. The recovery conditions for each component were first treating them with an acid to separate SiO2 and subsequently with H2SO4 to recover Ca in the form of sulfate, CaSO4. The remaining Mg was recovered by precipitation with Mg(OH)2 under strong basic conditions. This study suggested that it is possible to convert existing treatment process of asbestos waste by landfill through recovering the components into a resource-recycling green technology.

Flying-Wing Type UAV Design Optimization for Flight Stability Enhancement (전익기형 무인기의 비행 안정성 향상을 위한 형상 최적화 연구)

  • Seong, Dong-gyu;Juliawan, Nadhie;Tyan, Maxim;Kim, Sanho;Lee, Jae-woo
    • Journal of the Korean Society for Aeronautical & Space Sciences
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    • v.48 no.10
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    • pp.809-819
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    • 2020
  • In this study, the twist angle and wing planform shapes were selected as design variables and optimized to secure the stability of the flying-wing type UAV. Flying-wing aircraft has no separated fuselage and tails, which has advantages in aerodynamic characteristics and stealth performance, but it is difficult to secure the flight stability. In this paper, the sweep back angle and twist angle were optimized to obtain the lateral stability, the static margin and wing planform shapes were optimized to improve the longitudinal stability of the flying-wing, then effect of the twist angle was confirmed by comparing the stability of the shape with the winglet and the shape with the twist angle. In the optimization formulation, focusing on improving stability, constraints were established, objective functions and design variables were set, then design variable sensitivity analysis was performed using the Sobol method. AVL was used for aerodynamic analysis and stability analysis, and SQP was used for optimization. The CFD analysis of the optimized shape and the simulation of the dynamic stability proved that the twist angle can be applied to the improvement of the lateral stability as well as the stealth performance in the flying-wing instead of the winglet.

Joint Space-time Coding and Power Domain Non-orthogonal Multiple Access for Future Wireless System

  • Xu, Jin;Ding, Hanqing;Yu, Zeqi;Zhang, Zhe;Liu, Weihua;Chen, Xueyan
    • KSII Transactions on Internet and Information Systems (TIIS)
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    • v.14 no.1
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    • pp.93-113
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    • 2020
  • According to information theory, non-orthogonal transmission can achieve the multiple-user channel capacity with an onion-peeling like successive interference cancellation (SIC) based detection followed by a capacity approaching channel code. However, in multiple antenna system, due to the unideal characteristic of the SIC detector, the residual interference propagated to the next detection stage will significantly degrade the detection performance of spatial data layers. To overcome this problem, we proposed a modified power-domain non-orthogonal multiple access (P-NOMA) scheme joint designed with space-time coding for multiple input multiple output (MIMO) NOMA system. First, with proper power allocation for each user, inter-user signals can be separated from each other for NOMA detection. Second, a well-designed quasi-orthogonal space-time block code (QO-STBC) was employed to facilitate the SIC-based MIMO detection of spatial data layers within each user. Last, we proposed an optimization algorithm to assign channel coding rates to balance the bit error rate (BER) performance of those spatial data layers for each user. Link-level performance simulation results demonstrate that the proposed time-space-power domain joint transmission scheme performs better than the traditional P-NOMA scheme. Furthermore, the proposed algorithm is of low complexity and easy to implement.

Image Dequantization using Optimization (최적화 기반 영상 역양자화)

  • Choi, Min-Gyu;Kim, Tae-Hoon;Ahn, Jong-Woo
    • Journal of KIISE:Computer Systems and Theory
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    • v.34 no.7
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    • pp.296-303
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    • 2007
  • Color quantization replaces the color of each pixel with the closest representative color, and thus it makes the resulting image partitioned into uniformly-colored regions. As a consequence, continuous, detailed variations of color over the corresponding regions in the original image are lost through color quantization. In this paper. we present a novel blind scheme for restoring such variations from a color-quantized input image without it priori knowledge of the quantization method. Our scheme identifies which pairs of uniformly-colored regions in the input image should have continuous variations of color in the resulting image. Then, such regions are seamlessly stitched through optimization while preserving the closest representative colors. The user can optionally indicate which regions should be separated or stitched by scribbling constraint brushes across the regions. We demonstrate the effectiveness of our approach through diverse examples, such as photographs, cartoons, and artistic illustrations.

Inversion of Acoustical Properties of Sedimentary Layers from Chirp Sonar Signals (Chirp 신호를 이용한 해저퇴적층의 음향학적 특성 역산)

  • 박철수;성우제
    • The Journal of the Acoustical Society of Korea
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    • v.18 no.8
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    • pp.32-41
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    • 1999
  • In this paper, an inversion method using chirp signals and two near field receivers is proposed. Inversion problems can be formulated into the probabilistic models composed of signals, a forward model and noise. Forward model to simulate chirp signals is chosen to be the source-wavelet-convolution planewave modeling method. The solution of the inversion problem is defined by a posteriori pdf. The wavelet matching technique, using weighted least-squares fitting, estimates the sediment sound-speed and thickness on which determination of the ranges for a priori uniform distribution is based. The genetic algorithm can be applied to a global optimization problem to find a maximum a posteriori solution for determined a priori search space. Here the object function is defined by an L₂norm of the difference between measured and modeled signals. The observed signals can be separated into a set of two signals reflected from the upper and lower boundaries of a sediment. The separation of signals and successive applications of the genetic algorithm optimization process reduce the search space, therefore improving the inversion results. Not only the marginal pdf but also the statistics are calculated by numerical evaluation of integrals using the samples selected during importance sampling process of the genetic algorithm. The examples applied here show that, for synthetic data with noise, it is possible to carry out an inversion for sedimentary layers using the proposed inversion method.

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