• Bulletin of the Korean Chemical Society
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• 제18권9호
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• pp.1017-1021
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• 1997

Solvolyses of p-methoxyphenyl chloroformate in water, D2O, CH3OD, 50% D2O-CH3OD, and in aqueous binary mixtures of acetone, ethanol and methanol are investigated at 25.0 ℃. Product selectivities are reported at 25 ℃ for a wide range of ethanol-water and methanol-water solvent compositions. The Grunwald-Winstein plots of first-order rate constants for p-methoxyphenyl chloroformate with YCl (based on 1-adamantyl chloride) show marked dispersions into three separate curves for the three aqueous mixtures with a small m value and a rate maximum for aqueous alcohol solvents. Third-order rate constants, kww, kaw, kwa and kaa were calculated from the observed kww and kaa values together with kaw and kwa calculated from the intercept and slope of the plot of 1/S vs. [alcohol]/[water]. The calculated rate constants, kcalc and mol % of ester agree satisfactorily with those of the observed rate constants, kobs and mol % of ester, supporting the stoichiometric solvation effect analysis. The kinetic solvent isotope effects determined in water and methanol are consistent with the proposed mechanism of the general base catalyzed carbonyl addition-elimination.

• Geomechanics and Engineering
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• 제2권1호
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• pp.57-69
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• 2010

A major consideration in the design of tunnels in urban areas is the prediction of the ground movements and surface settlements associated with the tunneling operations. Excessive ground movements can damage adjacent building and utilities. In this paper, a neural network model is used to predict the maximum surface settlement, based on instrumented results from three separate EPB tunneling projects in Singapore. This paper demonstrates that by coupling the trained neural network model to a spreadsheet optimization technique, the reliability assessment of the settlement serviceability limit state can be carried out using the first-order reliability method. With this method, it is possible to carry out sensitivity studies to examine the effect of the level of uncertainty of each parameter uncertainty on the probability that the serviceability limit state has been exceeded.

• 한국지구과학회지
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• 제38권2호
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• pp.105-114
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• 2017

Two dimensional finite element method with quadrilateral basis functions was applied to the spherical high order filter on the spherical surface limited area domain. The basis function consists of four shape functions which are defined on separate four grid boxes sharing the same gridpoint. With the basis functions, the first order derivative was expressed as an algebraic equation associated with nine point stencil. As the theory depicts, the convergence rate of the error for the spherical Laplacian operator was found to be fourth order, while it was the second order for the spherical Laplacian operator. The accuracy of the new high order filter was shown to be almost the same as those of Fourier finite element high order filter. The two-dimension finite element high order filter was incorporated in the weather research and forecasting (WRF) model as a hyper viscosity. The effect of the high order filter was compared with the built-in viscosity scheme of the WRF model. It was revealed that the high order filter performed better than the built in viscosity scheme did in providing a sharper cutoff of small scale disturbances without affecting the large scale field. Simulation of the tropical cyclone track and intensity with the high order filter showed a forecast performance comparable to the built in viscosity scheme. However, the predicted amount and spatial distribution of the rainfall for the simulation with the high order filter was closer to the observed values than the case of built in viscosity scheme.

• 한국건축시공학회:학술대회논문집
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• 한국건축시공학회 2015년도 추계 학술논문 발표대회
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• pp.62-63
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• 2015

In this paper, to prevent overspending of the CM Fee, Agent CM for the normal work-oriented, Willing to separate order model being used in the construction, using a multi-national grouping Go to offer the right company, a number of groups according to the appropriate CM Fee setting is aimed to suggest a reasonable basis. This paper does not use the domestic point of order characteristic of the model, and using a different theory of affinity grouping projection method is presented. The main disadvantage of the domestic order model because it is a contractual relationship, the contractual relationship as unified as possible by the most reasonable way of construction and construction capabilities and commercialization agreement upon the ability of companies also expect to be very helpful. The grouping by using the multi-order construction of the separation problem of the increase and thus the management object construction type administration was to solve the problem.

• 한국통신학회논문지
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• 제39C권7호
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• pp.608-614
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• 2014

이 논문에서는 비간섭 전력 부하 감시에 알맞은 패턴 인식 시스템을 다룬다. 전력 신호의 고차 적률 정보를 써서 전기기구를 효과적으로 분별하여 인식할 수 있는 새로운 특징 추출 방법을 제안한다. 동작 특성이 비슷한 두 전기기구를 제안한 고차 적률 특징과 커널 판별 분석을 쓰는 패턴 인식 시스템이 효과적으로 분별하여 인식할 수 있다는 것을 모의실험으로 보인다.

• 한국정밀공학회지
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• 제22권11호
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• pp.64-71
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• 2005

In order to measure surface roughness profile, stylus type equipments are commonly used, but the stylus keeps contact with surface and damages specimens by its tip pressure. Therefore, optics based measurement systems are developed, and light phase interferometer, which is based on light interference phenomenon, is the most noticeable research. However, light interference based measurements require translation mechanisms of nano-meter order in order to generate phase differences or multiple focusing, thus the systems cannot satisfy the industrial need of on-the-machine and in-process measurement to achieve factory automation and productive enhancement. In this research, we focused light reflectance phenomenon rather than the light interference, because reflectance based method do not need translation mechanisms. However, the method cannot direct]y measure surface roughness profile, because reflected light consists of several components and thus it cannot supply surface height information with its original form. In order to overcome the demerit, we newly proposed an image processing based algorithm, which can separate reflected light components and conduct parameterization and reconstruction process with respect to surface height information, and then confirmed the reliability of proposed algorithm by experiment.

• 한국주거학회논문집
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• 제4권1호
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• pp.47-55
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• 1993

The research was carried out by posing a questionnaire, making middle and high schoolstudents 549 in Taehu an object of this research, in order to grasp the residential outlook of juveniles.1. The first order of reason why they have resided in present their houses was by a school group and their parents' choice and work place and second order of reason was by their parents' choice, life convenience in present house add traffice convenience And there was littledifference in the first and second residential reasons according to sew.2. In compareson with past and present house type, past and present house type shewed same tendency and future wanted house type was separate house absolutely.3. Points to be considered in selectong future were in the order of facilities, traffice,, surrounding, educational, social and economical circumstances. There was little difference in almost items to be considered in choosing accordant to sew. But in case of schoolgirls, they consisered more items in selecting houses than in schoolboys.4. As a result of researching ideal house of juvenile, happy family was most Preferred and the desire to possess house was expressed strongly.5. The first value on house was health of family, the stability, the stabi]ity and the residential convenience. And schoolboys attacged more importance to the gealth of family, ghe stability and the education fer children than in case of school-girls but on the other hand school girls attached more importance to economical value house and happy and harmonious family.

• International journal of advanced smart convergence
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• 제10권4호
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• pp.256-262
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• 2021

In order for small electric vehicles to drive on hilly roads in Korea, methods to improve the climbing ability and power performance of vehicles should be taken. In order to improve the power performance of small electric vehicles, the performance of motors mounted on electric vehicles should be improved. However, if the performance of the motor is improved to improve the power performance of the electric vehicle, it is possible to lower the price competitiveness accordingly. In addition, the power consumption of the battery is rapidly increased to drive the high-performance motor, so in order to introduce the small electric vehicle into the domestic market, various problems must be overcome. In order to commercialize small electric vehicles that do not emit harmful exhaust gases to the human body in the hilly domestic terrain, it is effective to introduce a separate continuously variable transmission system that can improve the climbing ability and power transmission ability. In this study, we propose a proprietary model of continuously variable transmissions that can be applied to small electric vehicles. The proposed continuously variable transmission is equipped with a spring in the driving pulley and the driven pulley, and has the advantage of performing a shift that increases torque in a situation where the vehicle needs to increase torque when driving on a hill. In addition, the basic design for commercialization of the proposed continuously variable transmission was carried out, and the prototype manufactured and attached to the body of a small electric vehicle.

• 호남수학학술지
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• 제41권2호
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• pp.403-420
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• 2019

The Helmholtz equation represents acoustic or electromagnetic scattering phenomena. The Method of Lines are known to have many advantages in simulation of forward and inverse scattering problems due to the usage of angle rays and Bessel functions. However, the method does not account for the jump phenomena on obstacle boundary and the approximation includes many high order Bessel functions. The high order Bessel functions have extreme blow-up or die-out features in resonance region obstacle boundary. Therefore, in particular, when we consider shape reconstruction problems, the method is suffered from severe instabilities due to the logical confliction and the severe singularities of high order Bessel functions. In this paper, two approximation formulas for the Helmholtz equation are introduced. The formulas are new and powerful. The derivation is based on Method of Lines, Huygen's principle, boundary jump relations, Addition Formula, and the orthogonality of the trigonometric functions. The formulas reduce the approximation dimension significantly so that only lower order Bessel functions are required. They overcome the severe instability near the obstacle boundary and reduce the computational time significantly. The convergence is exponential. The formulas adopt the scattering jump phenomena on the boundary, and separate the boundary information from the measured scattered fields. Thus, the sensitivities of the scattered fields caused by the boundary changes can be analyzed easily. Several numerical experiments are performed. The results show the superiority of the proposed formulas in accuracy, efficiency, and stability.

• 산업공학
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• 제15권1호
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• pp.26-39
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• 2002

Two key data areas of the integrated production database in computer-integrated manufacturing (CIM) systems are the product structure in the forms of bills of material(BOM) and the process structure in the forms of routings. The great majority of existing information systems regard the BOM and routing as two separate data entities, possibly with some degree of cross-referencing. This paper proposes new information structure called the bills of material and routings(BMR) that logically integrates the BOM and routings for the CIM systems in ship production. The characteristics of ship production are described as: 1) make-to-order production type, 2) combined manufacturing principles (workshop production and construction site production), 3) significant overlapping of design, planning and manufacturing, 4) very long order throughput time, 5) complex product structure and production process. The proposed BMR systematically manages ail parts and operations data needed ship production considering characteristics of ship production. Also, the BMR situated on the integrated production database more efficiently supports interface between engineering and production functions, and integrates a wide variety of functions within production such as production planning, process planning, operation scheduling, material planning, costing etc., and simplifies information flow between sub-systems in CIM systems.