• Title/Summary/Keyword: self-similar solution

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On Compositional Convection in Near-Eutectic Solidification System Cooled from a Bottom Boundary

  • Hwang, In Gook
    • Korean Chemical Engineering Research
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    • v.55 no.6
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    • pp.868-873
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    • 2017
  • Natural convection is driven by the compositional buoyancy in solidification of a binary melt. The stabilities of convection in a growing mushy layer were analyzed here in the time-dependent solidification system of a near-eutectic melt cooled impulsively from below. The linear stability equations were transformed to self-similar forms by using the depth of the mushy layer as a length scale. In the liquid layer the stability equations are based on the propagation theory and the thermal buoyancy is neglected. The critical Rayleigh number for the mushy layer increases with decreasing the Stefan number and the Prandtl number. The critical conditions for solidification of aqueous ammonium chloride solution are discussed and compared with the results of the previous model for the liquid layer.

Seepage characteristics of the leaching solution during in situ leaching of uranium

  • Sheng Zeng ;Jiayin Song ;Bing Sun;Fulin Wang ;Wenhao Ye;Yuan Shen;Hao Li
    • Nuclear Engineering and Technology
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    • v.55 no.2
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    • pp.566-574
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    • 2023
  • Investigating the seepage characteristics of the leaching solution in the ore-bearing layer during the in situ leaching process can be useful for designing the process parameters for the uranium mining well. We prepared leaching solutions of four different viscosities and conducted experiments using a self-developed multifunctional uranium ore seepage test device. The effects of different viscosities of leaching solutions on the seepage characteristics of uranium-bearing sandstones were examined using seepage mechanics, physicochemical seepage theory, and dissolution erosion mechanism. Results indicated that while the seepage characteristics of various viscosities of leaching solutions were the same in rock samples with similar internal pore architectures, there were regular differences between the saturated and the unsaturated stages. In addition, the time required for the specimen to reach saturation varied with the viscosity of the leaching solution. The higher the viscosity of the solution, the slower the seepage flow from the unsaturated stage to the saturated stage. Furthermore, during the saturation stage, the seepage pressure of a leaching solution with a high viscosity was greater than that of a leaching solution with a low viscosity. However, the permeability coefficient of the high viscosity leaching solution was less than that of a low viscosity leaching solution.

Investigation of Self-assembly Structure and Properties of a Novel Designed Lego-type Peptide with Double Amphiphilic Surfaces

  • Wang, Liang;Zhao, Xiao-Jun
    • Bulletin of the Korean Chemical Society
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    • v.31 no.12
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    • pp.3740-3744
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    • 2010
  • A typically designed 'Peptide Lego' has two distinct surfaces: a hydrophilic side that contains the complete charge distribution and a hydrophobic side. In this article, we describe the fabrication of a unique lego-type peptide with the AEAEYAKAK sequence. The novel peptide with double amphiphilic surfaces is different from typical peptides due to special arrangement of the residues. The results of CD, FT-IR, AFM and DLS demonstrate that the peptide with the random coil characteristic was able to form stable nanostructures that were mediated by non-covalent interactions in an aqueous solution. The data further indicated that despite its different structure, the peptide was able to undergo self-assembly similar to a typical peptide. In addition, the use of hydrophobic pyrene as a model allowed the peptide to provide a new type of potential nanomaterial for drug delivery. These efforts collectively open up a new direction in the fabrication of nanomaterials that are more perfect and versatile.

Determination of Horizontal Coefficient of Consolidation from the Self-boring Pressuremeter Holding Test by Considering Pore Pressure Dissipation Trend (간극수압 소산경향을 고려한 자가굴착식 프레셔메터로부터의 수평압밀계수 결정법)

  • 김영상
    • Journal of the Korean Geotechnical Society
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    • v.20 no.3
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    • pp.151-159
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    • 2004
  • This paper describes a systematic way of identifying the horizontal coefficient of consolidation of clayey soil by applying an optimization technique to the early part of dissipation data measured from the self-boring pressuremeter strain holding test. An analytical solution developed by Randolph & Wroth (1979) was implemented in normalized form to express the build-up of excess pore pressures as a function of the rigidity index and subsequent dissipation of excess pore pressures around a pressuremeter Horizontal coefficient of consolidation was determined by minimizing the differences between theoretical and measured excess pore pressure curves over 50% degree of dissipation range using optimization technique. The effectiveness of the proposed back-analysis method was examined against the real fled performances obtained from pressuremeter strain holding tests at Gimje and Yangsan site. It is shown that the proposed back-analysis method can evaluates the rational horizontal coefficient of consolidation, which is similar to those obtained from the piezocone dissipation test. Furthermore, proposed method can evaluate appropriate coefficient of consolidation for soil under partially drained condition.

Preparation of highly hydrophobic PVDF hollow fiber composite membrane with lotus leaf-like surface and its desalination properties

  • Li, Hongbin;Zi, Xingchen;Shi, Wenying;Qin, Longwei;Zhang, Haixia;Qin, Xiaohong
    • Membrane and Water Treatment
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    • v.10 no.4
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    • pp.287-298
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    • 2019
  • Lotus leaf has a special dual micro and nano surface structure which gives its highly hydrophobic surface characteristics and so-called self cleaning effect. In order to endow PVDF hollow fiber membrane with this special structure and improve the hydrophobicity of membrane surface, PVDF hollow fiber composite membranes was obtained through the immersion coating of poly(vinylidene fluoride-co-hexafluoropropylene) (PVDF-HFP) dilute solution on the outside surface of PVDF support membrane. The prepared PVDF composite membranes were used in the vacuum membrane distillation (VMD) for the desalination. The effects of PVDF-HFP dilute solution concentration in the dope solution and coating time on VMD separation performance was studied. Membranes were characterized by SEM, WCA measurement, porosity, and liquid entry pressure of water. VMD test was carried out using $35g{\cdot}L^{-1}$ NaCl aqueous solution as the feed solution at feed temperature of $30^{\circ}C$ and the permeate pressure of 31.3 kPa. The vapour flux reached a maximum when PVDF-HFP concentration in the dilute solution was 5 wt% and the coating time was kept in the range of 10-60 s. This was attributed to the well configuration of micro-nano rods which was similar with the dual micro-nano structure on the lotus leaf. Compared with the original PVDF membrane, the salt rejection can be well maintained which was greater than 99.99 % meanwhile permeation water conductivity was kept at a low value of $7-9{\mu}S{\cdot}cm^{-1}$ during the continuous testing for 360 h.

The Behavior of Solutes in Nonaqueous Solutions (Ⅱ). Relative Viscosities and Osmotic Coefficients of Urea, 1,3-Dimethylurea, Acetamide, and Propionamide (물아닌 용액에서의 용질의 행동에 관한 연구 (제2보). 요소, 1,3-디메틸요소, 아세트아미드와 프로피온아미드의 상대점도와 삼투계수)

  • Si-Joong Kim;Young-Kook Shin
    • Journal of the Korean Chemical Society
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    • v.24 no.3
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    • pp.209-217
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    • 1980
  • The relative viscosities and osmotic coefficients of solutions of urea, 1,3-dimethyl-urea(DMU), acetamide(AA), and propionamide (PA) in dimethylsulfoxide(DMSO), water, methanol, and in ethanol have been measured at 25 and $45^{\circ}$C by viscometry and osmometry. Viscosity increment in nonaqueous solutions decreased with increasing of the partial molal volumes of the solutes, but in aqueous solution the result was inversed. Viscosity increment of aqueous solution was smaller than that of aqueous DMU solution, but that of nonaqueous urea solution was larger than that of DMU. Amides, however, showed similar viscosity increment in any solvent.Osmotic coefficients of aqueous solution of urea were larger than those of DMU. In the nonaqueous solutions urea exhibited larger deviation from Raoult's law than DMU. The results indicated that urea molecules break water-structure in water, self-associate in DMSO, and showed larger solute-solvent interaction in alcohols than DMU. It can be also confirmed that amides break alcohol structure to a greater extent than any other solutes.

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The Strategy of Health Approach to Cope with the Environmental Change in 2000's (2000년대의 환경변화에 대응한 건강접근전략)

  • 변종화
    • Korean Journal of Health Education and Promotion
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    • v.7 no.2
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    • pp.1-14
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    • 1990
  • This papaer discusses the recent tendencies of health approach in the developed countries and suggests the strategy of health approach in order to cope with the changing environmental conditions of Korea in 2000's. In 2000's, Korea will have the environmental conditions and health problems similar to those of the developed countries at present. The American and European developed countries have shown the integrative approach trend by the interdisciplinary cooperation based on the holistic health conception, for example, as in the behavioral medicine, with the active drive of the medical self care movement and the national health preactice movement. The basic solution to the 2000's main health problems such as high morbidity of chronic diseases and high medical expenditure is to decrease the health need through the health promotion, disease prevention and early. ditection and early treatment of disease. The above actions need to induce the public to change their health behavior in the desirable direction through the national health practice movement and the health self care movement. The succeed of the movements depends upon how to use effectively the mass media, health and administrative organizations, schools, industrial and medical insurance organizations with the strong government support of health and preventive policies and programs.

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Preparation of Self-Cleaning Coating Films with Nano- and Microstructure (나노마이크로 구조의 자기세정 기능성 코팅막의 제조)

  • Jeong, A-Rong;Kim, Jun-Su;Yun, Jon-Do
    • Korean Journal of Materials Research
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    • v.22 no.8
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    • pp.416-420
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    • 2012
  • Recently nanoscience and nanotechnology have been studied intensively, and many plants, insects, and animals in nature have been found to have nanostructures in their bodies. Among them, lotus leaves have a unique nanostructure and microstructure in combination and show superhydrophobicity and a self-cleaning function to wipe and clean impurities on their surfaces. Coating films with combined nanostructures and microstructures resembling those of lotus leaves may also have superhydrophobicity and self-cleaning functions; as a result, they could be used in various applications, such as in outfits, tents, building walls, or exterior surfaces of transportation vehicles like cars, ships, or airplanes. In this study, coating films were prepared by dip coating method using polypropylene polymers dissolved in a mixture of solvent, xylene and non-solvent, methylethylketon, and ethanol. Additionally, attempts were made to prepare nanostructures on top of microstructures by coating with the same coating solution with an addition of carbon nanotubes, or by applying a carbon nanotube over-coat on polymer coating films. Coating films prepared without carbon nanotubes were found to have superhydrophobicity, with a water contact angle of $152^{\circ}$ and sliding angle less than $2^{\circ}$. Coating films prepared with carbon nanotubes were also found to have a similar degree of superhydrophobicity, with a water contact angle of 150 degrees and a sliding angle of 3 degrees.

A Study on Self-medication for Health Promotion of the Silver Generation

  • Oh, Soonhwan;Ryu, Gihwan
    • International Journal of Advanced Culture Technology
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    • v.8 no.4
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    • pp.82-88
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    • 2020
  • With the development of medical care in the 21st century and the rapid development of the 4th industry, electronic devices and household goods taking into account the physical and mental aging of the silver generation have been developed, and apps related to health and health are generally developed and operated. The apps currently used by the silver generation are a form that provides information on diseases by focusing on prevention rather than treatment, such as safety management apps for the elderly living alone and methods for preventing diseases. There are not many apps that provide information on foods that have a direct effect and nutrients in that food, and research on apps that can obtain information about individual foods is insufficient. In this paper, we propose an app that analyzes food factors and provides self-medication for health promotion of the silver generation. This app allows the silver generation to conveniently and easily obtain information such as nutrients, calories, and efficacy of food they need. In addition, this app collects/categorizes healthy food information through a textom solution-based crawling agent, and stores highly relevant words in a data resource. In addition, wide deep learning was applied to enable self-medication recommendations for food. When this technique is applied, the most appropriate healthy food is suggested to people with similar eating patterns and tastes in the same age group, and users can receive recommendations on customized healthy foods that they need before eating. This made it possible to obtain convenient healthy food information through a customized interface for the elderly through a smartphone.

Preparation of $Mg(OH)_2$and MgO from Acid Leaching $Mg^{++}$ Solution (산 침출$Mg^{++}$액으로부터 $Mg(OH)_2$및 MgO 粉末의 製造)

  • 최용각;이종현;원창환;이갑호
    • Resources Recycling
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    • v.10 no.5
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    • pp.16-21
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    • 2001
  • Ultrafine $Mg(OH)l_2$and MgO powders were recovered from the waste solution containing $Mg^{++}$ which was a by-product of SHS (Self-propagating High temperature Synthesis)process. The optimum experimental conditions to prepare $Mg(OH)_2$were 13.0 of pH and 0.7M of $Mg^{++}$ content with addition of 9M of KOH as a pH regulator in acid leaching solution. Complete pre-cipitation of Mg(OH)$_2$from $Mg^{++}$ was realized at that condition. The dehydration reaction of the prepared Mg(OH)$_2$was studied by DSC, and the result was used for calcination process. In order to obtain MgO powder, dried Mg(OH)2 powder was calcined at $400~450^{\circ}C$. Particle size and shape of the prepared $Mg(OH)_2$and MgO powder was similar to those of the commercial powders.

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