• 한국전기전자재료학회:학술대회논문집
• /
• 한국전기전자재료학회 2002년도 하계학술대회 논문집 Vol.3 No.2
• /
• pp.666-669
• /
• 2002

The differences of the effects of mechanical substance pre-activation in the mills with divers force effect schemes on the self-propagating high temperature synthesis (SHS) of the $SiO_2$ + 37.5% Al system were investigated. The power saturation of activated material state are estimated referring on the variations of dilatometry curve paths. The effects of activation time on the temperature of sample self-ignited in the furnace, combustion temperature and completeness of the quartz reaction with aluminium were determined. The enhancing effects of organic modifiers of quartz particle surfaces on the further SHS synthesis development were shown.

• 대한금속재료학회지
• /
• 제49권12호
• /
• pp.1001-1004
• /
• 2011

The formation of TiC and $Al_2O_3$ particles based on the self-combustion reaction of the $Al-TiO_2-C-CuO$ system in an Al alloy melt was investigated. With an adequate amount of CuO in the system, a spontaneous reaction occurred within the Al alloy melt at $850^{\circ}C$ and thereafter was self-maintained, producing an Al matrix composite reinforced with thermodynamically stable TiC and $Al_2O_3$ particles. TiC and $Al_2O_3$ particles contributed to a considerable increase in the strength and stiffness, demonstrating the feasibility of this method as a practical application for structural parts.

• 한국전기전자재료학회:학술대회논문집
• /
• 한국전기전자재료학회 2001년도 추계학술대회 논문집 Vol.14 No.1
• /
• pp.38-41
• /
• 2001

The combustion characteristics of the disilicides molybdenum system have been studied experimentally. The pertinent reaction parameters that control self-propagating high temperature synthesis reactions have been examined. These include reactant particle size, powder mixing and compaction, reaction stoichiometry, diluents. The influence of experimental variables on integrity, uniformity, structure, and related material properties will be discussed. Formation mechanism of $MoSi_2$ during SHS might be different and depending on experimental conditions.

• 한국전기전자재료학회:학술대회논문집
• /
• 한국전기전자재료학회 2001년도 추계학술대회 논문집
• /
• pp.38-41
• /
• 2001

The combustion characteristics of the disilicides molybdenum system have been studied experimentally. The pertinent reaction parameters that control self-propagating high temperature synthesis reactions have been examined. These include reactant particle size, powder mixing and compaction, reaction stoichiometry, diluents. The inf1uence of experimental variables on integrity, uniformity, structure, and related material properties will be discussed. Formation mechanism of MoSi$_2$ during SHS might be different and depending on experimental conditions.

• 한국세라믹학회지
• /
• 제31권11호
• /
• pp.1249-1258
• /
• 1994

Titanium carbide was synthesized by reacting the prepared titanium powder and carbon black using SHS method sustains the reaction spontaneously, utilizing heat generated by the exothermic reaction itself. In this process, the effect of the particle size of titanium powder on combustion temperature and combustion wave velocity was investigated. By controlling combustion temperature and combustion wave velocity via mixing Ti and C powder with TiC, the reaction kinetics of TiC formation by SHS method was considered. Without reference to the change of combustion temperature and combustion wave velocity, TiC was easily synthesized by combustion reaction. As the particle size of titanium powder was bigger, or, as the amount of added diluent(TiC) increased, combustion temperature and combustion wave velocity were found to be decreased. The formation of TiC by combustion reaction in the Ti-C system seems to occur via two different mechanisms. At the beginning of the reaction, when the combustion temperatures were higher than 2551 K, the reaction was considered to be controlled by the rate of dissolution of carbon into a titanium melt with an apparent activation energy of 148 kJ/mol. For combustion temperatures less than 2551 K, it was considered to be controlled by the atomic diffusion rate of carbon through a TiC layer with an apparent activation energy of 355 kJ/mol. The average particle size of the synthesized titanium carbide was smaller than that of the starting material(Ti).

• 한국세라믹학회지
• /
• 제36권2호
• /
• pp.203-209
• /
• 1999

Si 기판위에 Ba2YCu3O7-$\delta$ 고온초전도체를 응용하기 위해 요구되는 buffer층으로 유망한 재료인 LaAlO3 단일상 분말을 고상반응법과 자발착한 연소반응법으로 제조하였다. 제조된 LaAlO3 분말의 입자형태와 결정상태는 scanning electron microscope (SEM)과 X-ray diffractometer (XRD)를 이용하여 분석하였다. 분말의 비표면적과 소결특성은 각각 Brunauer-Emmett-Teller(BET) 방법과 dilatometer를 측정하였다. 고상반응법으로 LaAlO3 분말을 제조할 때에는 하소온도를 150$0^{\circ}C$까지 높게 하여도 단일상을 얻는 것이 어려웠으나 자발착한 연소반응법에 의한 분말제조는 $650^{\circ}C$의 저온에서 하소하여도 쉽게 얻을 수 있었다. Dilatometer 측정을 통하여 분석해 보면, 고상반응법에 의한 분말보다 자발착한 연소반응법에 의한 분말로 제조된 소결체가 고상반응법에 의한 소결체에 비해 1.4배나 큰 소멸밀도(98.87%)를 가졌다. 이렇게 소결밀도에서 큰 차이가 나는 것은 자발착한 연소방법에 의한 분말의 평균 입자크기가 nano crystal size이고 비표면적 값(56.54 $m^2$/g)이 매우 크기 때문이다. 두가지 방법으로 제조된 분말을 이용, LaAlO3 layer를 스크린 프린팅과 소결법으로 Si 기판상에 제조하였으며 자발착한 연소합성법으로 제조된 분말은 110$0^{\circ}C$에서 우수한 소결특성을 나타내었다.

• 한국분말재료학회지
• /
• 제2권2호
• /
• pp.149-157
• /
• 1995

In this study, an attempt was made to fabricate TiAl as well as its in situ composite via combustion synthesis. The processing variable of the combustion synthesis which include aluminum content and the heating rate were found to affect the combustion temperature. The combustion temperature measured, however, was lower than the melting temperature of TiAl and the reaction product were found to include incomplet reaction products. Carbon was added in order to increase the combustion temperature as well as to form in situ reinforcements. The reaction products showed homogeneous microstructures with carbide phases formed within indicating that the addition of carbon increased the combustion temperature above the melting temperature of TiAl.

• 한국세라믹학회지
• /
• 제37권5호
• /
• pp.444-452
• /
• 2000

Dense composites of titanium matrix and Al2O3 matrix with reinforcements of carbon or titanium carbide fibers were successfully fabricated by high-pressure self-combustion sintering method or combustion reacton under 30 MPa of uniaxial pressure with an aid of external heating in vaccum. It was found that the fibers were uniformly distributed in the matrix, and aligned in a phase perpendicular to the pressure axis. As a moel ratio of Ti/C or reaction time increased, the density of Ti-matrix composite increased Micro pores around fibers could be removed by using clean carbon fibers without sizing agent on their surface. The evolution of carbide fibers from carbon fibers was observed. The composition of the various phases around fibers were analyzed.

• 한국연소학회지
• /
• 제8권1호
• /
• pp.17-24
• /
• 2003

The conventional regenerative system has a high thermal efficiency as well as energy saving using the high preheated combustion air. in spite of these advantages, it can not avoid high nitric oxide emissions. Recently, flameless combustion has received much attention to solve these problems. In this research, numerical analysis is performed for flow-combustion phenomena in the self regenerative burner. In this analysis we used Fluent 6.0 code. the that is developed for commercial use, Methane gas is used as a fuel and two-step reaction model for methane and Zeldovich mechanism for NO generation are used. the velocity of the preheated combustion air is used as a parameter and we analyze the characteristics of flow-field, temperature distributions and NO emissions. Due to the increased recirculation rate, the maximum temperature of flame is significantly increased and NOx emissions is reduced.

• 대한금속재료학회지
• /
• 제50권9호
• /
• pp.677-684
• /
• 2012

A feasible way to fabricate in-situ Al/TiC composites was investigated. An elemental mixture of $Al-TiO_2-C$ pellet was directly added into an Al melt at $800-920^{\circ}C$ to form TiC by self-combustion reaction. The addition of CuO initiates the self-combustion reaction to form TiC in $1-2{\mu}m$ at the melt temperature above $850^{\circ}C$. Besides the CuO addition, a diluent element of excess Al plays a significant role in the TiC formation by forming a precursor phase, $Al_3Ti$. Processing parameters such as CuO content, the amount of excess Al and the melt temperature, have affected the combustion reaction and formation of TiC, and their influences on the microstructures of in-situ Al/TiC composites are examined.