• Bulletin of the Korean Chemical Society
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• v.28 no.12
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• pp.2354-2358
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• 2007

MALDI-TOF-MS technique was applied to obtain structural and compositional information of synthetic polyamides, Nylon6 and Nylon66. Mass spectra of both the original and the hydrolyzed polyamide samples were analyzed using the self calibration method as well as the internal calibration method with the standard materials of known masses. The MALDI-TOF mass spectra of Nylon6 samples showed the presence of protonated, sodiated, and potassiated ions that were assigned to cyclic and NH2/COOH terminated linear oligomers. From the MALDI-TOF mass spectra of Nylon66 samples, the potassiated linear oligomers with three different end groups are identified as well as the cyclic oligomers, i.e., NH2/COOH terminated oligomers, NH2/NH2 terminated oligomers, and COOH/COOH terminated oligomers. Full characterization of the molecular species and end groups present in the polyamide samples has been achieved, and also the changes in mass spectral patterns after the hydrolysis of the samples are presented.

• Bulletin of the Korean Chemical Society
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• v.28 no.12
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• pp.2359-2362
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• 2007

MALDI-TOF-MS technique was applied to obtain structural and compositional information of synthetic polyamides, Nylon6 and Nylon66. Mass spectra of both the original and the hydrolyzed polyamide samples were analyzed using the self calibration method as well as the internal calibration method with the standard materials of known masses. The MALDI-TOF mass spectra of Nylon6 samples showed the presence of protonated, sodiated, and potassiated ions that were assigned to cyclic and NH2/COOH terminated linear oligomers. From the MALDI-TOF mass spectra of Nylon66 samples, the potassiated linear oligomers with three different end groups are identified as well as the cyclic oligomers, i.e., NH2/COOH terminated oligomers, NH2/NH2 terminated oligomers, and COOH/COOH terminated oligomers. Full characterization of the molecular species and end groups present in the polyamide samples has been achieved, and also the changes in mass spectral patterns after the hydrolysis of the samples are presented.

• Journal of Environmental Science International
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• v.21 no.12
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• pp.1449-1454
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• 2012

The ion selective microelectrodes (ISME) have been applied to observe the continuous profiles of NO3-N and NH4-N in bulk solutions or biofilms. In order to evaluate the performance and applicability of ion concentration measuring system, the characteristics, such as slope of calibration curve, detection limit and potentiometric selectivity coefficient were investigated. The slopes of calibration curve showed high degree of correspondence for each target ion concentrations. And the detection limits of nitrate and ammonia ion selective microelectrode were 10-4.7 M and 10-4.4 M, respectively. These ion selective microelectrodes were proved that their own performance could be maintained for 16 days after making. NO3-N and NH4-N selective microelectrodes were also adapted to detect the continuous ion profiles of cilia media packed MLE (Modified Ludzack-Ettinger) process. And the monitored nitrate and ammonia ion profiles with the ion selective microelectrode were stable and well corresponded to the results with conventional ion chromatograph. However, the electric potential was unstable until 8 hr because of the unknown noise. The tip shape and performance of the ion selective microelectrode was stably kept over 2 days continuous monitoring.

• Bulletin of the Korean Chemical Society
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• v.32 no.2
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• pp.477-482
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• 2011

The structural analysis of polytrimethylene terephthalate (PTT) and characterization of the hydrolytic degradation products after acid hydrolysis were performed using MALDI-TOF mass spectrometry. Mass spectra of the PTT samples were analyzed using a self-calibration method as well as an internal calibration method with standard materials of known masses. PTT structures constituting the samples were determined from the analyses of the spectra, and their relative compositions were estimated. The MALDI-TOF mass spectra of the acid-hydrolyzed PTT sample showed three main series of oligomer products with different end groups in accordance with the hydrolysis schemes. From the spectra of both $Na^+$ and $K^+$ adducts, it was concluded that the PTT samples have higher affinity for $Na^+$ compared with $K^+$ and therefore show higher ionization efficiency with sodium ions when dithranol is used as a matrix. Two different wavelength laser beams ($\lambda$ = 337 nm and 355 nm) were tested and it was observed that the 355 nm beam was more efficient in obtaining the MALDI spectra of PTT using dithranol as a matrix under our experimental conditions.

• Steel and Composite Structures
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• v.34 no.4
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• pp.561-580
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• 2020

Buckling restrained braces (BRBs) were developed as an enhanced alternative to conventional braces by restraining their global buckling, thus allowing development of a stable quasi-symmetric hysteretic response. A wider adoption of buckling restrained braced frames is precluded due to proprietary character of most BRBs and the code requirement for experimental qualification. To overcome these problems, BRBs with capacities corresponding to typical steel multi-storey buildings in Romania were developed and experimentally tested in view of prequalification. In the second part of this paper, a complex nonlinear numerical model for the tested BRBs was developed in the finite element environment Abaqus. The calibration of the numerical model was performed at both component (material models: steel, concrete, unbonding material) and member levels (loading, geometrical imperfections). Geometrically and materially nonlinear analyses including imperfections were performed on buckling restrained braces models under cyclic loading. The calibrated models were further used to perform a parametric study aiming at assessing the influence of the strength of the buckling restraining mechanism, concrete class of the infill material, mechanical properties of steel used for the core, self-weight loading, and frame effect on the cyclic response of buckling restrained braces.

• The Transactions of the Korean Institute of Electrical Engineers
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• v.43 no.7
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• pp.1206-1213
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• 1994

This paper presents the operation principle and design rule of the Rogowski coil which can measure the transient current and describes the calibration and application experimental results for performance evaluation. It is obtained that the response curves of the Robowski coil with the turns of 300 and the passive integrator to sinusoidal input give a good linearity up to the frequency of 500 [kHz] and the current measurement system gaving the Rogowski coil is the frequency bandwidth of 40 [Hz]~700 [kHz]. As an application experiment for the fabricated modeling power transmission line, the impulse current, which limitates the direct lightning return stroke to overhead ground wire, is measured by the Rogowski coil and its fast Fourier transformation is carried out. The equivalent circuit of the Rogowski coil considering the stray capacitances is proposed, and the theoretical analysis is in good agreement with the measurement results. Also, it is found that for high frequency domain the stray capacitance such as a distributed capacitance to the shield and the capacitance between windings of coil should be considered in designing the Rogowski coils since the resonance originates from the stray capacitance and the self-inductance of the Rogowski coil.

• Journal of the Optical Society of Korea
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• v.19 no.4
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• pp.415-420
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• 2015

A novel method to measure the scale factor for the all-optical atomic spin inertial measurement device (ASIMD) is demonstrated in this paper. The method can realize the calibration of the scale factor by a self-consistent method with small errors in the quiescent state. At first, the matured IMU (inertial measurement unit) device was fixed on an optical platform together with the ASIMD, and it has been used to calibrate the scale factor for the ASIMD. The results show that there were some errors causing the inaccuracy of the experiment. By the comparative analysis of theory and experiment, the ASIMD was unable to keep pace with the IMU. Considering the characteristics of the ASIMD, the mismatch between the driven frequency of the optical platform and the bandwidth of the ASIMD was the major reason. An all-optical atomic spin magnetometer was set up at first. The sensitivity of the magnetometer is ultra-high, and it can be used to detect the magnetization of spin-polarized noble gas. The gyromagnetic ratio of the noble gas is a physical constant, and it has already been measured accurately. So a novel calibration method for scale factor based on the gyromagnetic ratio has been presented. The relevant theoretical analysis and experiments have been implemented. The results showed that the scale factor of the device was $7.272V/^{\circ}/s$ by multi-group experiments with the maximum error value 0.49%.

• Journal of the Korean Institute of Telematics and Electronics C
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• v.35C no.9
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• pp.81-92
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• 1998

A new hybrid technique using several sub-populations having completely different evolutionary behaviors is proposed to increase the possibility to quickly find the global optimum of continuous optimization problem. It has three sub-populations. Two NPOSA algorithms showing good performance in the problem having a rugged fitness function are applied to two sub-populations and a self-adaptive evolutionary algorithm to the other sub-population. Sub-populations evolve in different manners and the interaction among these sub-populations lead to the global optimum quickly. The efficiency of this technique is verified through benchmark test functions. Finally, the algorithm with three sub-populations has been applied to seek for the optimal camera calibration parameters. After an error function has been defined using measured feature points of a calibration block, it has been shown that the algorithm searches for the camera parameters that minimize the error function.

• Proceedings of the Korean Institute of Information and Commucation Sciences Conference
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• v.9 no.1
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• pp.1141-1144
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• 2005

In this paper, we propose an automatic displacement system for testing stability of structure. Photogrammetry is a method which can measure accurate 3D data from 2D images taken from different locations and which is suitable for analyzing and measuring the displacement of structure. This paper consists of camera calibration, feature extraction using coded target & retro-reflective circle, 3D reconstruction and analyzing accuracy. Multi-view camera which is used for measuring displacement of structure is placed with different location respectively. Camera calibration calculates trifocal tensor from corresponding points in images, from which Euclidean camera is calculated. Especially, in a step of feature extraction, we utilize sub-pixel method and pattern recognition in order to measure the accurate 3D locations. Scale bar is used as reference to measure. the accurate value of world coordinate..

• Korean Journal of Remote Sensing
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• v.19 no.6
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• pp.431-445
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• 2003

In this paper, we experimentally investigated the precision of 3D positioning using 4S-Van images in photograrmmetric perspective. The 3D calibration target was built over building facade outside and was captured separately by two CCD cameras installed in 4S-Van. After then, we determined the interior orientation parameter for each CCD camera through self-calibration technique. With the interior orientation parameter computed, the bundle adjustment was performed to obtain the exterior orientation parameters simultaneously for two CCD cameras using calibration target image and object coordinates. The reverse lens distortion coefficients were computed and acquired by least squares method so as to introduce lens distortion into epipolar line. It was shown that the reverse lens distortion coefficients could transform image coordinates into lens distorted image coordinates within about 0.5 pixel. The proposed semi-automatic matching scheme incorporated with lens distorted epipolar line was implemented with scene images captured by 4S-Van in moving. The experimental results showed that the precision of 3D positioning from 4S-Van images in photograrmmetric perspective is within 2cm in the range of 20m from the camera.