• 대한금속재료학회지
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• 제50권8호
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• pp.557-562
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• 2012

Self-organized ruthenium (Ru) dots were fabricated by $400^{\circ}C$ RTA (rapid thermal annealing) and ALD (atomic layer deposition). The dots were produced under the $400^{\circ}C$ RTA conditions for 10, 30 and 60 seconds on all Si(100)/200 nm-SiO2, glass, and glass/fluorine-doped tin oxide (FTO) substrates. Electrical sheet resistance, and surface microstructure were examined using a 4-point probe and FE-SEM (field emission scanning electron microscopy). Ru dots were observed when a 30 nm-Ru layer on a Si(100)/200 nm-SiO2 substrate was annealed for 10, 30 and 60 seconds, whereas the dots were only observed on a glass substrate when a 50 nm-Ru layer was annealed on glass. For a glass/FTO substrate, RTA <30 seconds was needed for 30 nm Ru thick films. Those dots can increase the effective surface area for silicon and glass substrates by up to 5-44%, and by 300% for the FTO substrate with a < $20^{\circ}$ wetting angle.

• 한국재료학회지
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• 제29권10호
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• pp.592-602
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• 2019

Feasibility is investigated for reduction of chromium ore by Si sludge with mixed silicothermic and carbothermic reaction. The reduction behavior of chromium ore using Si sludge is investigated precisely to determine the effects of carbon addition, reaction time, and reaction temperature. The pellets are dropped into the furnace after temperature stabilized. As the amount of C addition increases, the amounts of CO and $CO_2$ gas generation increase. After the dropping of the pellets, the pellets are heated and the reaction starts at about 1,573 K or higher. The pellets maintain their shape until 10 min after the drop, and then melted. As the holding time increased, the size of the reduced metal particles increased. The chromium ore is rapidly reduced by the Si sludge, and the slag penetrated into the chromium ore and reduction progressed inside. As the reduction temperature increased, the reaction initiation time is shortened and the reaction fraction of the reduction reaction increased. As the reaction temperature increased, agglomeration of reduced ferrochrome metal is promoted.

• 한국전기전자재료학회:학술대회논문집
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• 한국전기전자재료학회 1999년도 춘계학술대회 논문집
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• pp.442-446
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• 1999

Melting behavior and bridge phenomenon of solder paste, which is essential for surface mount technology in packaging, were investigated. solder paste of Sn-37%Pb was printed on Sn-coated Cu-pattern of PCB, and heated over melting point. Melting behavior of the paste was observed using CCD-camera. In order to modelize the melting and agglomeration phenomena of the paste, two solder balls of 0.76mm diameter were used. As experimental results, the paste start to melt from the margin of the printed shape. The hight of the melted paste decreased from 270 $\mu$m to 200 $\mu$m firstly, and finally recovered to 250 $\mu$m. During the melting procedure, pores were evolved from the molten paste. Bridge Phenomenon of the molten Paste depends upon the pitch of the pattern.

• 대한금속재료학회지
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• 제48권4호
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• pp.326-334
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• 2010

Porous and net-shaped tantalum powder for a capacitor was formulated in a SHS (self-propagating high-temperature synthesis) process. However, this powder, which has weak strength among its particles and low flow ability, cannot be used for a capacitor. Therefore, this powder was sintered in a high-vacuum furnace to increase agglomeration to improve the flow ability, bonding strength among the particles, and shrinkage during pellet sintering. Finally, it was deoxidated with 2 wt% Mg powder to remove the increased surface oxygen that arose during the sintering process. The final product was analyzed in terms of its chemical and physical properties and was compared with a commercial powder used by a capacitor manufacturer.

• 전기전자학회논문지
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• 제20권2호
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• pp.177-180
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• 2016

본 연구에서는 4H-SiC(0001)기판 위에서 형성되는 나노구조화를 제어하기 위해 상지층과 하지층으로 구성된 이중층 금속을 증착하고 두께, 열처리 시간을 변화하였다. 또한 표면에너지와 응집현상의 상관관계를 분석하기 위해 SiC와는 다른 표면에너지를 갖는 Glass와 Si기판에도 같은 조건으로 실험하였다. FE-SEM을 통하여 금속이 나노구조화를 형성하는 두께가 Ag=20nm, Ti=2nm임을 확인 했으며 두께가 두꺼울 수록 나노 입자가 형성되지 않았다. 세기판의 표면에너지를 구하기 위해 접촉각 측정기를 통해 정접촉각법으로 측정하였다. 그 결과 표면에너지 값이 가장 높은 Glass(53.89 mN/m) 기판에서 나노 입자가 가장 고르게 분포된 형태를 보였으며 SiC(41.13 mN/m)에서 나노구조화 되는 양상을 보였고, Si(32.96 mN/m)에서는 NPs 형성이 되지 않았다. 표면에너지가 작을수록 나노 입자형성이 고르게 분포되는 현상을 Young equation으로 분석하였다.

• Bulletin of the Korean Chemical Society
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• 제29권4호
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• pp.799-804
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• 2008

An amphiphilic diacetylene compound was deposited on the surface of nano sized magnetite particles ($Fe_3O_4$) using a self-assembly method. The diacetylene molecular assembly formed on the surface of nanoparticle was subjected to photopolymerization. This resulted in the formation of a polymeric assembly on the surface of the nanoparticles in which the adjacent diacetylene molecules were connected through conjugated covalent networks. The presence of immobilized polymer species on the surface of nanoparticles is expected to protect them from agglomeration and ripening, thereby stabilizing their physical properties. In this work, $Fe_3O_4$ nanoparticles were prepared by chemical coprecipitation method and the diacetylene molecule 10,12- pentacosadiynoic acid (PCDA) was anchored to the surface of $Fe_3O_4$ nanoparticles through its carboxylate head group. Irradiation of UV light on the nanoparticles containing immobilized diacetylenes resulted in the formation of a polymeric assembly. Presence of diacetylene molecules on the surface of nanoparticles was confirmed by X-ray photoelectron spectroscopy and FT-IR measurements. Photopolymerization of the diacetylene assembly was detected by UV-Visible spectroscopy. Magnetic properties of the nanoparticles coated with polymeric assembly were investigated with SQUID and magnetic hysteresis showed superparamagnetic behaviors. The results put forward a simple and effective method for achieving polymer coating on the surface of magnetic nanoparticle.

• The Journal of Asian Finance, Economics and Business
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• 제9권2호
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• pp.419-426
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• 2022

The digital economy is becoming an increasingly important source of regional competitiveness enhancement. The purpose of this research is to examine the spatial distribution characteristics of China's digital economy from 2016 to 2019. Moran's I analysis was performed to see if China's digital economy has spatial self-correlation. The Getis-Ord General G test was used to determine the clustering type of China's digital economy. In addition, we used OLS and GWR methodologies to figure out what drives China's digital economy level. The findings show that the digital economy is rapidly expanding throughout China; yet, there is a significant regional imbalance in the digital economy level in China, and the agglomeration of the digital economy is increasing over time. Furthermore, the findings reveal that human capital, information staff, telegram income, and Internet access are vital factors in the development of the digital economy. To close the digital economy gap, policymakers must invest in human capital and technology innovation. Simultaneously, the government must speed up the development and implementation of electronic information services.

• 한국전기전자재료학회논문지
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• 제35권5호
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• pp.439-444
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• 2022

Laser-induced plasmonic sintering of metal nanoparticles (NPs) is a promising technology to fabricate flexible conducting electrodes, since it provides instantaneous, simple, and scalable manufacturing strategies without requiring costly facilities and complex processes. However, the metal NPs are quite expensive because complicated synthesis procedures are needed to achieve long-term reliability with regard to chemical deterioration and NP aggregation. Herein, we report laser-induced Ag NP self-generation and sequential sintering process based on low-cost Ag organometallic material for demonstrating high-quality microelectrodes. Upon the irradiation of laser with 532 nm wavelength, pre-baked Ag organometallic film coated on a transparent polyimide substrate was transformed into a high-performance Ag conductor (resistivity of 2.2 × 10^-4 Ω·cm). To verify the practical usefulness of the technology, we successfully demonstrated a wearable transparent heater by using Ag-mesh transparent electrodes, which exhibited a high transmittance of 80% and low sheet resistance of 7 Ω/square.

• 한국경제지리학회지
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• 제7권2호
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• pp.261-281
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• 2004

전북지역 자동차산업 입지는 1990년대 초반 양적성장단계에 접어든 완성차업체의 저렴한 생산공간 확보전략과 정부의 선도기업 입지에 의한 지역균형발전 개발정책에 의해 이루어졌다. 그 결과 부품산업의 기반 없이 완성차업체가 입지한 후 부품 및 소재업체가 입지하는 반대되는 발전 패턴을 취하고 있기 때문에 취약한 지역산업의 구조적인 문제점을 보이고 있다. 우선, 지역 부품산업의 계층적인 구조가 정립되지 않아 효율적인 분업생산체제를 갖추지 못하여 많은 부품을 외부지역에 의존하고 있다. 그리고 대부분의 부품업체는 특정 완성차업체에 전속되어 있으며, 지역 부품산업의 대부분은 단순 임가공을 필요로 하는 저부가가치 업종으로 이루어져 있다. 마지막으로, 다른 지역에 비해 상대적으로 연관산업의 집적도가 낮아 기업유치 경쟁력이 낮은 문제점 등을 가지고 있다. 자동차산업을 지역산업으로 특화시켜 지역경제발전을 도모하기 위해서는 연관산업의 공간적 집적을 이루어 생산과정의 유연화를 창출해야 할 것이다. 최근 자동차산업은 적기조달방식과 모듈생산의 진전으로 완성차업체와 부품업체간의 지리적 근접성이 중요한 입지결정 요인으로 작용하고 있으며, 모듈생산방식은 기존의 공장에서 시도되기 보다는 새롭게 개발된 공장에서 주로 시도되고 있는 것으로 나타나고 있다. 따라서 지역단체는 우호적인 기업환경의 조성과 적극적인 기업유치전략을 통해 모듈화된 부품공급이 가능하도록 집적화된 산업단지의 육성을 도모해야 할 것이다.

• 한국지역지리학회지
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• 제4권2호
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• pp.183-199
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• 1998

본 연구는 지속가능한 개발(ESSD)에 있어 신도시 자족성의 의미를 이론적으로 고찰하고, 일산신도시를 사해로 자족성을 실증적으로 분석함으로써 자족성 제고를 위한 정책 방안을 계시하고자 하였다. ESSD의 관점에서는 자족시설을 이용하는 주민의 행태분석이 연구의 중심이 된다. 이에 따라 일산신도시외 토지이용계획의 특성을 살펴보고 통학시설, 통근시설 및 상업 서비스시설의 각 부문별로 자족성을 분석하였다. 일산신도시는 수도권정비계획법상 과밀억제권역에 속해 기본적으로 자족시설을 건설할 여건이 조성되어 있지 못하기 때문에 통근자족률은 21.8%에 불과하였다. 상업 서비스시설의 자족율은 89.4%에 달하나, 공공서비스시설의 자족성이 낮은 것으로 분석되었다. 통학시설자족률은 94.0%로 매우 높게 나타났다. 따라서 수도권 내 새로운 신도시외 조성이 필요한 경우 거리와 법적규제를 고려하여, 과밀억제권역을 벗어난 지역에서 입지를 모색할 것을 제안하였다. 자족시설에 있어서는 공업기능보다는 3차산업 중심의 자족시설 계획을 수립하는 것이 바람직하며, 3차산업의 신도시 유치를 위란 유인책을 마련하고, 유사한 기능끼리 특성화시피 집적이익을 추구할 수 있는 여건을 조성해 주어야 한다. 아울러 유관 정부기능이 입지하면, 이와 관련된 업무시설의 입지는 보다 쉽게 이루어 질 수 있을 것이다. 공공서비스시설 등 주민편익시설을 적기에 공급하기 위해 주택과 자족시설의 공급시기를 조절하면서 장기적 안목에서 신도시가 건설되어야 할 것이다.