• Title/Summary/Keyword: selective Removal

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A Circulating Fluidized Bed Scrubbing Technology for Dry Removal of the SOx and NOx of Coal Combustion Gases (석탄연소가스내의 SOx/NOx 동시처리를 위한 순환유동식 건식세정기술)

  • 이상권;조경민
    • Proceedings of the Korea Society for Energy Engineering kosee Conference
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    • 1999.05a
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    • pp.69-74
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    • 1999
  • 각종 산업체의 공정에서 혹은 석탄 혹은 석유를 사용하는 화력발전설비에서 다량 발생되는 질소산화물(NOx), 황산화물(SOx)의 배출규제가 점점 강화되어 감에 따라 배출량 절감이 절실히 요구된다. 기존의 배기가스 정화장치는 처리대상에 따라 다양한 방법들이 사용되는데 황산화물의 경우 습식, 반건식, 건식세정법에 의해, 질소산화물은 선택적 촉매환원법(Selective Catalytic Reduction)과 선택적 무촉매환원법(Selective Non Catalytic Reduction)이 널리 이용되고 있다.(중략)

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Removal of Cd(II) from water using carbon, boron nitride and silicon carbide nanotubes

  • Azamat, Jafar;Hazizadeh, Behzad
    • Membrane and Water Treatment
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    • v.9 no.1
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    • pp.63-68
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    • 2018
  • Molecular dynamics simulations were used to study the removal of Cd(II) as a heavy metal from wastewater using armchair carbon nanotube, boron nitride nanotube and silicon carbide nanotubes under applied electric field. The system contains an aqueous solution of $CdCl_2$ as a heavy metal and a (7,7) nanotube as a nanostructured membrane, embedded in a silicon nitride membrane. An external electric field was applied to the considered system for the removal of $Cd^{2+}$ through nanotubes. The simulation results show that in the same conditions, considered armchair nanotubes were capable to remove $Cd^{2+}$ from wastewater with different ratios. Our results reveal that the removal of heavy metals ions through armchair carbon, boron nitride and silicon carbide nanotubes was attributed to the applied electric field. The selective removal phenomenon is explained with the calculation of potential of mean force. Therefore, the investigated systems can be recommended as a model for the water treatment.

Preparation of Hydrazine Impregnated Adsorbents and Selective Adsorption Properties for Carbonyl Compounds in Cigarette Mainstream Smoke (Hydrazine 첨착 흡착제의 제조 및 담배 주류연 중 카보닐 화합물의 선택 흡착 특성)

  • Lee, John-Tae;Park, Jin-Won;Lee, Jeong-Min;Rhee, Moon-Soo;Hwang, Keon-Joong;Hwang, Taek-Sung
    • Polymer(Korea)
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    • v.30 no.3
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    • pp.210-216
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    • 2006
  • To use the filter materials for selective removal of carbonyl compounds in cigarette mainstream smoke, hydrazine such as 2,4-dinitrophenylhydrazine (2,4-DNPH) and dansylhydrazine (DAH) impregnated adsorbents were prepared with perchloric acid or phosphoric acid as an accelerator in hydrazone formation reaction. Changes of molecular structure and morphology of adsorbents in various of impregnator were investigated by FTIR/ATR and SEM. Impregnation amount caused by reaction time, acid type and impregnation reagent, and the adsorption properties of carbonyl compounds in cigarette mainstream smoke were studied. Amounts of impregnation increased with increasing reaction time. The removal amount for vapor phase carbonyl compounds by 2,4-DNPH impregnated adsorbent was higher than that of dansylhydrazine impregnated adsorbent. The selectivity of 2,4-DNPH impregnated polyacrylic type adsorbent was superior to those of other adsorbents. This result indicates that the 2,4-DNPH impregnated polyacrylic adsorbent is applicable to cigarette filter material because of its fast reactivity and porosity.

Cleaning Method for Selective Removal of Stains from Historic Textiles and Stains Change by Long Period Storage -Focused on Blood Soil- (복식유물 오구의 선택적 제거를 위한 세척방법 및 장기간 보관에 따른 오구 변화 -혈액오구를 중심으로-)

  • Roh, Eui Kyung;Ryu, Hyo-Seon;Chae, Jeongmin
    • Journal of the Korean Society of Clothing and Textiles
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    • v.41 no.2
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    • pp.341-351
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    • 2017
  • This study evaluates a cleaning method to maintain and minimize the change of blood soil for the selective removal of stains from textiles with historical significance and special meaning. Cotton and silk fabrics were soiled with blood, aged artificially and then washed by wet cleaning or dry cleaning (water, nonionic surfactant; Triton, natural surfactant; saponin, organic solvent; n-Decane). The washed fabrics were stored at room temperature for four years. The change of the blood soil was evaluated by SEM, weight, thickness, and color differences. Subsequently, the shape and the amount of blood adsorption on the fabric varied depending on fiber type and fabric structure characteristics; in addition, long term storage affected changes to blood soil. It was difficult to remove artificially aged blood soil from fabrics by wet or dry cleaning. However, the changes of the blood soil by these cleanings can be explained by the changes on SEM, weight, thickness and fabric color. The changes (especially color) showed over time. Wet cleaning showed that the changes of those factors were slightly lower than those by dry cleaning.

Development of Oil-water Separator for the Effective Application of Highly Selective Membranes (고선택성 유수분리막 적용성 향상을 위한 유수분리장치 성능 개선 연구)

  • Choi, Kwang-Soon;Lee, Donghun;Uhm, Sunghyun
    • Applied Chemistry for Engineering
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    • v.30 no.1
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    • pp.39-42
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    • 2019
  • We report on the design of oil-water separators and the selection of materials for the effective application of highly selective membranes fabricated by commercial PET (polyester) fabrics. The waterproof ability of PET fabrics was optimized to improve the separation selectivity. The density of individual PET fabrics should be over $60g/m^2$, and the multi-layered structure is more favorable for the waterproof ability together with maintaining the removal efficiency. For the continuous adsorption and removal process, the rotating perforated cylinder was selected, and covered with membranes. Furthermore, more improved and stable removal efficiency was obtained by installing floating baffles which forces the oil content to move toward membranes.

Development of solid absorbents for the removal of NOx (NOx 제거용 고체흡수제 개발)

  • Sahn, Jong-Rack
    • Proceedings of the KIEE Conference
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    • 1997.11a
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    • pp.709-712
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    • 1997
  • Selective removal of NOx by binary oxide systems of Ba-Cu and Mn-Zr was investigated. These mixed oxides were effective in removing NOx at $400^{\circ}C$ by absorption in or on the solid as nitrate. The reaction was investigated by oxidation of NO which was promoted in the presence of $O_2$ on Mn or Cu sites. Then, the oxidized species were stored in the solid as nitrate ions on Ba or Zr sites.

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Overlook of carbonaceous adsorbents and processing methods for elemental mercury removal

  • Bae, Kyong-Min;Kim, Byung-Joo;Park, Soo-Jin
    • Carbon letters
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    • v.15 no.4
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    • pp.238-246
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    • 2014
  • People have been concerned about mercury emissions for decades because of the extreme toxicity, persistence, and bioaccumulation of methyl Hg transformed from emitted Hg. This paper presents an overview of research related to mercury control technology and identifies areas requiring additional research and development. It critically reviews measured mercury emissions progress in the development of promising control technologies. This review provides useful information to scientists and engineers in this field.

Electroconvective Instability on Undulated Ion-selective Surface (파상형 이온 선택 표면상의 전기와류 불안정성)

  • Lee, Hyomin
    • Korean Chemical Engineering Research
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    • v.57 no.5
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    • pp.735-742
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    • 2019
  • In this work, the electrokinetic interactions between the undulated structure of an ion-selective membrane and electroconvective instability has been studied using numerical analysis. Using finite element method, electric field-ionic species transport-flow field were analyzed by fully-coupled manner. Through the numerical study, the Dukhin's mode as the mechanism of undulated surface for the electroconvective instability were proven. The Dukhin's mode which competes with Rubinstein's mode has roles of (i) decreasing transition voltage to overlimiting regime and (ii) non-linearly increasing of overlimiting current. Also, (iii) the mixing efficiency is enhanced by removal mechanism of high-frequency Fourier mode of the electroconvective instability. Conclusively, the undulated ion-selective surface would provide energy-efficient mechanism for ion-selective transport systems such as electrodialysis, electrochemical battery, etc.

A Study on the Recycling of Metals and Removal of Organics By Electrochemical Treatment of Mixed Waste Water of Surface Finishing Industry (표면처리 공정에서 발생하는 혼합 폐수의 전기화학적 처리에 의한 중금속의 재활용 및 유기물의 제거에 관한 연구)

  • 김영석;이중배
    • Journal of the Korean institute of surface engineering
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    • v.36 no.2
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    • pp.184-193
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    • 2003
  • Cyclic sweep voltametry was performed to investigate the electrochemical behavior of heavy metal ions and the organic additives in surface finishing process. And electrolysis using parallel plate electrode electrolyzer was carried out to simulate the treatment of real waste water. Results showed that more than 99 percent of Cu was recovered and selective recovery of Cu in mixed waste water was possible, but the possibility of economical recovery of Ni and Cr were very low due to the evolution of hydrogen gas. Electrochemical oxidation of cyanide and organic additives on anode showed very excellent removal rate. The complete removal of several hundred ppm of cynide was possible within several tens minutes and organics within 2 or 3 hours. Even in case of concentrate waste water, the complete removal of COD by using NaCl and air stirring seemed to be possible.