• Title/Summary/Keyword: segregation

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Intergranular Corrosion Mechanism of Slightly-sensitized and UNSM-treated 316L Stainless Steel

  • Lee, J.H.;Kim, K.T.;Pyoun, Y.S.;Kim, Y.S.
    • Corrosion Science and Technology
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    • v.15 no.5
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    • pp.226-236
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    • 2016
  • 316L stainless steels have been widely used in many engineering fields, because of their high corrosion resistance and good mechanical properties. However, welding or aging treatment may induce intergranular corrosion and stress corrosion cracking etc. Since these types of corrosion are closely related to the formation of chromium carbide in grain boundaries, the alloys are controlled by methods such as the lowering of carbon content, solution heat treatment. This work focused on the intergranular corrosion mechanism of slightly-sensitized and Ultrasonic Nano-crystal Surface Modification (UNSM)-treated 316L stainless steel. Samples were sensitized for 1, 5, and 48 hours at $650^{\circ}C$ in $N_2$ gas atmosphere. Subsequently UNSM treatments were carried out on the surface of the samples. The results were discussed on the basis of the sensitization by chromium carbide and carbon segregation, the residual stress and grain refinement. Even though chromium carbide was not precipitated, the intergranular corrosion rate of 316L stainless steel was drastically increased with aging time, and it was confirmed that the increased intergranular corrosion rate of slightly-sensitized (not carbide formed) 316L stainless steel was due to the carbon segregation along the grain boundaries. However, UNSM treatment improved the intergranular corrosion resistance of aged stainless steels, and its improvement was due to the reduction of carbon segregation and the grain refinement of the outer surface, including the introduction of compressive residual stress.

Effect of Heat Treatment on the Corrosion Properties of Seamless 304L Stainless Steel Pipe (이음매 없는 304L 스테인리스강관의 부식특성에 미치는 열처리의 영향)

  • Kim, K.T.;Um, S.B.;Kim, Y.S.
    • Corrosion Science and Technology
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    • v.16 no.6
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    • pp.305-316
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    • 2017
  • Austenitic stainless steels have been widely used for various systems of nuclear power plants. Among these stainless steels, small pipes with diameter less than 14 inch have been produced in the form of seamless pipe. Annealing and cooling process during the manufacturing process can affect corrosion properties of seamless stainless steels. Therefore, 12 inch-diameter of as-received 304L stainless steel pipe was annealed and aged in this study. Intergranular corrosion resistance was evaluated by ASTM A262 Practice A, C, and E methods. The degree of sensitization was determined using a DL-EPR test. U-bend method in an autoclave was used to evaluate the SCC resistance in 0.01 M $Na_2S_4O_6$ or 40% NaOH solution at $340^{\circ}C$. As-received specimen showed relatively high degree of sensitization and intergranular corrosion rate. Carbon segregation was also observed near grain boundaries. Annealing treatment could give the dissolution of segregated carbon into the matrix. Aging treatment could induce segregation of carbon and finally form carbides. Microstructural analysis confirmed that high intergranular corrosion rate of the as-received seamless pipe was due to micro-galvanic corrosion between carbon segregation and grains.

Isolation Effectiveness by Progressive Space Organization in Negative Pressured Isolation Unit (음압격리병실에 있어서 단계별 공간구성의 격리효과)

  • Kwon, Soonjung;Sung, Minki
    • Journal of The Korea Institute of Healthcare Architecture
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    • v.22 no.4
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    • pp.79-86
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    • 2016
  • Purpose: The purpose of this study is to identify the effect of Progressive Space Organization (ante-rooms) in Negative Pressured Isolation Unit(NPIU) such as National and Regional Isolation Units in Korea in order to build basic data for the evidence based design of Airborne Infection Isolation Units which should prepare and respond effectively to the public health crisis due to the hazardous airborne infectious disease. Methods: 1) Gas(SF6) test and analysis on the 23 Korean Isolation Units under operation. 2) Assessment of the isolation level of the space components by checking the Gas concentration. 3) Analysis of the Isolation Effectiveness according to Space Organizational levels. Results: 1) The higher segregation level is, the lower Gas(SF6) concentration is. 2) Too many segregations(anterooms) of Isolation Unit are not efficient for the prevention of infectious bacillus spread. For example, 4 level of segregation has similar segregation effect to the 3 level of segregation. Implications: Many anterooms in front of the isolated patient bedroom will guarantee the safe environment against the danger of hazardous airborne nosocomial infection. On the other hand, too many segregations is inefficient, expensive, inconvenient, narrow(unflexible) and so on. This study can be used as basic data for further development of design guidelines of isolation units.

Changing Residential Segregation of Asians in Westchester, New York (교외 지역 아시아인의 거주지 분리에 관한 연구 -뉴욕 웨체스터 사례-)

  • Beck, Yeong Ki
    • Journal of the Korean association of regional geographers
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    • v.22 no.4
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    • pp.774-791
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    • 2016
  • Recent studies on Asian suburbanization suggest that their settlement patterns do not confirm to those of earlier migrant streams, and that different residential patterns of Asian ethnic minority groups have created a complex ethnic mosaic in suburban areas. This paper examines the extent to which residential patterns of main Asian minority groups have changed in Westchester, where is one of suburban counties around New York City. With mapping base on Census of Population data in 2000 and 2010 years, the residential patterns of five Asian groups (Asian Indians, Chinese, Filipinos, Japanese, and Koreans) are analyzed through the indices of segregation. The residential segregation geography of the Asian ethnic groups is characterized by dispersed concentration. There is a difference among the characteristics of the ethnic neighborhoods in which Asian minority groups are residentially concentrated.

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Influence of Various Replacing Ratios of SCMs on Properties of High Fluidity Concrete (광물질 혼화재의 치환율 변화가 고유동 콘크리트의 특성에 미치는 영향)

  • Han, In-Deok
    • Journal of the Architectural Institute of Korea Structure & Construction
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    • v.35 no.12
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    • pp.165-172
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    • 2019
  • The aim of the research is to evaluate the influence of various replacing ratios of supplementary cementitious materials(SCMs) such as fly ash(FA), blast furnace slag(BS), and both FA and BS on general properties including segregation resistance as a powder based high fluidity concrete of normal strength grade with water-to-cement ratio 0.40. Specifically, by replacing the SCMs with low density powders, it was assessed that the decreased segregation resistance due to the decreased viscosity by J-ring test. As a result of the experiment, from the general test, the mixtures with SCMs showed increased segregation resistance by increased viscosity as the references, while some segregation was shown from J-ring test due to the decreased density of fresh state mixture related with the capacity of delivering coarse aggregate.

One-Step β-Li2SnO3 Coating on High-nickel Layered Oxides via Thermal Phase Segregation for Li-ion Batteries

  • Seongmin Kim;Hanseul Kim;Sung Wook Doo;Hee-Jae Jeon;In Hye Kim;Hyun-seung Kim;Youngjin Kim
    • Journal of Electrochemical Science and Technology
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    • v.14 no.3
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    • pp.293-300
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    • 2023
  • The global energy storage markets have gravitated to high-energy-density and low cost of lithium-ion batteries (LIBs) as the predominant system for energy storage such as electric vehicles (EVs). High-Ni layered oxides are considered promising next-generation cathode materials for LIBs owing to their significant advantages in terms of high energy density. However, the practical application of high-Ni cathodes remains challenging, because of their structural and surface instability. Although extensive studies have been conducted to mitigate these inherent instabilities, a two-step process involving the synthesis of the cathode and a dry/wet coating is essential. This study evaluates a one-step β-Li2SnO3 layer coating on the surface of LiNi0.8Co0.2O2 (NC82) via the thermal segregation of Sn owing to the solubility limit with respect to the synthesis temperature. The doping, segregation, and phase transition of Sn were systematically revealed by structural analyses. Moreover, surface-engineered 5 mol% Sn-coated LiNi0.8Co0.2O2 (NC82_Sn5%) exhibited superior capacity retention compared to bare NC82 owing to the stable surface coating layer. Thus, the developed one-step coating method is suitable for improving the properties of high-Ni layered oxide cathode materials for application in LIBs.

Characterization of Alcohol Fermentation and Segregation of Protoplast Fusant of Saccharomyces cerevisiae and Pichia stipitis

  • YOON, GEE-SUN;TAE-SIK LEE;CHUL KIM;JIN-HO SEO;YEON-WOO RYU
    • Journal of Microbiology and Biotechnology
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    • v.6 no.4
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    • pp.286-291
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    • 1996
  • A study was conducted to investigate the characteristics of segregation and alcohol fermentation of intergeneric fusants. The protoplast fusion of both Pichia stipitis CBS 5776 and Saccharomycess cerevisiae STV 89 was carried out. The fusion frequency was $5\times10^{-8}$ and among fusants selected, a fusant F5 showed the best results in ethanol production by sucrose and xylose fermentations. The performance of xylose fermentation by this fusant was better than that of P. stipitis CBS 5776 and fusant F5 exhibited sucrose fermentation patterns intermediate to the two parent strains. The fusant F5 was segregated into a pair of parental strains during the several culture passages. In the average, 91$%$ of colonies had a similar characteristics of P. stipitis while 7$%$ of colonies resembled S. cerevisiae. Only 2$%$ of colonies had the characteristics of the original fusants. At the sixth passage, all segregants resembled P. stipitis. From these results it is suggested that intergeneric protoplast fusion led to an integration of S. cerevisiae genes, rather than whole chromosomes, within the entire genome of P. stipitis.

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Target Speech Segregation Using Non-parametric Correlation Feature Extraction in CASA System (CASA 시스템의 비모수적 상관 특징 추출을 이용한 목적 음성 분리)

  • Choi, Tae-Woong;Kim, Soon-Hyub
    • The Journal of the Acoustical Society of Korea
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    • v.32 no.1
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    • pp.79-85
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    • 2013
  • Feature extraction of CASA system uses time continuity and channel similarity and makes correlogram of auditory elements for the use. In case of using feature extraction with cross correlation coefficient for channel similarity, it has much computational complexity in order to display correlation quantitatively. Therefore, this paper suggests feature extraction method using non-parametric correlation coefficient in order to reduce computational complexity when extracting the feature and tests to segregate target speech by CASA system. As a result of measuring SNR (Signal to Noise Ratio) for the performance evaluation of target speech segregation, the proposed method shows a slight improvement of 0.14 dB on average over the conventional method.

A Fundamental Study on the Estimation of Construction Cost of High Fluidity Concrete Applying Flowing Concrete Method (유동화공법에 의해 제조한 고유동 콘크리트의 원가분석에 관한 기초적 연구)

  • 한민철;손성운;오선교;김성수;한천구
    • Proceedings of the Korean Institute of Building Construction Conference
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    • 2002.11a
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    • pp.99-102
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    • 2002
  • This paper discusses the estimation of construction cost of high fluidity concrete using segregation reducing type superplasicizer with 350kgf/cm2 of design strength and 60$\pm$5cm of slump flow in order to verify the cost down effect of high fluidity concrete compared with that of plain concrete with 350kgf/cm2 of design strength and 18cm of slump and with 210kgf/cm2 of design strength and 15cm of slump. According to research, under same strength levels, although material cost of high fluidity concrete is somewhat higher than that of plain concrete due to segregation reducing type superplasticizer, labor cost and equipment cost of high fluidity concrete is cheaper than that of plain concrete. However, based on the strength differences, high fluidity concrete shows lower material cost, labor cost and equipment cost than that of plain concrete due to decreasing in size of member and re-bar caused by high strength development of concrete.

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Dynamics Simulation of Solid Particles in Compression Deformation of Rheology Material (레오로지 소재의 압축변형시 고상입자 거동의 동역학 해석)

  • Lee, C.S.;Kang, C.G.
    • Transactions of Materials Processing
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    • v.15 no.5 s.86
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    • pp.395-401
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    • 2006
  • It is reported that semi-solid forming process takes many advantages over the conventional forming process, such as a long die life, good mechanical properties and energy saves. It is important to predict the deformation behavior for optimization of the forging process with semi-solid materials and to control liquid segregation for mechanical properties of materials. But rheology material has thixotropic, pseudo-plastic and shear-thinning characteristics. So, it is difficult for a numerical simulation of the rheology process to be performed because complicated processes such as the filling to include the state of the free surface and solidification in the phase transformation must be considered. General plastic or fluid dynamic analysis is not suitable for the analysis of the rheology material behavior. Recently, molecular dynamics is used for the behavior analysis of the rheology material and turned out to be suitable among several methods. In this study, molecular dynamics simulation was performed for the control of liquid segregation, forming velocity, and viscosity in compression experiment as a part of study on the analysis of rheology forming process.