• Bulletin of the Korean Chemical Society
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• v.25 no.8
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• pp.1182-1188
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• 2004

Polydisperse oligo(PO-b-EO) allyl ether siloxane surfactants were synthesized by the hydrosilylation reaction of OMTS with Allyl-oligo(PO-b-EO) series. The surface tension of siloxane surfactants increased with increasing the EO chain length while it decreased with increasing the PO ratio. However, the sedimentation time of the aqueous solution showed opposite trend to the surface tension data. Both the surface tension and sedimentation time of the aqueous solution containing inorganic electrolyte gradually decreased as the content of inorganic electrolyte increased because of the surface arrangement of surfactant molecules. However, they increased with an increase of pH values due to the hydrolysis of the siloxane backbone. The $C_p$ values tended to increase with the increase in the EO chain length and decrease of the PO ratio. It seems that intermolecular interaction between PO/EO block copolymer and water affects the variation of transition temperature.

• Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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• 2008.06a
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• pp.112-112
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• 2008

최근 Ruthenium (Ru) 은 높은 화학적 안정성, 누설전류에 대한 높은 저항성, 저유전체와의 높은 안정성 등과 같은 특성으로 인해 금속층-유전막-금속층 캐패시터의 하부전극으로 각광받고 있다. 또한 Cu와의 우수한 Adhesion 특성으로 인해 Cu 배선에서의 Cu 확산 방지막으로도 주목받고 있다. 그러나 이렇게 형성된 Ru 하부전극의 각 캐패시터간의 분리와 평탄화를 위해서는 CMP 공정이 도입이 필요하다. 이러한 CMP 공정에 공급되는 Slurry 에는 부식액, pH 적정제, 연마입자 등이 첨가되는데 이때 연마입자가 응집하여 Slurry의 분산 안전성 저하에 영향을 줄수 있다. 이로 인해 응집된 Slurry는 Scratch와 Delamination 과 같은 표면 결함을 유발할 수 있으며, Slurry의 저장 안정성을 저하시켜 Slurry의 물리적 화학적 특성을 변화시킬 수 있다. 그리하여 본 연구에서는 Ru CMP Slurry에서의 Surfactant와 같은 분산 안정제에 따른 Surface tension, Zeta potential, Particle size, Sedimentation의 분석을 통해 Slurry 안정성에 대한 영향을 살펴보았다. 그 결과 pH9 조건의 31ppm Dispersant 농도에서 50%이상의 Sedimentation 상승효과를 얻을 수 있었다. 또한 선택된 Surfactant가 첨가된 Ru CMP Slurry를 제조하여 Ru wafer의 Static etch rate, Passivation film thickness 와 Wettability를 비교해 보았다. 그리고 CMP 공정을 실시하여 Ru의 Removal rate와 TEOS에대한 Selectivity를 측정해 보았다.

• Journal of Korean Society of Water and Wastewater
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• v.20 no.6
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• pp.911-918
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• 2006

This study was conducted to evaluate the effect of the launder type on settling performance and hydrodynamic behavior within the two certain full-scale sedimentation basins (each flow rate/one basin; $10,000m^3/d$); one is the transverse typed launder(existing basin) and the other is building the finger type launder in combination with the longitudinal baffle. Comparative experimental investigations have been carried out through residual turbidity and particle concentration measurements in each effluent from two basins with the transverse and the finger type launders, respectively. From the experimental results, we could observe that turbidity removal rate in the finger type launder basin (modified basin) is about 30% higher than that in the transverse type launder basin (existing basin). Also, from the measurement of total particle concentration in each effluent, the removal efficiency was improved about 27% within modified basin compared to the existing basin. In order to explain the comparative experimental results and investigate the hydridynamic behavior within each basin in more detail, we conducted computational fluid dynamics (CFD) simulation and verified simulation results with acoustic Doppler velocimetry (ADV) technique. From the CFD simulation, it was investigated that extreme upward flow occurs underneath of the transverse launder. On the other hand, in the case of modified basin, the upward flow, which occurred in the beneath of launder, was much less than that in the existing basins.

• Proceedings of the Korean Society of Agricultural Engineers Conference
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• 2003.10a
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• pp.567-570
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• 2003

Nutrients behavior were investigated at a paddy fields area(Soro-ri) with large-scaled plots on loam soil during irrigation seasons of $2001{\sim}2002$. The average concentration of TN, TDN and TDP in drainage water was higher than that in irrigation water. On the other hand, TP in irrigation water was higher than that in drainage water. The ratio of a TDN to TN accounts for over 90% and the ratio of TDP to TP accounts for $50{\sim}70%$. Especially, the ratio of TDP to TP in drainage water was bigger than that in irrigation water, suggesting that much of particulate component was reduced due to sedimentation and adsorption in paddy fields plots.

• Proceedings of the Korea Water Resources Association Conference
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• 2004.05b
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• pp.543-546
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• 2004

Nutrients behavior were investigated at a paddy fields area(Soro-ri) with large-scaled plots on loam soil during irrigation seasons of $2001\~2003$. The average concentration of TN, TDN and TDP in drainage water was higher than that in irrigation water. On the other hand, the average concentration TP in irrigation water was higher than in drainage water. The ratio of TDN to TN accounted (or over $90\%$ and the ratio of TDP to TP accounted for $50\~70\%$. Especially the ratio of TDP to TP in drainage water was higher than that in irrigation water, suggesting that much of particulate component was reduced due to sedimentation and adsorption in paddy fields plots. Overall, particulate phosphorus usually account for 44 to $77\%$ of tile total phosphorus during storm events.

• Journal of Korean Society of Water and Wastewater
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• v.14 no.2
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• pp.164-173
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• 2000

Fluoridation of drinking water to a level of about 0.8mg/l (below 1.5mg/l) for reducing the incidence of tooth decay is recommended. However, concerns about potential problems of unknown effects and overdosing hinders the fluoridation. This study describes the work performed to obtain information on the behavior of fluoride under various conditions in the process of water fluoridation. Effects of water treatment chemicals, water treatment unit, and water distribution on water fluoridation were investigated at both lab and an actual water treatment plant. Residual fluoride concentration was not affected by lime and chlorine dosage up to 20mg/l. Flocculation with PAC slightly decreased the residual fluoride concentration as PAC dosage increased. Average fluoride concentration of 0.87mg/l at an intake basin was decreased to 0.83mg/l by sedimentation, 0.81mg/l by dual media(sand+anthracite) filtration, and 0.79mg/l by granular activated carbon filtration in the water treatment plant.

• Journal of the Korean GEO-environmental Society
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• v.12 no.6
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• pp.25-34
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• 2011

Dredged and reclaimed ground in progress at the West Coast has a high content of coarse particles. There will be different behaviors depending on the location of outlet and engineering properties of soil when its ground is dredged by a pump. Therefore, the experiments were conducted that were manufactured about the chamber equipment of length 2,650mm, width 770mm, height 735mm, experimented step filling method and water content about 300%, 500% and 700% respectively with SM and ML samples in order to realize segregating sediment characteristics of dredged ground with changing much fine. With results of analysis, ML sample by higher initial water content was reached to the period of complete sedimentation and coefficient of sedimentation consolidation increased with increases of diffusion distance. SM samples showed behavior of coarse soil with diffusion distance 120cm, diffusion distance of more than 120cm showed a similar tendency with ML sample under the influence of fines. In ML sample, it could be also found that lower depth and the more increasing diffusion distance increase in percentage of sieve #200 but water content decreases. In SM sample, it could be also found that coarse soil was piled at near the diffusion distance zone but fine soil was piled at the far diffusion distance zone and prominent difference showed between percentage of sieve #200 and water content(%) by boundary point 120cm~160cm of both samples. Also, shear strength was expressed ML-maximum 2.97kPa, SM-maximum 10.2kPa with diffusion distance.

• Journal of Environmental Science International
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• v.21 no.7
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• pp.837-843
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• 2012

The aims of this study were to investigated the occurrence of caffeine and carbamazepine in Nakdong river basin (8 mainstreams and 2 tributaries) and the behavior of caffeine and carbamazepine under drinking water treatment processes (conventional and advanced processes). The examination results showed that caffeine was detected at all sampling sites (5.4~558.5 ng/L), but carbamazepine was detected at five sampling sites (5.1~79.4 ng/L). The highest concentration level of caffeine and carbamazepine in the mainstream and tributaries in Nakdong river were Goryeong and Jinchun-cheon, respectively. These pharmaceutical products were completely removed when they were subject to conventional plus advanced processes of drinking water treatment processes. Conventional processes of coagulation, sedimentation and sand-filtration were not effective for their removal, while advanced processes of ozonation and biological activated carbon (BAC) filtration were effective. Among these pharmaceuticals, carbamazeoine was more subject to ozonation than caffeine.

• Journal of Korean Society of Water and Wastewater
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• v.23 no.6
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• pp.799-810
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• 2009

With time, the stable management of turbidity is becoming more important in the water treatment process. So optimization of coagulation is important for the improvement of the sedimentation efficiency. we evaluated the mixing and hydrodynamic behavior in the coagulation basin using Computational Fluid Dynamics (CFD). The items for evaluation are a location and the speed of agitator and angle of an injection pipe. The results of the CFD simulation, the efficacy of mixing in the coagulation basin was not affected according to one or two injection pipe and angle of an injection pipe. If there is a agitator near outlet of coagulation basin, the efficacy of mixing don't improve even though the speed of agitator increase. So location of agitator is perfect when it locate center at the inlet stream. The coagulation basin at this study, the proper speed of agitator is form 20rpm to 30rpm.

• Journal of the Korean Ceramic Society
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• v.47 no.6
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• pp.566-571
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• 2010

Dispersion behavior of the slurries consisted of bimodal-type AlN powders was examined in non-aqueous solvent system. Azotropic solvent system and copolymer acidic dispersant were applied to the slurries. Measurements of the sedimentation height and the viscosity of the each slurry, and the test of particle size distribution of the each powder sample were conducted as examinations for the dispersion behavior at the various dispersant contents. The bimodal-type particle size distribution was continued after addition of the dispersant and small particle portions were increased as the dispersant content increases. The density of the green sheet was also increased as the dispersant content increases and a green density of $2.114\;g/cm^3$ was obtained at the sample prepared from 2.4 wt% dispersant content. The increase of large particle portions resulted in the surface defects of the green sheets.