• 제목/요약/키워드: secondary pollutants

검색결과 132건 처리시간 0.021초

석조문화재 표면 산화물의 산출상태와 지구화학적 거동: 익산 미륵사지 석탑 (Geochemical Behavior and Occurrence of Surface Oxidized Materials on the Stone Cultural Heritage: Iksan Mireuksaji Stone Pagoda)

  • 이동식;이찬희;양희제;최기영
    • 자원환경지질
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    • 제40권4호
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    • pp.375-387
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    • 2007
  • 국보 제11호 익산미륵사지석탑은 현재 문화유산의 원형보존을 위하여 해체복원 중이다. 이 석탑의 구성암석은 비교적 풍화에 강한 화강암으로 이루어져 있으나 오랜 세월 동안 대기환경에 노출되면서 다양한 형태의 오염물이 피복되어 원암의 색상을 잃었다. 이 연구에서는 이차적 무기오염물을 성인적 유형으로 세분하고, 육안으로 확연히 판별되는 산화 변색된 부재만을 엄선하여 오염물질의 산출상태 및 오염종을 정량분석 하였다. 또한 용해실험을 통해 가용성 오염종의 지구화학적 거동특성을 규명하고 세정방법 및 효과 등을 분석하여, 표면 세정제의 보존과학적 적용가능성을 검토하였다.

도시 협곡에서 건물 지붕 냉각이 스칼라 물질 확산에 미치는 영향 (Effects of Building-roof Cooling on Scalar Dispersion in Urban Street Canyons)

  • 박수진;김재진
    • 대기
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    • 제24권3호
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    • pp.331-341
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    • 2014
  • In this study, the effects of building-roof cooling on scalar dispersion in three-dimensional street canyons are investigated using a computational fluid dynamics (CFD) model. For this, surface temperature of building roof is systematically changed and non-reactive pollutants are released from street bottom in urban street canyons with the aspect ratio of 1. The characteristics of flow, air temperature, and non-reactive pollutant dispersion in the control experiment are analyzed first. Then, the effects of building-roof cooling are investigated by comparing the results with those in the control experiment. In the control experiment, a portal vortex which is a secondary flow induced by ambient air flow is formed in each street canyon. Averaged air temperature is higher inside the street canyon than in both sides of the street canyon, because warmer air is coming into the street canyon from the roof level. However, air temperature near the street bottom is lower inside the street canyon due to the inflow of cooler air from both sides of the street canyon. As building-roof temperature decreases, wind speed at the roof level increases and portal vortex becomes intensified (that is, downdraft, reverse flow, and updraft becomes stronger). Building-roof cooling contributes to the reduction of average concentration of the non-reactive pollutants and average air temperature in the street canyon. The results imply that building-roof cooling has positive effects on improvement of thermal environment and air quality in urban areas.

A Commentary on Air Pollution Monitoring Programs in Korea

  • Ghim, Young-Sung;Kim, Jin-Young;Shim, Shang-Gyoo;Moon, Kill-Choo
    • Journal of Korean Society for Atmospheric Environment
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    • 제18권E1호
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    • pp.21-28
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    • 2002
  • Air quality issues in Korea rapidly changed at the beginning of the 1990s from primary to secondary pollutants starting in Seoul, the capital of Korea. The present frame of national air pollution monitoring networks was established between the end of the 1980s and the beginning of the 1990s. Background monitoring was initiated in the middle of the 1990s in response to increasing public concern about the long-range transport of air pollutants. Apart from the national monitoring, both routine and intensive measurements of fine particles have been made for research purposes since the middle of the 1990s at several background sites. However, air pollution monitoring in urban areas for other purposes was relatively scarce as national monitoring has been concentrated in these areas. Although ozone pollution has become a significant issue in major metropolitan areas every summer, only a little information on ozone precursors is available. During the past few years, the number of national monitoring stations has greatly increased. The government has a plan to gradually expand monitoring items as well as stations. It is anticipated that highly detailed information on both photochemical reactants and products will be available within the next several years. More emphasis will be placed on toxic substances based on risk assessment in monitoring for both research and policy making.

생물계면활성제를 이용한 디이젤 오염토양세척기술에 관한 연구 (A Study on Remediation of Diesel-Contaminated Soil by Biosurfactant- Enhanced Soil Washing)

  • 문혜준;임영경;김윤관;주춘성;방기연;정욱진;이승우
    • 한국지하수토양환경학회지:지하수토양환경
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    • 제7권2호
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    • pp.13-22
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    • 2002
  • 본 연구에서는 토양에 오염된 디이젤 성분을 제거하기 위한 토양세척 기술 중에서 적절한 계면활성제를 사용하여 토양입자에 결합되어 있는 유해 유기물질의 표면장력을 약화시켜 제거하는 기술을 이용하기 위해 생분해성이 우수하고 2차 오염문제가 없는 생물계면활성제를 생산하였다. Peudomonas aeruginosa ATCC 9027를 이용하여 생산된 생물계면활성제인 rhamnolipid와 기존에 사용되고 있는 화학계면활성제와의 디이젤 세척효능을 비교분석하였다. 회분식, 연속식 세척실험 결과 디이젤 오염토양 초기농도 5,000ppm에서 계면활성제 1%, 세척시간 24시간 경과 후 본 연구에서 생산된 rhamnolipid의 세척효율이 모두 약 95%로 사용된 계면활성제 중에서 가장 우수한 세척효율을 보였다. 화학계면활성제들은 대부분 50∼80% 미만의 세척효율을 나타내었으며, HLB값이 8에서 15사이에서의 화학계면활성제의 경우 75%이상의 분해효율을 나타내었다. 그러나, HLB값이 8이하이거나 15이상에서는 60%이하의 낮은 디이젤 분해효율을 나타내었다.

오픈 소스 전산 유체 역학 해석 프로그램을 이용한 전기집진기 내부 정전 유동 해석 (Numerical Analysis of Electro-Hydrodynamic (EHD) Flows in Electrostatic Precipitators using Open Source Computational Fluid Dynamics (CFD) Solver)

  • 송동근;홍원석;신완호;김한석
    • 한국입자에어로졸학회지
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    • 제9권2호
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    • pp.103-110
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    • 2013
  • The electrostatic precipitator (ESP) has been used for degrading atmospheric pollutants. These devices induce the electrical forces to facilitate the removal of particulate pollutants. The ions travel from the high voltage electrode to the grounded electrode by Coulomb force induced by the electric field when a high voltage is applied between two electrodes. The ions collide with gas molecules and exchange momentum with each other thus inducing fluid motion, electrohydrodynamic (EHD) flow. In this study, for the simulation of electric field and EHD flow in ESPs, an open source EHD solver, "espFoam", has been developed using open source CFD toolbox, OpenFOAM(R) (Open Field Operation and Manipulation). The electric potential distribution and ionic space charge density distribution were obtained with the developed solver, and validated with experimental results in the literature. The comparison results showed good agreement. Turbulence model is also incorporated to simulate turbulent flow; hence the developed solver can analyze laminar and turbulent flow. In distributions of electric potential and space charge, the distributions become distorted and asymmetric as the flow velocity increases. The effect of electrical drift flow was investigated for different flow velocities and the secondary flow in a flow of low velocity is successfully predicted.

The Effects of Panax ginseng on TCDD-induced Testicular Atrophy in Guinea Pigs

  • Kim, Wun-Jae;Hwang, Seok-Yeon;Lee, Hyung-Lae;Song, Geun-Song;Kim, Si-Kwan
    • 고려인삼학회:학술대회논문집
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    • 고려인삼학회 1998년도 Advances in Ginseng Research - Proceedings of the 7th International Symposium on Ginseng -
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    • pp.300-311
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    • 1998
  • 2,3,7,8-Tetrachlorodibenzo-p-dioxin (TCDD), one of the most notorious toxic environmental pollutants, induces various toxic effects in many organs including testes and is regarded as an endocrine disruptor. Korean ginseng, on the other hand, has been well known for its preventive effects on lox- ins, diabetes melltus and hyperlipidemia. We investigated, histopathologically, the effect of Korean Red ginseng water extract (KR-WE) on guinea pig testes damaged by TCDD. Ninety guinea pigs were divided into 6 groups: normal control (NC) group received vehicle and saline; TCDD,1191kg b.w., was administered intraperitoneally to the single dose TCDD-treated (77) group; 100 mghg b.w.16 and 200mg1kg b.w./d KR-WE were injected intraperitoneally to the preventive groups (PIOO and P2OO, respectively) for 28 days from 1 week before TCDD injection, and to the therapeutic groups (CIOO and C2OO, respectively) for 14 days since 1 week after TCDD administration. Increment of body weight was retarded to a larger extent by TCDD. Moreover, body weight of the 77 group decreased significantly 7 days after TCDD exposure, while that of preventive groups kept increasing. Decrease in body weight was not observed in KR-WE-treated groups. Weight decrease in testes caused by TCDD was remarkably protected by KR-WE. Testicles in 77 group displayed decreased tubular size and maturation arrest at the primary or secondary spermatocyte stage. On the other hand, maturation arrest in germ cells by TCDD was improved in KR-WE treated groups. Almost complete protection of the testes was observed in PIOO and P2OO groups. In addition, the therapeutic effect was noticed in C 100 and C2OO groups. These results provided strong evidence that Korean Red ginseng might be a useful agent for the prevention and treatment of testicular damage induced by environmental pollutants.

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광주지역 미세먼지의 화학적 조성이 시정에 미치는 영향에 관한 연구 (The Effect on Visibility of the Chemical Composition of Fine Particles in the Gwangju Area)

  • 정선아;임철수;조미라;이상보;김정수;신은상
    • 한국환경보건학회지
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    • 제44권1호
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    • pp.1-14
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    • 2018
  • Objectives: The purpose of this study is to investigate the main cause of visibility impairment by analyzing the contributions of the light extinction coefficient of major air pollution components and the change of the light extinction coefficient by relative humidity. Methods: The characteristics of the light extinction coefficient calculated by the photochemical method using fine particle component data measured in 2015 in the Gwangju area were examined. Results: The extinction efficiency per unit mass of $PM_{2.5}$ particles was $4.5m^2/g$ and that of $PM_{10-2.5}$ particles was $0.6m^2/g$. This difference indicates that most of the visibility impairment in Gwangju was caused by $PM_{2.5}$ particles. When visibility was poor, the contribution of ammonium sulphate and ammonium nitrate was significantly increased. Relative humidity was also a major cause of visibility decay. The influx of air currents in Gwangju was mostly caused by the long distance movement of pollutants emitted from the eastern part of China. Ammonium sulphate and ammonium nitrate, which are hygroscopic secondary contaminants, were the main causative agents of visibility impairment. Conclusions: Ammonium sulphate and ammonium nitrate were the main causative agents of visibility impairment in Gwangju. The influx of air currents in Gwangju was mostly caused by the long distance movement of pollutants emitted from the eastern part of China.

황사 에피소드 발생시 대기먼지의 농도 특성과 인체 영향 (Concentration Characteristics and Health Effect Assessment of Atmospheric Particulate Matters During Asian Dust Storm Episodes)

  • 강공언
    • 한국환경보건학회지
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    • 제35권1호
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    • pp.21-35
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    • 2009
  • The Asian dust storms which originated in the deserts of Mongolia and China transported particles to Korea and led to a high concentration of atmospheric particulate matters (PM) of more than $1000{\mu}g/m^3$ throughout the country in the spring, of 2007. Public concern, in Korea, about the possible adverse effects of these dust events has increased, as these dust storms can contain various air pollutants emitted from heavily industrialized eastern China. The objectives of this study were to understand the concentration characteristics of PM as a function of particle size between the Asian dust storm episodes and non-Asian dust period and to consider the mass size distribution of PM in the Asian dust storms and their water soluble ion species on the potential, possible effects on deposition levels in the three regions (nasopharyngeal, tracheobronchial, and alveolar) of the human respiratory system. The size distribution of PM mass concentration during the Asian dust storms showed a peak in the coarse particle region due to the long-range transport of soil particles from the deserts of Mongolia and China, which was identified by HYSPLIT-4 model for backward trajectory analysis of air arriving in the sampling site of Iksan. During the non-Asian dust period, there were two different types in PM size distribution: bimodal distribution when low concentrations of $PM_{2.5}$ were observed, while unimodal distribution having a peak in fine particle region when high concentrations of $PM_{2.5}$ were showed. This unimodal distribution with high concentrations of fine particulate and secondary air pollutants such as ${SO_4}^{2-}$, ${NO_3}^-$, ${NH_4}^+$ was found to be due to the long-range transport of air pollutants from industrialized eastern China. During the Asian dust storms, the mean concentrations of PM that can be deposited in the nasopharyngeal, tracheobronchial, and alveolar region were $128.8{\mu}g/m^3$, $216.5{\mu}g/m^3$, and $89.6{\mu}g/m^3$, respectively. During the non-Asian dust period, the mean concentrations of PM that can be deposited in the nasopharyngeal, tracheobronchial, and alveolar region were $8.4{\mu}g/m^3$, $9.5{\mu}g/m^3$ and $38.5{\mu}g/m^3$, respectively.

부산지역 대기측정망 자료에 나타난 미세먼지 농도의 시계열 해석 (Interpretating the Spectral Characteristics of Measured Particle Concentrations in Busan)

  • 손혜영;김철희
    • 한국대기환경학회지
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    • 제25권2호
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    • pp.133-140
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    • 2009
  • In order to examine the effects of micrometeorological and climatological influences on urban scale particulate air pollutants observed in Busan, power spectrum analysis was applied to the observed particulate matter with aerodynamic diameter ${\le}10{\mu}m$ ($PM_{10}$) for the period from 1991 to 2006. Power spectrum analysis has been employed to the daily mean $PM_{10}$ concentrations obtained at 13 sites to identify different scales of periodicities of $PM_{10}$ concentrations. The results show that, aside from the typical and well-known periodicities such as diurnal and annual variations caused by anthropogenic emission influences, another two significant peaks of power spectrum density were identified: 21 day and $3{\sim}4$ year of periodicities. Cospectrum analysis indicates that the intraseasonal 21 day periodicity are found to be negatively correlated with wind speed and surface pressure but shows consistently positive with relative humidity and temperature. This result implied that 21 day periodicity is presumably relevant to the secondary aerosol formation processes through the photochemical reaction that can be subsequently resulted from hygroscopic characteristics of aerosol formation. However, the interannual $3{\sim}4$ year of periodicity is found to have positive correlation with pressure, and negative with temperature and relative humidity, which is rather consistent with both characteristics of air mass during the Asian dust event and the occurrence frequency of Asian dust whose periodicities have been recorded inter-annually over the Korean peninsula.

그물망 압착식 섬유여과장치를 이용한 물 재이용 시스템 개발 (Development of Water Reusing System by Using Net3FM (Net Fit Fiber Filter Module))

  • 김정숙;김미란;조명찬;장정국
    • 한국환경과학회지
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    • 제21권12호
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    • pp.1523-1528
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    • 2012
  • This study was carried out to develop pilot plant Net3FM(Net Fit Fiber Filter Module) system and to suggest optimum operating condition for municipal wastewater reuse. SS concentration of biologically treated sewage effluent was reduced from 1.5~5.4mg/L to 0.4~1.0mg/L without coagulant injection in Net3FM system, and the SS removal efficiency was average 84.7%. And also, the removal efficiencies of COD and T-P were decreased slightly due to the SS removal by filtration. Coagulation-Filtration test was conducted to enhance the removal efficiencies of SS and T-P. The optimum dosage of coagulant was injected automatically by auto-controlling system, which is controlled by detecting value of turbidity of secondary sewage effluent. SS, COD and T-P concentrations in filtrated effluent were 0.21~0.57, 1.6~6.2 and 0.137~0.392mg/L with coagulant injection by in-line mixer in Net3FM system, respectively. The removal efficiencies of SS and T-P were highly increased to 92.8% and 89.8%, respectively. It was due to the combined the processes of coagulation and filtration. Net3FM system was evaluated that the removal efficiency of pollutants in secondary sewage effluent and the utilization potential as reclaimed water technology were very high.