• Title/Summary/Keyword: secondary pollutants

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Analysis of Chemical and Meteorological Effects on the Concentration Difference of Photochemical Air Pollutants between Coastal and Inland Regions in Busan (부산시 해안 및 내륙지역에서 광화학 오염물질의 농도 차이에 영향을 주는 화학 및 기상조건 분석)

  • Sang, Sang-Keun;Shon, Zang-Ho
    • Journal of Environmental Science International
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    • v.17 no.10
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    • pp.1169-1182
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    • 2008
  • The chemical and meteorological effects on the concentration variations of air pollutants ($O_3$ and its precursors) were evaluated based on ground observation data in coastal and inland regions, Busan during springs and summers of 2005-2006. For the purpose of this study, study areas were classified into 5 categories: coastal area (CA), industrial area (IA), downtown area (DA), residential area (RA), and suburban area (SA). Two sites of Dongsam (DS) and Yeonsan (YS) were selected for the comparison purpose between the coastal and inland regions. $O_3$ concentrations in CA and SA were observed to be highest during spring (e.g., 40 ppb), whereas those in DA and RA were relatively low during summer (e.g., $22\sim24$ ppb). It was found that $O_3$ concentrations in IA were not significantly high although high VOCs (especially toluene of about 40 ppb) and $NO_x$ ($\geq$ 35 ppb) were observed. On the other hand, the concentration levels of $O_3$ and $PM_{10}$ at the DS site were significantly higher than those at the YS site, but $NO_x$ was slightly lower than that at the YS site. This might be caused by the photochemical activity and meteorological conditions (e.g., sea-land breeze and atmospheric stagnance). When maximum $O_3$ (an index of photochemical activity) exceeds 100 ppb, the contribution of secondary $PM_{10}\;((PM_{10})_{SEC})$ to total observed $PM_{10}$ concentrations was estimated up to 32% and 17% at the DS and YS sites, respectively. In addition, the diurnal variations of $(PM_{10})_{SEC}$ at the DS site were similar to those of $O_3$ regardless of season, which suggests that they are mostly secondary $PM_{10}$ produced from photochemical reactions.

Case Study of Hazardous Air Pollutant Concentrations in Residential Areas nearby Small and Medium scale Shipbuilding Companies (중소규모 조선소 인근 주거지역의 유해대기오염물질 농도에 대한 사례연구)

  • Chung, Jae-Woo;Lee, Myoung-Eun
    • Journal of Environmental Science International
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    • v.18 no.5
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    • pp.517-525
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    • 2009
  • We measured ambient concentrations of hazardous air pollutants such as volatile organic compounds (VOCs) and aldehydes in residential areas nearby small and medium scale shipbuilding companies. The VOC concentrations were higher during the normal operation periods than vacation at which almost all operations were shutdown. Concentrations of VOCs was higher, as the sampling site was nearer from shipbuilding companies. The major components of VOCs were m,p-xylene, ethylbenzene, o-xylene, toluene, and 1,3,5-trimethylbenzene which had been found as major VOC compounds emitted from painting processes of shipbuilding in the previous studies. The major components of aldehydes analyzed were benzaldehyde, acrolein, formaldehyde, and acetaldehyde. The concentration of aldehydes was highest at the furthest sampling point from shipbuilding companies because the formation of aldehyde compounds could be occurred by the secondary chemical reactions of VOCs. The results of this study shows a proper counterplan need to be established for the reduction of hazardous air pollutants emitted from small and medium scale shipping companies.

A Study of Concentration Prediction of Automobile Air Pollutant Near the Highway (자동차 대기오염물질이 고속도로 인접지역에 미치는 농도 예측에 관한 연구)

  • Park, Seong-Gyu;Kim, Sin-Do;Kim, Jong-Ho
    • Journal of Korean Society for Atmospheric Environment
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    • v.14 no.6
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    • pp.607-620
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    • 1998
  • The influence of transportation on air quality has been elevating in urban area. Air pollutants from automobiles cause primary and secondary air pollution, and need to be tightly controlled. In this study, the effect of automobile air pollutants on highway vicinity area was evaluated by the comparison of field measurement. and target was for modeling using CALINE3, NO2 was the target for this work. It was found that the concentration predicted by CALINE3 is overestimated at low wind speed and input data of wind speed requires correction. Based on the measured data, the wind speed was modified by effective wind speed equation [Ue=U+0.24·EXP(-pxU)], and there after the accuracy of CALINE3 calculation was improved neighborhood area of highway. It was also observed that weather conditions and traffic volume affect the concentration of air pollution. Finally, the NO2 effect of automobile air pollutants on the vicinity area of highway proved to be up to 400∼600m from the highway.

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Air Quality Management in the Industrial Estate, HAP or VOC\ulcorner (산업단지 대기질 관리, HAP인가 VOC인가\ulcorner)

  • 김영성
    • Journal of Korean Society for Atmospheric Environment
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    • v.15 no.4
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    • pp.513-517
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    • 1999
  • Problems of secondary pollution and hazardous pollutants have rapidly come to the front in our society during the past few years. More attention should be paid to monitoring and assessment in order to identify the nature of complicated problems, but our air-quality policy is hurriedly seeking for management strategies. A typical example is air quality management in the industrial estates such as those located in Yochon and Ulsan. Yochon Industrial Estate was designated as a special air-quality management area of volatile organic compounds(VOCs) in 1996. And VOCs in the air of Ulsan Industrial Estate has been specially controlled since 1997. In this paper, however, it is suggested that hazardous air pollutants(HAPs) rather than VOCs should have been managed in the industrial estates. History of studies on organic compounds in the air of the industrial estates is reviewed. A stepwise approach for air quality management in the industrial estates is recommended.

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Experimental Study on Thermal NOx and CO Emission in a Laboratory-Scale Incinerator with Reversed Secondary Air Jet Injection (역방향 2차 공기 주입 방식을 적용한 소각 연소로의 Thermal NOx 및 CO 배출특성에 대한 축소모형실험 연구)

  • Choi, Chonggun;Choi, Woosung;Shin, Donghoon
    • Transactions of the Korean Society of Mechanical Engineers B
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    • v.40 no.8
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    • pp.503-510
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    • 2016
  • Incinerators generally emit pollutants such as NOx and CO during the combustion process. In this paper, pollutant emissions and temperature distributions were studied in a simulated incinerator with a reversed (relative to the flue gas flow) secondary air injection system. The experiments were performed by using a lab-scale furnace in order to evaluate the effects of the injection location, direction and flow rate of secondary air jets. The emission of NOx was lower in the case of reversed secondary air injection than in the case of cross injection, due to the recirculation and mixing of the exhaust gas. In the reversed air injection cases, thermal NOx emissions decreased as secondary air ratio increased from 30 to 60 and slightly increased at secondary air ratios higher than 60. In most cases, CO emissions were not detected except for a few reversed secondary air injection cases, in which cases CO concentrations below 2ppm were observed.

The Aerosol Characteristics in Coexistence of Asian Dust and Haze during 15~17 March, 2009 in Seoul (짙은 황사와 연무가 공존한 대기의 에어러솔 특성 - 2009년 3월 15~17일 -)

  • Lee, Hae-Young;Kim, Seung-Bum;Kim, Su-Min;Song, Seung-Joo;Chun, Young-Sin
    • Journal of Korean Society for Atmospheric Environment
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    • v.27 no.2
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    • pp.168-180
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    • 2011
  • The variation of the physicochemical properties of atmospheric aerosols in coexistence of the heavy Asian Dust and Haze observed from $15^{th}$ to $17^{th}$ March 2009 in Seoul was scrutinized through the mass and ion concentration observations and synoptic weather analysis. Although the ratio of PM1.0/PM10 was constant at 0.3 (which is typical during Asian Dust period in Korea) during the measurement period, both PM10 and PM1.0 mass concentrations were 3~6 times and 2~4 times higher than that of clear days, respectively. Water-soluble ion components accounted for 30~50% of PM10 and 50~70% of PM1.0 mass concentration. One of the secondary pollutants, $NO_3^-$ was found to be associated with $Ca^{2+}$ and $Na^+$ in coarse mode indicating that the aerosol derived from natural source was affected by anthropogenic pollutants. While the acidity of the aerosols increased in fine mode when the stagnation of weather patterns was the strongest (March $16^{th}$), the alkalinity increased in coarse mode when new air masses arrived with a southwestern wind after ending a period of stagnation (March $17^{th}$). In the selected case, SOR (Sulfur Oxidation Ratio, $nSO_4^{2-}/[nSO_4^{2-}+nSO_2]$) and NOR (Nitrogen Oxidation Ratio, $nNO_3^-/[nNO_3^-+nNO_2]$) values of ion components were higher than the general values during Asian Dust period. These results imply that dust aerosols could be mixed with pollutants transported from China even in heavy Asian Dust cases in Korea.

Emission Estimation and Exposure to Hazardous Gaseous Pollutants Associated with Use of Air Fresheners Indoors (실내 방향제 사용에 의한 유해 가스상 오염물질 배출 산정 및 노출 평가)

  • Jo, Wan-Kuen;Shin, Seung-Ho;Kwon, Gi-Dong;Lee, Jong-Hyo
    • Environmental Analysis Health and Toxicology
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    • v.24 no.2
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    • pp.137-148
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    • 2009
  • This study quantitatively investigated the emissions of indoor air pollutants associated with the utilization of air fresheners indoors, and evaluated individual exposure to five specified indoor air pollutants, which were chosen on the basis of selection criteria. An electrically-polished stainless steel chamber (50L) was employed to achieve this purpose. Test air fresheners were selected through three steps: first, on the basis of market sales; second, on the basis on a preliminary head-space study; and lastly, on the basis of emissions of toxic compounds (benzene, ethyl benzene, limonene, toluene, and xylene). The empirical mathematical model fitted well with the time-series concentrations in the environmental chamber (in most cases, determination coefficient, $R^2{\gtrsim}$0.9), thereby suggesting that the empirical model was suitable for testing emissions. The concentration equilibrium appeared 180 min after the introduction of sample air fresheners into the chamber. Both the chamber concentrations of emission rates or factors varied greatly according to air freshener type. It is noteworthy that although benzene, ethyl benzene, toluene, and xylene were emitted from all test air fresheners, their exposure levels were not significant enough to result in any significant health risk. However, certain type of air fresheners were observed to emit significant amount of limonene, which is potentially reactive with ozone to generate secondary pollutants with oxidants such as ozone, hydroxyl radicals, and nitrogen oxides. The exposure levels to limonene associated with the utilization of three air fresheners were estimated to be 13 to 175 times higher than that of other air fresheners. This information can help consumers to select low-pollutant-emitting air fresheners.

Air pollution and hospital admissions for chronic obstructive pulmonary disease: are their potentially sensitive groups?

  • Tsai, Shang-Shyue;Yang, Ya-Hui;Liou, Saou-Hsing;Wu, Trong-Neng;Yang, Chun-Yuh
    • Advances in environmental research
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    • v.1 no.1
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    • pp.57-68
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    • 2012
  • Recent studies showed that air pollution is a risk factor for hospitalization for chronic obstructive pulmonary disease (COPD). However, there is limited evidence to suggest which subpopulations are at higher risk from air pollution. This study was undertaken to examine the modifying effect of specific secondary diagnosis (including hypertension, diabetes, pneumonia, congestive heart failure) on the relationship between hospital admissions for COPD and ambient air pollutants concentrations. Hospital admissions for COPD and ambient air pollution data for Taipei were obtained for the period from 1999-2009. The relative risk of hospital admissions for COPD was estimated using a case-crossover approach. None of the secondary diagnosis we examined showed much evidence of effect modification.

Analysis of Combustion Air Flow in Incinerator (소각로의 연소 공기 유동 해석)

  • Lee, Dong-Hyuk
    • Design & Manufacturing
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    • v.16 no.2
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    • pp.26-32
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    • 2022
  • It is known that the fluidized bed incinerator, which is the subject of analysis, shows excellent performance in heat and mass transfer due to excellent mixing and contact performance between fluidized sand and fuel, and also shows relatively good combustion characteristics thanks to good mixing and long residence time for low-grade fuels. have. In this study, air flow analysis is performed to understand the characteristics of co-firing of sludge, waste oil and solid waste in the fluidized bed incinerator, flow characteristics of flue gas, and discharge characteristics of pollutants.The fluidized bed incinerator subject to analysis is a facility that incinerates factory waste and general household waste together with sludge, with a processing capacity of 32 tons/day. to be. In addition, the operation method was designed for continuous operation for 24 hours. As a result, it can be seen that the lower combustion air and the introduced secondary air are changed to a strong turbulence and swirl flow form and exit through the outlet while rotating inside the freeboard layer. The homogeneous one-way flow form before reaching the secondary air nozzle has very high diffusivity with the high-speed jet flow of the nozzle.

Treatment Efficiency of a Pond-Wetland System for the Water Quality Conservation of Estuarine Lake (담수호 수자원보전을 위한 수질정화 연못-습지 시스템의 초기처리수준)

  • Yang, Hongmo
    • Journal of the Korean Society of Environmental Restoration Technology
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    • v.4 no.4
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    • pp.64-71
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    • 2001
  • Treatment efficiency was examined of a pond-wetland system constructed for water quality conservation of Koheung Estuarine Lake over one year after its establishment in July 2000. The system is composed of primary and secondary ponds in series and six wetland cells in parallel. Cattails (Typha angustiflora) were planted in three wetland cells and common reeds (Phragmites australis) in three other cells. Water pumped from Sinyang Stream flowing into the Lake was funneled into primary pond whose effluent was discharged into secondary pond by gravity flow. Effluent from secondary pond was distributed into each wetland cell. SS, $BOD_5$, T-N, and T-P concentrations in influent to primary pond, and effluent from primary pond, secondary pond, and three wetland cells planted with cattails were analyzed for about one year from August 2000 to August 2001. The removal rates at primary pond for SS, $BOD_5$, T-N and T-P were 29%, 30%, 15%, and 36%, respectively. The abatement rates at secondary pond for SS, $BOD_5$, T-N and T-P were 38%, 40%, 30%, and 47%, respectively. The reduction rates measured at three cattail-planted wetland cells for SS, $BOD_5$, T-N and T-P were 54%, 57%, 60%, and 68%, respectively. Considering early stage of the pond-wetland system and inclusion of winter during the research period, its treatment efficiency was rather good. Cattails had not yet grown to dense stands due to initial establishment period, which resulted in slightly lower treatment efficiencies of wetland cells for these pollutants, compared with those of ponds.

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