• Environmental Engineering Research
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• v.21 no.3
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• pp.311-317
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• 2016

A new type of biofilter packed with composite carriers was designed for tertiary denitrification of the secondary effluent with removal of both oxidized nitrogen and suspended solids (SS). At the empty bed residence time of 15 min and organic carbon to nitrate nitrogen ($C/NO_3-N$) ratios of 2, 1.5 and 1 g/g, the removal percentage of $NO_3-N$ was 67%, 58% and 36% in the ethanol biofilter, and was 61%, 43% and 26% in the acetate biofilter, respectively. The biofilters packed with composite carriers removed SS effectively, with the effluent turbidity in both biofilters of less than 3 NTU. During the operating cycle between the biofilter backwashings, the $NO_3-N$ removal percentage decreased initially after backwashing, and then gradually increased. Under $C/NO_3-N$ ratios of 2, 1.5 and 1 g/g, the $NO_3-N$ reduction rate was 1.75, 1.04 and $0.68g/m^2/d$ in the ethanol biofilter, and was 1.56, 1.07 and $0.76g/m^2/d$ in the acetate biofilter, respectively. In addition, during denitrification, the ratio of the consumed chemical oxygen demand to the removed $NO_3-N$ was 5.06-8.23 g/g in the ethanol biofilter, and was 4.26-8.6 g/g in the acetate biofilter.

• Journal of Korean Society for Atmospheric Environment
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• v.31 no.4
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• pp.345-355
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• 2015

Carbonaceous compounds in the atmospheric particulate matter with an aerodynamic diameter of less than or equal to a nominal $10{\mu}m$ ($PM_{10}$) were analyzed for the samples collected during the period of August 2006 to August 2007 at Jongro in Seoul. A total 18 dicarboxylic acids (DCAs) and levoglucosan, as well as organic carbon (OC), elemental carbon (EC), and water soluble organic carbon (WSOC), were analyzed. Distinctive seasonal patterns of the concentrations of OC, EC, and WSOC including levoglucosan were observed with the highest concentrations in winter and the lowest concentrations in summer. In addition, OC, WSOC, and most of DCAs showed also higher concentration in summer than in winter. Using the seasonal patterns and relevant indicative ratios (WSOC/EC and $OC_{sec}/OC_{tot}$) of the carbonaceous compounds, it was verified that (1) primary emission sources were elevated in winter, and (2) the formation of secondary OC increased due to the prompted photochemical reaction in summer. Results from this study also suggest that some organic compounds were likely attributed to longrange transport.

• Asian Journal of Atmospheric Environment
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• v.10 no.1
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• pp.32-41
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• 2016

Particle-phase concentrations were measured at 10, 80, and 200 m from the roadside of a national highway near Seoul in January and May 2008. The highway has two lanes each way, with an average hourly traffic volume of 1,070 vehicles. In January 2008, $PM_{10}$ concentrations decreased from 10 to 80 m but increased at 200 m. Black carbon (BC) decreased only slightly with distance due to the influence of biomass burning and open burning from the surrounding areas. In May 2008, the effect of secondary formation on both $PM_{10}$ and $PM_{2.5}$ was significant due to high temperatures compared with January. Because on-road emissions had little effect on secondary formation for a short time, variations in $PM_{10}$ concentrations became smaller, and $PM_{2.5}$ concentrations increased with distance. The effects of fugitive dust on PM concentrations were greater in May than in January when the mean temperature was below freezing. In the composition variations, the amounts of primary ions, organic carbon (OC), and BC were larger in January, while those of secondary ions and others were larger in $PM_{10}$, as well as $PM_{2.5}$ in May.

• Carbon letters
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• v.4 no.1
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• pp.1-9
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• 2003

Recently, the control of pore-characteristics of nano-porous materials has been studied extensively because of their unique applications, which includes size-selective separation, gas adsorption/storage, heterogeneous catalysis, etc. The most widely adopted techniques for controlling pore characteristics include the utilization of pillar effect by metal oxide and of templates such as zeolites. More recently, coordination polymers constructed by transition metal ions and bridging organic ligands have afforded new types of nano-porous materials, porous metal-organic framework(porous MOF), with high degree and uniformity of porosity. The pore characteristics of these porous MOFs can be designed by controlling the coordination number and geometry of selected metal, e.g transition metal and rare-earth metal, and the size, rigidity, and coordination site of ligand. The synthesis of porous MOF by the assembly of metal ions with di-, tri-, and poly-topic N-bound organic linkers such as 4,4'-bipyridine(BPY) or multidentate linkers such as carboxylates, which allow for the formation of more rigid frameworks due to their ability to aggregate metal ions into M-O-C cluster, have been reported. Other porous MOF from co-ligand system or the ligand with both C-O and C-N type linkage can afford to control the shape and size of pores. Furthermore, for the rigidity and thermal stability of porous MOF, ring-type ligand such as porphyrin derivatives and ligands with ability of secondary bonding such as hydrogen and ionic bonding have been studied.

• The Korean Journal of Ecology
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• v.7 no.4
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• pp.203-207
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• 1984

This report is an investigation of the revegetation and secondary succession in the burned area of Mt. Sanseung in Taegu region. The forest fire took place in December, 1977. The survey was conducted eight times, -three times from October 1, 1983 to October 3, the same year and five times from August 10, 1984 to August 15, the same year. The floristic compositions in the sampled sites constituted 25 kinds of vascular plants and 21 kinds in the burned area and the unburned area respectively. The biological type in both the burned and unburned areas was H-D1-R5-e type, which is generally common to other areas (Taegu, Kyungpook, Chung Buk and Kangweon areas). In the burned area dominant species were Carex humilisvar. nana, Arundinella hirata and Quercus serrata and on the other hand, in the unburned area Pinus densiflora, Carex humilis var. nana, Rhododendron mucrfonulatum var. ciliatum and Quercus serrata. The species diversity diversity index(H) and eveness index(e) of the burned area were higher than those unburned area. Degree of succession (DS) was 650 in the burned area at the 6th years after the fires and 962 in the unburned area. THe vegetation of the burned area was slowly recovered as of 1984 compared with each other. According to the analysis of the soil preperties, pH, available phosphorus and exchangeable potassium were increased, but organic matter, total nitrogen and total organic carbon were decreased. It is assumed that these results were due to the forest fire.

• The Korean Journal of Ecology
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• v.12 no.4
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• pp.285-295
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• 1989

This report is results of an investigation on the secondary succession and species diversity of the burned area. Fifty hectares of pine forest was burned by the crown fire of the spring (April 6) 1986. The results obtained from spring 1989 were summarized as follows: In the burned area , site and unburned area (U), the vascular plant fo 69 kinds, 49 kinds and 24 kinds were lsted respectively. The life form spectrum of burned area was H---e type, which is common type in most burned area and that unburned area, H---e type. The species diversity (H)and evenness index (e) of burned area (, site) were H=2.51, 1.65 and e=0.59, 0.44 and those of unburned area (U) were H=1.28 and e=0.40. The similarity index was the value of 0.594 in - and 0.236 in -U site. The similarity between and site was greater than between site and U site, and that between and U-site, The dominance index (c) of , and U-site was 0.16, 0.39 and 0.42 respectively. The succession degree (DS) of , and U-site was 244.0, 227.6 and 854.4 respectively. Soil pH, available phosphorous, and exchangeable potassium in the burned area were higher than those in the unburned area, and total nitrogen, organic carbon, and C/N ratio in the burned area were higher than those in the unburned area, and organic matter in the burned area was higher than that in the unburned area.

• Particle and aerosol research
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• v.15 no.3
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• pp.91-104
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• 2019

In this study, hourly measurements of $PM_{2.5}$ and its major chemical constituents such as organic and elemental carbon (OC and EC), and ionic species were made between January 15 and February 10, 2018 at the air pollution intensive monitering station in Gwangju. In addition, 24-hr integrated $PM_{2.5}$ samples were collected at the same site and analyzed for OC, EC, water-soluble OC (WSOC), humic-like substance (HULIS), and ionic species. Over the whole study period, the organic aerosols (=$1.6{\times}OC$) and $NO_3{^-}$ concentrations contributed 26.6% and 21.0% to $PM_{2.5}$, respectively. OC and EC concentrations were mainly attributed to traffic emissions with some contribution from biomass burning emissions. Moreover, strong correlations of OC with WSOC, HULIS, and $NO_3{^-}$ suggest that some of the organic aerosols were likely formed through atmospheric oxidation processes of hydrocarbon compounds from traffic emissions. For the period between January 18 and 22 when $PM_{2.5}$ pollution episode occurred, concentrations of three secondary ionic species ($=SO{_4}^{2-}+NO_3{^-}+NH_4{^+}$) and organic matter contributed on average 50.8 and 20.1% of $PM_{2.5}$, respectively, with the highest contribution from $NO_3{^-}$. Synoptic charts, air mass backward trajectories, and local meteorological conditions supported that high $PM_{2.5}$ pollution was resulted from long-range transport of haze particles lingering over northeastern China, accumulation of local emissions, and local production of secondary aerosols. During the $PM_{2.5}$ pollution episode, enhanced $SO{_4}^{2-}$ was more due to the long-range transport of aerosol particles from China rather than local secondary production from $SO_2$. Increasing rate in $NO_3{^-}$ was substantially greater than $NO_2$ and $SO{_4}^{2-}$ increasing rates, suggesting that the increased concentration of $NO_3{^-}$ during the pollution episode was attributed to enhanced formation of local $NO_3{^-}$ through heterogenous reactions of $NO_2$, rather than impact by long-range transportation from China.

• Journal of the Korean Electrochemical Society
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• v.3 no.3
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• pp.173-177
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• 2000

The synthetic carbon was coated with tin oxide and copper by fluidized-bed chemical vapor deposition method. $(CH_3)_4Sn\;and\;Cu(hfac)_{2s}$ were employed as the metallic organic precursor, respectively. The modified synthetic carbons were used for lithium secondary battery anode to investigate their coating effects on electrochemical characteristics as alternative anode materials for lithium secondary batteries. The electrode which prepared by the synthetic carbons(MCMB) coated with tin oxide gave the higher capacity than that of raw material. Their capacity decreased with the progress of cycling possibly due to severe volume changes. But the cyclability was improved by coating with copper on the surface of the tin oxide coated carbon, which plays an important role as an inactive matrix buffering volume changes.

• Journal of Forest and Environmental Science
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• v.29 no.4
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• pp.249-256
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• 2013

The aim of the study was to reveal the scope and benefits derives from establishing carbon forests in a country like Bangladesh. Carbon forestry is the modernized forestry practice that evolves no cutting of trees or vegetation rather conserves them in the wood. Trees might be the source of carbon sink at large scale by establishing carbon forests. To find out how and in what extent forests of Bangladesh could contribute to global emission reduction, tree species of economic importance were taken into account about their carbon sequestration potential. Data source was a secondary one. Bangladesh has subtropical evergreen and deciduous forest tree species. Here trees can sequester almost 45-55 percent organic carbon in their biomass. On an average, trees in different types of stands can sequester 150-300 tC/ha. Carbon value of these forests might be 7,500-15,000 USD per hactre (assuming 50 USD per equivalent $tCO_2$). Thus, accounting tree carbon credits of total forested lands of Bangladesh, there might be a lump sum value of $1.89{\times}10^{10}-3.79{\times}10^{10}$ USD. If soil carbon is added, this amount would jump. Alternatively, there are two times higher spaces as marginal lands than this for starting carbon forestry. However, carbon forestry concept is still a theoretical conception unless otherwise their challenges are addressed and solved. Despite of this, forests of Bangladesh might be the key showcase for conserving biodiversity in association with carbon capture. Protected areas in Bangladesh are of government wealth, however, degraded and denuded waste and marginal lands might be the best fit for establishing carbon forests.

• Asian Journal of Atmospheric Environment
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• v.11 no.3
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• pp.165-175
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• 2017

In Japan, the primary carbonaceous particles emitted from motor vehicles and waste incinerators have been reduced due to strict regulations against exhaust gas. However, the relative contribution of carbonaceous particles derived from plants and biomass has been increasing. Accordingly, compositional analysis of carbonaceous particles has become increasingly important to determine the sources and types of particles produced. To reveal the sources of the organic particles contained in particulate matter with diameters of ${\leq}2.5{\mu}m$ ($PM_{2.5}$) and the processes involved in their generation, we analyzed molecular marker compounds (2-methyltetrols, cis-pinonic acid, and levoglucosan) derived from the plants and biomass in the $PM_{2.5}$ collected during daytime- and nighttime-sampling periods in summer (July and August) and autumn (November) in Kazo, which is in the northern area of Saitama prefecture, Japan. We also measured $^{14}C$ carbonaceous concentrations in the same $PM_{2.5}$ samples. The concentrations of 2-methyltetrols were higher in the summer than in the autumn. Because the deciduous period overlaps with this decrease in the levels of 2-methyltetrols, we considered the emission source to broad-leaved trees. In contrast, the emission source of the cis-pinonic acid precursor was considered to be conifers, because its concentration remained almost constant throughout the year. The concentration of levoglucosan was considerably increased in the autumn due to frequent biomass open burning. The ratio of plant-derived carbon to total carbon, obtained by measuring of $^{14}C$, in summer $PM_{2.5}$ sample was higher in the nighttime, and could be influenced by anthropogenic sources during the daytime.