• Journal of the Korean Society of Marine Environment & Safety
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• v.3 no.1
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• pp.99-109
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• 1997

The in situ observations and the seawater analyses were conducted in July and August, 1996 for the purpose of describing the characteristics of organic pollution, dissolved oxygen distributions, and the evaluation of water quality in Mokpo harbour. The vertical density distribution of water column was found to be in stable structure with higher water temperature and lower salinity on surface layer at ebb tide in summer. In July, dissolved oxygen was shown to be oversaturated on surface and bottom layers, while in August, which was shown to be oversaturated on surface layer, and to be unsaturated on bottom layer as 68∼93% of saturation percentage. Dissolved oxygen of bottom layer in August was evaluated to be under the regular grades, based on Korean standards of seawater quality. In view of COD, the seawater quality of Mokpo harbour in summer was evaluated to be deteriorated due to organic wastes and graded to be the third class, and TSS of Mokpo harbour in summer was graded to be the second class, based on Korean standards of seawater quality. In particular, COD of surface layer in August was found to be under the regular grades. It is, therefore, necessary to take measures for the control of pollution loads and the proper management of seawater quality in Mokpo harbour. The distribution patterns of DO, COD, VSS and Chlorophyll-a on surface layer along the downstream center line from inner harbour to harbour entrance were similar to one another at ebb tide in August.

• Corrosion Science and Technology
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• v.20 no.5
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• pp.281-288
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• 2021

Due to advancement of the industry, operation of a device in a harsh environment is increasing. Especially, the marine environment contains Cl^- ions which causes localized corrosion such as pitting and crevice corrosion of stainless steel and various metals. In this study, electrochemical corrosion behaviors of austenitic stainless steel (STS 316L) and nickel alloy (Inconel 600) with different seawater concentrations (fresh water, seawater, mixed water) were investigated. The STS 316L and Inconel 600 were etched in 10% oxalic acid and composed of an austenitic phase. Results of Tafel analysis in seawater showed that STS 316L and Inconel 600 presented the highest corrosion current densities of 7.75 × 10^-4 mA/cm² and 1.11 × 10^-4 mA/cm² and the most negative pitting potentials of 0.94 V and 1.06 V, respectively. The maximum damage depths and surface damage ratio by pitting corrosion increased with chloride concentration. The STS 316L had higher PREN than Inconel 600. However, the surface damage and weight loss of Inconel 600 were superior to STS 316L. It was difficult to compare the pitting resistance of STS 316L based on Fe and Inconel 600 based on Ni with PREN simply.

• Journal of the Korean Society of Marine Environment & Safety
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• v.25 no.3
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• pp.334-343
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• 2019

The Al-Zour coastal area, located in southern Kuwait, is a region of concentrated industrial water use, seawater intake, and the outfall of existing power plants. The Al-Zour LNG import facility project is ongoing and there are two issues regarding the seawater temperature in this area that must be considered: variations in water temperature under local meteorology and an increase in water temperature due to the expansion of the thermal discharge of expanded power plant. MIKE 3 model was applied to simulate the water temperature from June to July, based on re-analysis data from the European Centre for Medium-Range Weather Forecasts (ECMWF) and the thermal discharge input from adjacent power plants. The annual water temperatures of two candidate locations of the seawater intake for the Al-Zour LNG re-gasification facility were measured in 2017 and compared to the numerical results. It was determined that the daily seawater temperature is mainly affected by thermal plume dispersion oscillating with the phase of the tidal currents. The regional meteorological conditions such as air temperature and tidal currents, also contributed a great deal to the prediction of seawater temperature.

• Journal of Environmental Science International
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• v.11 no.8
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• pp.793-800
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• 2002

Butyltin (BT) compounds were measured in seawater, sediment, sediment core, settling solids, and plankton from Gwangyang Bay in 2001, Tributyltin (TBT) was detected in seawater from 1 out of the 7 seawater sampling sites and in sediment from 18 out of the 35 sediment sampling sites. The highest concentration of TBT was found in the sediment from the site near Yeosu Harbor (53 ng Sn/g dry wt), acting as the point source for TBT The mean concentrations of TBT were in the order of plankton> settling solids> sediment. The degradation indexes ([DBT]+[MBT]/[TBT]) for the plankton were less than 1, indicating the possibility of recent inputs of TBT. The indexes for the sediment and settling solids ranged from 1.14 to 8.73. The composition of the BT compounds found in the settling solids was similar to that found in the sediment. The vertical profile of the total BT compounds in the sediment was characterized by an abrupt decline from the surface. However, no butyltin compounds appeared below a depth of 10 cm, corresponding to the 1980s. Accordingly, the current results demonstrated that the levels of all butyltin species in the environment of Gwangyang Bay were relatively lower than those in other polluted coastal areas. The vertical profile also suggested a fairly recent history for the down-core.

• Journal of the Korean Society for Marine Environment & Energy
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• v.8 no.2
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• pp.74-77
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• 2005

The injection of cement stabilizer is used as one of ways to stabilize soft sea-bottom. However, this method makes an argument for the possibility of releasing heavy metals from the cement stabilizer to the seawater. To investigate the effect of the cement stabilizer on the seawater, field measurements were carried out in Ocheon harbor of the Chunsoo Bay. Although the highest concentrations of dissolved heavy metals were found in the surface seawater of the injection point and the metal concentrations decreased with distances, the levels of heavy metals in all the seawater met the demand of environmental criteria of Korea, US and UK.

• Journal of Soil and Groundwater Environment
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• v.7 no.4
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• pp.59-67
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• 2002

As a parameter for hydrodynamic modeling to define the range of seawater intrusion, dispersivities are frequently determined from pre-experiments or theoretical studies because field experiments need a lot of time and expenses. If the dispersivities are inadequate for an aquifer, the numerical results may have some errors. We examined the validity of longitudinal dispersivities by comparing the ranges of seawater intrusion with numerical modeling, field data and apparent resistivity sections. In the numerical modeling the TDS distributions simulated by the Xu's longitudinal dispersivity are more similar to the values of TDS measured at monitoring wet]s and boreholes than those by the Neuman's longitudinal dispersivity. The ranges of seawater intrusion by numerical simulations using Xu's longitudinal dispersivity show that the contour line of 1000 ㎎/L. as TDS is located at 480 m from the coast in May, while at 390 m in July. The difference is originated from the shift of the interface between seawater and fresh water. It moved toward the coast in July because of the seasonal increase of hydraulic gradient according to rainfall. A contour line of 15 ohm-m was used to define the range of seawater intrusion in apparent resistivity sections. From this criterion on the interface between seawater and fresh water, the range of seawater intrusion is located at 450 m from the coast. This result is similar to the range of seawater intrusion simulated by the numerical modeling using Xu's dispersivity. Therefore the range of seawater intrusion shows the difference due to the dispersivities used for the hydrodynamic modeling and the dispersivity generated by the Xu's equation is considered more effective to decide the range of seawater intrusion in this study area.

• Journal of the Korean Society for Marine Environment & Energy
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• v.4 no.3
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• pp.3-15
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• 2001

The in situ observations and the seawater analyses were conducted for 3 years from August 1996 to August 1999 in order to elucidate and evaluate seasonal variations of marine water quality and trophic state in Mokpo harbour of Korea. Compared the seasonal seawater qualities of Mokpo harbour with the OECD standards of trophic classification in parameters such as Secchi depth, dissolved inorganic nitrogen, phosphate phosphorus and chlorophyll-a, the trophic level of seawater in Mokpo harbour was evaluated to be in mesotrophic or eutrophic state through all 4 seasons and to be in eutrophic state, particularly In summer. The estimation of pollution index by eutrophication showed the seawater quality of Mokpo harbour to deteriorate and fall under the regular grades through all 4 seasons, although the seawater quality of Mokpo harbour was evaluated to be equivalent to the second or third class of the Korean seawater quality standards in view of COD values. The results of eutrophication index estimation showed the high potentiality of red tide occurrence In Mokpo harbour, particularly in summer or fall. In the light of the average atomic ratio of N/P in seawater, the limiting nutrient factor against the growth of phytoplankton was concluded to be phosphorus rather than nitrogen in Mokpo Harbour.

• Journal of Soil and Groundwater Environment
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• v.8 no.1
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• pp.68-74
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• 2003

SHARP numerical model was used to estimate the interface, ranges and seasonal variations of seawater intrusion. The interface obtained from the SHARP model represented more sensitive to seasonal variations than that estimated from the monitoring wells. When TDS and groundwater velocity vector distributions generated by SUTRA simulations are compared to the interfaces obtained from SHARP simulation, the difference of the range on seawater intrusion is less than 50 m, and the range of seawater intrusion from seasonal variations has the difference of about 12 m. These differences are small for the numerical simulation of the coastal aquifer at regional scale. Therefore, the model with sharp interface is very useful to estimate the interface at this study site, where is regional aquifer system in the scale of seawater infusion. However the SHARP model have some limitations in simulating the range of seawater intrusion, when the hydrodynamic dispersion is significant for seawater intrusion at local aquifer system.

• Applied Chemistry for Engineering
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• v.34 no.6
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• pp.567-575
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• 2023

Water electrolysis is undergoing active research as one of the promising technologies for producing effective green hydrogen. Using seawater directly as a raw material for a water electrolysis system can solve the problem of the limitations of existing freshwater raw materials, as seawater accounts for approximately 97% of the water on Earth. At the same time, abundant by-product materials can be obtained, representative examples of which are Cl₂, ClO^-, Br₂, and Mg(OH)₂ produced during electrolysis, depending on their composition and pH environment. In order to develop a successful seawater electrolysis system and oxygen evolution reaction (OER) and hydrogen evolution reaction (HER) catalysts, it is necessary to understand the causes and consequences of reactions that occur in the seawater environment. Therefore, in this paper, we will investigate the reaction mechanism and characteristics of the seawater electrolysis system as well as the research and development trends of electrochemical catalysts used in anode and cathode electrodes.

• Environmental Sciences Bulletin of The Korean Environmental Sciences Society
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• v.10 no.S_3
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• pp.107-111
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• 2001

Surface seawater was sampled from 20 stations in Youngil Bay, Korea in November 2000. The samples were analyzed for eight chlorobenzenes(CBs) out of a total of 12 in the congener series using a gas chromatography coupled to a mass spectrometer detector(GC/MSD). The total CB levels varied from 1.3 to 6.1 ng/L with a mean of 4.0 ng/L. Trichlorobenzene groups (sum of 1,3,5-, 1,2,4-, and 1,2,3-trichlorobenzene) were the predominant class among the four congener groups, while tetrachlorobenzenes(sum of 1,2,3,5-, 1,2,4,5-, and 1,2,3,4- tetrachlorobenzene) and pentachlorobenzene showed a low presence. The total CB levels exhibited similar patterns for all the stations. A significant positive correlation was observed between the individual CB compounds in the particulate samples, while the dissolved samples revealed a strong correlation between the heavier molecular weight CBs.