• Journal of the Korean Society for Marine Environment & Energy
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• v.12 no.3
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• pp.202-208
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• 2009

In order to understand the circulation of nutrient between muddy tidal flat and the surrounding coastal area, tidal time-scale variations in nutrient concentrations were seasonally investigated at the entrance of Hampyeong Bay. The results show that the temperature was higher in ebb tide and lower in flood tide during the summer, but it was lower in ebb tide and higher in flood tide during the autumn/winter. The salinity was higher in flood tide and lower in ebb tide during the summer/winter because of the inflow of external sea water resulting from the increase in the tide level. By contrast, the salinity was lower in flood tide and higher in ebb tide during the autumn. Salinity difference was lower than 0.3 psu between flood tide and ebb tide during survey period. Meanwhile, all nutrient concentrations observed in Hampyeong Bay was lower in flood tide and higher in ebb tide during the summer, and by contrast, it was higher in flood tide and lower in ebb tide during the winter. Characteristically, no clear variation of concentrations was found depending on the tide level during the autumn. This tidal variations imply that the muddy tidal flat of Hampyeong Bay supplies nutrients to the seawater in summer and removes nutrient from the seawater in winter. During tidal cycle, seasonal variation of nutrient concentration in seawater is considered as the result of complex interactions between the mud flat and external sea water.

• Korean Journal of Environmental Biology
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• v.22 no.3
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• pp.419-425
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• 2004

Two different groups (30 and 60 inds.) of olive flounder (Paralichthys olivaceus) were abruptly (within 30 min) exposed to hypo-salinities from seawater (SW, 35$\textperthousand$) to freshwater (FW, 0$\textperthousand$) (30FW and 60FW) and to 35$\textperthousand$ (30SW and 60SW) in a flow through seawater culture systems. Analysis of plasma samples showed the following significant increase at 0$\textperthousand$: cortisol from $2.8\;ng\;mL^{-1}$ to $66.9\;ng\;mL^{-1}$ (30FW) and from $2.7\;ng\;mL^{-1}$ to $314.1\;ng\;mL^{-1}$ (60FW) after 24 hours of exposure; glucose from $15.8\;mg\;dL^{-1}$ to $257.7\;mg\;dL^{-1}$ after 3 hours exposure and to $164.0\;mg\;dL^{-1}$ after 24 hours in 60FW. Plasma $Na^+$ concentration of 30FW and 60FW were decreased until 24 hours after expose. However that in 30SW and 60SW showed no significant differences. Plasma $Cl^-$ concentration of 60FW was decreased from $59.0\;mEq\;L^{-1}$ to $43.5\;mEq\;L^{-1}$ and to $30.0\;mEq\;L^{-1}$ after 3 and 24 hours of exposure, respectively. At all experimental groups, survival were 100% until 24 hours.

• Korean Chemical Engineering Research
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• v.57 no.6
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• pp.758-762
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• 2019

Sodium borohydride,$NaBH_4$, has many advantages as hydrogen source for portable proton exchange membrane fuel cells (PEMFC). When PEMFC is used for marine use, $NaBH_4$ hydrolysis using seawater is economical. Therefore, in this study, hydrogen was generated by using seawater instead of distilled water in the process of hydrolysis of $NaBH_4$. Properties of $NaBH_4$ hydrolysis reaction using activated carbon supported Co-B/C catalyst were studied. The yield of hydrogen decreased as $NaBH_4$ concentration and NaOH concentration were increased during $NaBH_4$ hydrolysis using sea water. At higher concentrations of $NaBH_4$ and NaOH, byproducts adhered to the surface of the catalyst after hydrolysis reaction using sea water, reduced hydrogen yield compared to distilled water. The activation energy of $NaBH_4$ hydrolysis is 59.3, 74.4 kJ/mol for distilled water and sea water, respectively. In order to increase the hydrogen generation rate in seawater as high as distilled water, the reaction temperature has to be increased by $80^{\circ}C$ or more.

• Journal of the Korean Society of Marine Environment & Safety
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• v.18 no.6
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• pp.569-576
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• 2012

In general, aluminum alloys forms the passive film($Al_2O_3$, $Al_2O_3{\cdot}3H_2O$) in neutral solution. However, the passive film created on the surface will be destroyed by chloride ions contained in sea water so the corrosion will occur. In this study, in order to solve the problem of corrosion under a seawater environment, potentiostatic protection techniques were applied to Al-4.5%Mg-0.6%Mn aluminum alloy in seawater. At polarization experiments, active state were observed at anodic polarization and concentration polarization by reduction of dissolves oxygen and activation polarization were found at anodic polarization. As a results of potentiostatic experiment, calcareous deposit were created much more as applying time increase from the turning point of the concentration polarization and activation polarization and crevice corrosion was partially observed between calcareous deposit and surface of base metal. Overall potentiostatic anodic polarization experiment was difficult to apply potentiostatic corrosion protection technology by occurrence of active state, whereas potentiostatic cathodic polarization experiment examined optimum corrosion protection condition of -1.1 V~-0.75 V within the range of concentration polarization considered various applying time.

• Journal of Environmental Science International
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• v.11 no.7
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• pp.721-727
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• 2002

The characteristics of drinking groundwater quality at Chung Cheong Nam Do was analyzed by investigating the 3,086 groundwater data which were carried out the water quality inspection from Jan. 1998 to Dec. 1998. It was found that all the mean concentration of items was not over the drinking water quality standard except Zn at Yeongee area. The highest mean concentration of nitrate was $8.2 mg/{\ell}$ at Hongsung area. And the mean concentrations of nitrate and ammonium at Sucheon, Yesan, Yeongee were relatively higher. It was considered that the groundwater of that area was contaminated by breeding livestock as farm pollutants. The mean concentrations of chloride, hardness and evaporation residual at coastal regions were higher than inland regions. Especially the mean concentration of chloride was 2.5 times higher. It was considered that the groundwater at coastal regions was affected by seawater. It was found that the correlation between Fe and Mn was relatively high(r=0.776) and the correlation between hardness and evaporation residual was very high(r=0.983). The rainfall series and detection rate of E-coli had the hydrologic persistence. The correlation between the detection rate and rainfall series over 150 mm was very high (r=0.9146). Therefore it is surely required to control the groundwater sanitation in the rainy season.

• Journal of Environmental Health Sciences
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• v.22 no.4
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• pp.62-68
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• 1996

Precipitation samples were collected by the wet-only event sampling method at Seoul from September 1991 to April 1995. Concentrations of samples for the ion components($NO_3^-, NO_2^-, SO_4^{2-}, Cl^-, F^-, Na^+, K^+, Ca^{2+}, Mg^{2+}$ and $NH_4^+$) were measured in addition to pH and electric conductivity. During the sampling period, 182 samples were collected, but only 163 samples were identified as valid. The pH, calculated from the volume-weighted $H^+$ concentration, was found to be 4.7, indicating a relatively intensive acidity compared with data from other regions of the world, where acid deposition was known to be a problem. Above all, the concentration of non-seasalt sulfate was $84 \mu eq/L$, which was the highest compared to that measured in other regions of the world. The major acidifying ions in the precipitation at Seoul were identified as sulfate and nitrate except for chloride, because the Cl/Na ratio in the precipitation was close to the ratio in seawater. If all of the non-seasalt sulfate and nitrate existed in the form of sulfuric and nitric acids, respectively, the average pH in the precipitation was calculated as 3.7, lower than the measured value. Consequently, the difference between the calculated and measured pH suggest that the acidity of precipitation was neutralized by alkaline species, not due to the low contribution of an anthropogenic air pollutants to the precipitation. The equivalent concentration ratio of sulfate to nitrate was 3.5, which indicated that the contributions of sulfuric and nitric acids to the precipitation acidity were 78% and 22%, respectively.

• Korean Journal of Materials Research
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• v.29 no.1
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• pp.16-22
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• 2019

Indirect oxidation using chlorine species oxidizing agents is often effective in wastewater treatment using an electrochemical oxidation process. When chlorine ions are contained in the wastewater, oxidizing agents of various chlorine species are produced during electrolysis. In a ballast water management system, it is also used to treat ballast water by electrolyzing seawater to produce a chlorine species oxidizer. However, ballast water in the brackish zone and some wastewater has a low chlorine ion concentration. Therefore, it is necessary to study the chlorine generation current efficiency at various chlorine concentration conditions. In this study, the chlorine generating current efficiency of a boron-doped diamond(BDD) electrode and insoluble electrodes are compared with various chloride ion concentrations. The results of this study show that the current efficiency of the BDD electrode is better than that of the insoluble electrodes. The chlorine generation current efficiency is better in the order of BDD, MMO(mixed metal oxide), $Ti/RuO_2$, and $Ti/IrO_2$ electrodes. In particular, when the concentration of sodium chloride is 10 g/L or less, the current efficiency of the BDD electrode is excellent.

• Journal of the Korean Society for Marine Environment & Energy
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• v.11 no.4
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• pp.227-231
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• 2008

The purpose of this study is to clarify the behavior of stranded crude oil and to estimate the restoration of seawater infiltration by application of dispersant as one of cleaning techniques. We made visualization of infiltration process of seawater and stranded crude oil on the sandy beach sediments by using of a model sandy beach. Major conclusions derived from this study are as follows. The seawater infiltration volume was reduced by the stranded crude oil. However, thirty percentage of the sweater infiltration into the sediments was restored by dispersant application to the penetrated oil in sandy beach. The penetration depth of stranded oil were dropped at first falling tide, but were not significantly fluctuated after that. Moreover, oil concentration was most high within the upper 2 cm. The stranded crude oil was broken into small size droplets and dispersed into the sediments by the dispersant application. Therefore, dispersant applications play an important roles in the large increase of surface area of given volume of oil, and it resulted in promoting to biological degradation process at the oil/water interface, dispersing the stranded oil into the water column and restoration of the supplement of the dissolved oxygen and nutrients to the benthic organisms.

• Journal of the Korean Society for Marine Environment & Energy
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• v.18 no.1
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• pp.36-44
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• 2015

The spatial and temporal distribution of dissolved trace metals has been studied to identify trends in space and time and to evaluate the pollution status in a semi-closed bay (Gohyun bay), Korea. Surface seawater samples were collected over four seasons at 18 stations in the bay between 2003 and 2004 and once at 7 stations around a large shipyard in May 2004. The concentration of Cd, Co, Cu, Ni, Pb, and Zn in seawater in February and May were highly variable in space, showing the higher value relative to other season. Those metals concentrations were decreased from inner-to outer-stations. In around the shipyard, Cu, Pb and Zn showed the higher variability depending on time. Cu and Zn concentrations at the sites around the shipyard had 2 times higher values compared with the average of inner stations in Gohyun bay. The very high correlations between salinity and either Cu and Zn has been showed. Especially, there was a significant relationship between Cu and Zn. We recognize that the shipyard is major source of Cu and Zn in seawater. Therefore, marine environment management policy such as the prevention and control of heavy metal input from a shipyard is required.

• Korean Journal of Fisheries and Aquatic Sciences
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• v.25 no.4
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• pp.307-313
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• 1992

To study the seasonal variation of heterotrophic bacteria near the surrounding seawater of Porphyra forming area, samples were collected in the intertidal waters of Mokp'o of the Yellow Sea from February to December, 1990. Annual distribution of heterotrophic bacteria ranged from $7.5\times10^2\;to\;1.1\times10^5\;cfu/ml,$ annual distribution of physiological characteristic bacteria ranged from $5.0\times10\;to\;4.34\times10^4\;cfu/ml$ for proteolytic bacteria, from 0 to $1.35\times10^4\;cfu/ml$ for lipolytic bacteria and from 0 to $1.2\times10^4\;cfu/ml$ for amylolytic bacteria. Sixty-five percent of isolates from seawater were rods, and $76.7\%$ of isolates were Gram-negative. Most isolates were mesophiles and showed utilization of various carbon sources such as glucose, maltose, lactose, sucrose and arabinose. Most isolates also showed tolerance to a broad range of salt concentration. Dominant genus in seawater were Flavobacterium spp., in February, Moraxella spp., Acinetobacter spp. in March, Bacillus spp., Chromobacterium spp., Micrococcus spp., Vibrio spp. in July and Chromobacterium spp., Micrococcus spp., Bacillus spp. in November.