• Asian Journal of Atmospheric Environment
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• v.9 no.1
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• pp.66-77
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• 2015

In order to survey the seasonal variation of the chemical composition of particulate matter of $2.5{\mu}m$ or less ($PM_{2.5}$), $PM_{2.5}$ was sampled from 8 February 2013 to 31 March 2014 in an industrial area of Chiba Prefecture, Japan. Chemical measurements of the sample included: ionic components ($Na^+$, $NH_4{^+}$, $Ca^{2+}$, $Mg^{2+}$, $K^+$, $Cl^-$, $NO_3{^-}$ and $SO_4{^{2-}}$), carbonaceous components - organic carbon (OC) and elemental carbon (EC), and water-soluble organic carbon (WSOC). Also, secondary organic carbon (SOC) was measured based using the EC tracer method, and char-EC and soot-EC were calculated from the analytical results. The data obtained were interpreted in terms of temporal variation. Of the overall mean value of $PM_{2.5}$ mass concentration obtained during the study period, ionic components, OC and EC accounted for 45.3%, 19.7%, and 8.0%, respectively. $NO_3{^-}$ showed a unique seasonal distribution pattern due to a dependence on temperature and absolute humidity. It was estimated that an approximate temperature of $14^{\circ}C$, and absolute humidity of $7g/m^3$ were critical for the reversible reaction of $NH_4NO_3(p){\leftrightharpoons}NH_3(g)+HNO_3(g)$. The amount of OC and EC contributing to the monthly $PM_{2.5}$ mass concentration was higher in autumn and winter compared to spring and summer. This result could be attributed to the impact of burning biomass, since WSOC and the ratio of char-EC/soot-EC showed a similar pattern during the corresponding period. From the comparison of monthly WSOC/OC values, a maximum ratio of 83% was obtained in August (summer). The WSOC and estimated SOC levels derived from the EC tracer method correlated (R=0.77) in summer. The high occurrence of WSOC during summer was mainly due to the formation of SOC by photochemical reactions. Through long-term observation of $PM_{2.5}$ chemical components, we established that the degree to which the above-mentioned factors influence $PM_{2.5}$ composition, fluctuates with seasonal changes.

• Proceedings of the Korea Water Resources Association Conference
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• 2017.05a
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• pp.183-183
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• 2017

Pan evaporation (Epan) is an important indicator of water and energy balance. Despite global warming, decreasing annual Epan has been reported across different continents over last decades, which is claimed as pan evaporation paradox. However, such trend is not necessarily found in seasonal data because the level of contributions on Epan vary among meteorological components. This study investigates long-term trend in seasonal pan evaporation from 1908 to 2016 across South Korea. Meteorological variables including air temperature (Tair), wind speed (U), vapor pressure deficit (VPD), and solar radiation (Rs) are selected to quantify the effects of individual contributing factor to Epan. We found overall decreasing trend in Epan, which agrees with earlier studies. However, mixed tendencies between seasons due to variation of dominant factor contributing Epan were found. We also evaluated the reference evapotranspiration based on Penman-Monteith method and compared this with Epan to better understand the physics behind the evaporation paradox.

• Asian Journal of Atmospheric Environment
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• v.7 no.3
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• pp.169-175
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• 2013

Measurement of the phosphorus concentration in aerosols in Beijing, which was a representative East Asian mega-city, was carried out. The optimum procedure for analyzing phosphorus in aerosols was found in this study. Recovery of phosphorus in environmental samples through the improved method was almost 100%. The concentration of phosphorus in TSP was $145{\pm}47\;ng/m^3$, with a seasonal variation showing high concentrations in winter and low concentrations in summer. The concentrations of phosphorus in $PM_{2.5}$ accounted for $35{\pm}6%$ of those in TSP, with no seasonal variations. The major source of phosphorus in aerosols in Beijing was soil dust, and additional sources of phosphorus in fine particles could be coal combustion and biomass burning.

• Journal of Environmental Health Sciences
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• v.24 no.1
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• pp.62-69
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• 1998

It has been studied that the measurement of odor component emission at confectionery manufacture. The objects of this study were to investigate reduction of offensive odor. The survey effects of odorous materials are presented as follows. The countermeasure of operating process is to minimize sludge sediment in each unit facility. Especially, in summer, we have to clean the sludge frequently, because anaerobic decomposing is likely to occur easily. The sludge or scum from sedimentation tank pond, and floating tank should be treated quickly. We should avoid overloading operation. In the case of overloading, dissolved oxygen should be increased, the quality of wastewater input should be decreased. When dried cakes from condense tank or floating tank are left in treatment plant, we should cover, to prevent diffusion of smell with masking materials. The seasonal condition of operating should be fixed and the kind of coagulants should be changed because the wastewater in each season have different loading rates and organic materials. Odorous materials are very sensitive to the seasonal temperature variation. Especially, when the amount of rainfall is small and the high temperature of maintenance in long periods, air diffusion rate is large, so odorous materials can make great effect on surroundings comparision with other periods. To reduce odorous gas, as short term method, we had better take ceramic addition method. Especially, in summer we should take ceramic addition method. Also, as long term method, the size of wastewater treatment facility is the most important in the normal operating of wastewater treatment facility. But wastewater treatment facilities in this factory are too old, treatment process is old fashion, and the size is too small. So, large wastewater quantity to treat in summer. As results, the expansion of wastewater treatment facility and the process of improvement are required. Restriction level of odor was exceed. As it is overloaded in summer, the basis cause of odor is that the size of wastewater treatment facility is small. The prediction of air quality equilibrium density variation show that the odorous materials from working place are Amine materials whose smell strength is about 2.5(a little strong degree). We can suppose that in summer is sensitive to temperature variation, smell strength is larger as to reduce the origin of odor. We must expand wastewater treatment facility and improve the process A.S.A.P.

• Journal of the Korean earth science society
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• v.25 no.7
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• pp.545-557
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• 2004

The purpose of this study is to classify types of preconception on the seasonal change to middle school students and to find out how the developed multimedia material changes their conception in the seasonal change. The questionnaire about the variation of season consisted of 10 items. Questions are given to 80 ninth graders. Control and experimental group was 23 and 57 students, respectively and they were instructed for two class periods. A learning method using multimedia was applied to the experimental group. On the other hand, traditional teaching-learning method was used for the control group. A learning method using multimedia in this study had an effect on the conceptual changes (p$<$0.01). Data in this study was divided into six levels to classify the changes of concepts in detail. As a result, it showed that a learning method using multimedia was effective for students to make progress from unscientific to scientific concepts, to build up scientific concepts, to build up scientific concepts, and to elaborate scientific concepts as compared with traditional method.

• ALGAE
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• v.23 no.4
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• pp.311-316
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• 2008

The seasonal variation of marine algal biomass and community were studied with nondestructive sampling and quadrat method during May 2006 to April 2008 in the intertidal and subtidal zone at Yokjido. As result, total 120 species, 13 Chlorophyta, 34 Phaeophyta, 71 Rhodophyta and 2 Spermatophyta were identified in this study. The major species which contributed significantly to the total biomass were Ulva pertusa, Undaria pinnatifida, Ecklonia stolonifera, Sargassum horneri, S. serratifolium, Gelidium amansii and Prionitis cornea. The mean biomass was 235.5 g wet wt m$^{-2}$ in intertidal, 1,038.9 g wet wt m$^{-2}$ in 1 m, 1,013.1 g wet wt m$^{-2}$ in 5 m, and 19.7 g wet wt m$^{-2}$ in 10 m depths of mean sea level. Seasonal biomass change in intertidal zone, the peak season was in spring, while the lowest was in autumn. The vertical distribution of marine vegetation was characterized by Ulva pertusa - Gelidium divaricatum - Gloiopeltis furcata - Sargassum thunbergii - Hizikia fusiformis at intertidal zone, and Caulerpa okamurae - Gelidium amansii - Chondrus ocellatus - Ecklonia stolonifera - Sargassum horneri - Gracilaria textorii at subtidal zone. These result indicates that the marine algal species and biomass of 1 m and 5 m depths in subtidal zone are greater than intertidal zone, and Ecklonia stolonifera and Sargassum spp. are the dominant species of Yokjido.

• Natural Product Sciences
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• v.27 no.4
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• pp.280-283
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• 2021

Cercidiphyllum japonicum is being used for the treatment of obesity and liver fibrosis in Korean local clinics. In the present study, we tried to develop an analytical methodology for the determination of the chemical markers of Cercidiphyllum japonicum. Four chemicals, maltol (1), chlorogenic acid (2), quercetin (3), and avicularin (4), were selected for method validation, and the analytical conditions were optimized and validated using high-performance liquid chromatography coupled with an ultraviolet detector (HPLC-UV). Additionally, the seasonal variations of four markers were monitored every month for six months. The contents of four chemicals markers were most detected in a sample collected in June.

• Journal of Korean Society on Water Environment
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• v.33 no.3
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• pp.256-272
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• 2017

Extreme rainfall has become more frequent over the Korean peninsula in recent years, causing serious damages. In a changing climate, traditional approaches based on historical records of rainfall and on the stationary assumption can be inadequate and lead to overestimate (or underestimate) the design rainfalls. A main objective of this study is to develop a stochastic disaggregation method of seasonal rainfall to hourly extreme rainfall, and offer a way to derive the nonstationary IDF curves. In this study, we propose a novel approach based on a Four-Parameter Beta (4P-beta) distribution to estimate the nonstationary IDF curves conditioned on the observed (or simulated) seasonal rainfall, which becomes the time-varying upper bound of the 4P beta distribution. Moreover, this study employed a Bayesian framework that provides a better way to take into account the uncertainty in the model parameters. The proposed model showed a comparable design rainfall to that of GEV distribution under the stationary assumption. As a nonstationary rainfall frequency model, the proposed model can effectively translate the seasonal variation into the sub-daily extreme rainfall.

• Journal of Korean Society of Rural Planning
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• v.24 no.4
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• pp.99-119
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• 2018

Unit load factor, which is used for the quantification of non-point pollution in watersheds, has the limitation that it does not reflect spatial characteristics of soil, topography and temporal change due to the interannual or seasonal variability of precipitation. Therefore, we developed the method to estimate a watershed-scale non-point pollutant load using seasonal forecast data that forecast changes of precipitation up to 6 months from present time for watershed-scale water quality management. To establish a preemptive countermeasure against non-point pollution sources, it is possible to consider the unstructured management plan which is possible over several months timescale. Notably, it is possible to apply various management methods such as control of sowing and irrigation timing, control of irrigation through water management, and control of fertilizer through fertilization management. In this study, APEX-Paddy model, which can consider the farming method in field scale, was applied to evaluate the applicability of seasonal forecast data. It was confirmed that the rainfall amount during the growing season is an essential factor in the non-point pollution pollutant load. The APEX-Paddy model for quantifying non-point pollution according to various farming methods in paddy fields simulated similarly the annual variation tendency of TN and TP pollutant loads in rice paddies but showed a tendency to underestimate load quantitatively.

• The Sea:JOURNAL OF THE KOREAN SOCIETY OF OCEANOGRAPHY
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• v.17 no.2
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• pp.120-129
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• 2012

We investigated seasonal variation of sediment-water oxygen and inorganic nitrogen fluxes, and denitrification at tidal flat sediments located in the Nakdong River Estuary from July 2005 to September 2006. Net oxygen fluxes, measured with sediment incubations at in situ temperature, varied from -37.0 to $0.5mmol\;O_2\;m^{-2}\;d^{-1}$. Oxygen fluxes into the sediments from the overlying water increased due to the increased water temperature. Denitrification rate ($4{\sim}2732{\mu}mol\;N\;m^{-2}\;d^{-1}$) in this study was higher compared to the other Korean coast measured with the same method. Denitrification showed the same seasonal variation as oxygen fluxes. Denitrification rate based on $^{15}N$-nitrate showed a strong correlation with nitrate flux into the sediments from the overlying water. Denitrification via "water column supplied nitrate ($D_w$)", calculated from Isotope pairing technique, also correlated well with nitrate flux into the sediments. Nitrate from water column seems to account for seasonal variation of denitrification in Nakdong River Estuary. To understand general patterns and trends of biogeochemical processes of sediments in the Nakdong River Estuary, we categorized biogeochemical fluxes measured in this study according to direction and sizes of fluxes. Type 1(high oxygen and inorganic nitrogen fluxes into the sediments and high denitrification) occurred in summer, whereas Type 2(low oxygen and inorganic nitrogen fluxes into the sediments and low denitrification) occurred in rest of the season. Intertidal flat sediments seem to react sensitively to influence of freshwater from the Nakdong River.