• 제목/요약/키워드: sea-salt

검색결과 527건 처리시간 0.022초

PMF 모델을 이용한 미세분진의 오염원 확인과 기여도 추정 : 탄소성분을 이용한 휘발유 및 경유차량 오염원의 분리 (Identifying Ambient PM2.5 Sources and Estimating their Contributions by Using PMF : Separation of Gasoline and Diesel Automobile Sources by Analyzing ECs and OCs)

  • 이형우;이태정;김동술
    • 한국대기환경학회지
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    • 제25권1호
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    • pp.75-89
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    • 2009
  • The purpose of this study was to identify $PM_{2.5}$ sources and to estimate their contributions to the border of Yongin-Suwon area, based on the analysis of the $PM_{2.5}$ mass concentration and the associated inorganic elements, ions and carbon components. The contribution of $PM_{2.5}$ sources were estimated by using a positive matrix factorization (PMF) model to identify air emission sources. For this study, $PM_{2.5}$ samples were collected from May, 2007 to April, 2008. The inorganic elements were analyzed by an ICP-AES. The ionic components in $PM_{2.5}$ were analyzed by an Ie. The carbon components were also analyzed by DRI/OGC analyzer. After performing PMF modeling, a total of 12 sources were identified and their contributions were quantitatively estimated. The contributions from each emission source were as follows: 11.3% from oil combustion source, 3.4% from bus/highway source, 5.8% from diesel vehicle source, 4.7% from gasoline vehicle source, 8.8% from biomass burning source, 15.1 % from secondary sulfate, 5.2% from secondary nitrate source, 13.4% from industrial related source, 4.1% from Cl-rich source, 19.6% from soil related source, 1.0% from aged sea salt, and 7.4% from coal combustion source, respectively. This study provides basic information on the major sources affecting air quality, and then it will help to effectively control $PM_{2.5}$ in this study area.

Corrosion Protection Method of Reinforcing Steel in Concrete by Using Corrosion Inhibitors

  • Bae Su-Ho;Chung Young-Soo;Kim Dae-Ho
    • KCI Concrete Journal
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    • 제14권4호
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    • pp.145-150
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    • 2002
  • Reinforced concrete is inherently a durable composite material. When properly designed for the environment to be exposed and carefully constructed, reinforced concrete is capable of giving maintenance-free performance. However, unintentionally using improper materials such as non-washed sea sand having much salt together with poor controlled quality, or the concrete are placed in highly severe environment such as marine atmosphere, the corrosion of reinforcing steel in concrete becomes one of the most significant concerns of concrete. The purpose of this experimental research is to evaluate the performance of corrosion inhibitors for normal strength and high strength concrete, and to propose desirable measures for controlling corrosion of reinforcing steel in concrete. Test specimens in normal strength and high strength concrete were made with and without corrosion inhibitors. The accelerated corrosion test for reinforcing steel in concrete was adopted in accordance with JCI-SC3, which required the periodic 20 cycles for 140 days. One cycle includes 3 days for the wetting condition of $65^{\circ}C$ and $90\%$ RH, and 4 days for the drying condition of $15^{\circ}C\;and\;60\%$ RH. It was observed from the test that corrosion inhibitors in normal strength concrete and high strength concrete showed excellent corrosion resistance for reinforcing steel in concrete, but the silica fume in high strength concrete was found to have a negligible corrosion resistance if not used with corrosion inhibitors, since the chloride corrosion threshold limit in concrete containing silica fume without corrosion inhibitor was found to be considerably smaller than that of the case with corrosion inhibitor.

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제주시 강우의 화학적 조성 특성에 관하여 (Chemical Characterization of Rainwater Sampled in Cheju city)

  • 이기호;허철구
    • 한국환경과학회지
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    • 제5권6호
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    • pp.739-748
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    • 1996
  • This study was carried out to investigate the chemical characteristics ol rainwater sampled in Cheju City from July 1994 to June 1996. Concentrations of major ions (Cl-,$SO_4^{2-}$, NO_3^-$, $Na^+$, $K^+$, Ca^{2+}$, $Mg^{2+}$ and NH_4^+$) were determined. The pH of rainwater, calculated from the volume weighted H+ concentration, was found to be 5.61, indicating extensive neutralization of the acidity in the rain. The relative magnitude of average ionic concentrations followed the relation Cl-> $SO_4^{2-}$) $Na^+$> Ca^{2+}$> NH_4^+$> NO_3^-$> $Mg^{2+}$> $K^+$. The ions associated with sea salt, namely $Na^+$ and $Cl^-$, dominated the total concentration of ions in the rainwater and the $SO_4^{2-}$ ion accounts for 20% of total concentration. [H+][nss-SO42-+NO3] ratio and a multiple regression for $SO_4^{2-}$ and NO3- ions against $H^+$, $Ca^{2+}$ and $NH_4^+$ suggested that all of $SO_4^{2-}$ and $NO_3^-$ in rainwater was not necessarily associated with $H_2SO_4$ and $HNO_3$, but might also occur in combination with $NH_4^+$ or Ca^{2+}$. The monthly mean concentrations of $SO_4^{2-}$-, Ca^{2+}$ and $NH_4^+$ in spring time was higher than those in other seasons. These results may De attributed to the fertilizer application as the local sources and the yellow sand phenomina as a regional-scale sources.

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시화호와 인근 해역의 동물플랑크톤 분포로 본 시화호의 생태적 안정성 (Ecological Stability of the Shihwa Lake Evaluated by Zooplankton Distribution in the Lake Shihwa and Adjacent Coastal Area)

  • 박철;허성회
    • 한국해양학회지:바다
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    • 제2권2호
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    • pp.87-91
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    • 1997
  • 시화 방조제의 건설로 형성된 시화 인공호수의 생태적 안정성을 동물플랑크톤의 종 조성과 생물량 변동을 통해 파악하였다. 방조제 바깥쪽 해수면의 동물플랑크톤은 인근 아산만의 경우와 매우 유사한 종 조성과 계절간 변동을 보였다. 그러나, 시화호의 동물플랑크톤은 기수종으로 알려진 요각류 Sinocalanus tenellus 단 한종이 차지하는 비율이 절대적으로 높았으며(봄철 약 66%, 겨울철 약 80%, 여름과 가을에는 98% 이상 점유), 종 조성이 매우 단순하였고, 생물량에 있어서도 $10^4$ 단위까지 차이가 나는 매우 격심한 변동을 보였다. 이러한 변동은 인공호수인 시화호가 생태적으로 매우 불안정한 상태에 있음을 보이는 것이며, 그 원인은 담수 유입시의 오염 부하량의 변화나, 부정기적인 수문의 개폐와 수문 개폐시의 물의 흐름 방향의 가변성 등에 기인된 염분의 불규칙적인 변화 등이 주요 원인으로 판단되었다.

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부산지역 강우의 화학적 특성 I. pH 및 주요이온의 시ㆍ공간적 변화 (Chemical Characteristics of Precipitation in Pusan I. Temporal and spatial variation of pH and major ions)

  • 전은주;양한섭;옥곤;김영섭
    • 한국환경과학회지
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    • 제7권5호
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    • pp.707-716
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    • 1998
  • The chemical characteristics of precipitation was investigated in Pusan area. Samples were collected from January to November in 1996 at 4 sites, and analyzed pH, major soluble ionic components(C $l^{[-10]}$ , N $O_3$$^{[-10]}$ , S $O_4$$^{2-}$, N $a^{+}$, $K^{+}$, N $H_4$$^{+}$, $Mg^{2+}$, $Ca^{2+}$). The order of anion and cation concentrations for the initial precipitation were C $l^{[-10]}$ > S $O_4$$^{2-}$ > N $O_3$$^{[-10]}$ , and $Ca^{2+}$ > N $a^{+}$ > N $H_4$$^{+}$$Mg^{2+}$$K^{+}$, respectively. At coastal sites(P1 and P2) C $l^{[-10]}$ and N $a^{+}$ of maritime sources (seasalt) were high, but at inland sites(P3 and P4) nss-C $a^{2+}$ and nss-S $O_4$$^{2-}$ were high. Calcium ion for the initial precipitation showed high value of enrichement factor(EF) relative to seawater composition. The contribution of seasalt to the composition of precipitation was higher at bite P1 (53.5%) than those of the other sites. Throughout the year the concentrations of major ions for the initial precipitation were low in the heavy rain season. The mean pH for the initial precipitation was 5.4 and showed the negative relationship with the precipitaion amount. The S $O_4$$^{2-}$ and N $O_3$$^{[-10]}$ do not play an important role in rain acidification due to the high(97%) neutralizing effect of amonia and calcium species.and calcium species.

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Effects of Thermal Treatment on Antioxidant Activity in Yam (Dioscorea batatas DECNE.)

  • Kim, Han-Soo;Duan, Yishan;Ryu, Jae-Young;Kim, Sang-Woo;Jang, Seong-Ho
    • 한국응용과학기술학회지
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    • 제32권1호
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    • pp.127-135
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    • 2015
  • The aim of this study was to investigate the antioxidant activity of thermal treatment yam (Dioscorea batatas DECNE.) in Korea. Thermal treatment yam was extracted by different solvents including 70% methanol, 70% ethanol and chloroform-methanol mixture (CM, 2:1, v/v). Then color property, total phenol content and antioxidant activity were analyzed. Yam possessed high $L^*$ value and $H\limits^{\circ}$ value, which were $54.92{\pm}2.18$ and $73.20{\pm}0.77$, respectively. Thermal treatment yam exhibited great antioxidant activity evaluated by ABTS [2,2'-azino-bis(3-ethylbenzothiazoline-6-sulfonic acid) diammonium salt] radical scavenging activity, DPPH (2,2-diphenyl-1-picrylhydrazyl) radical scavenging activity, reducing power, and ferric reducing antioxidant power. Total phenol contents of various extracts from thermal treatment yam increased in the following order: 70% methanol extract ($63.53{\pm}0.33mg\;CAE/g$), 70% ethanol extract ($69.47{\pm}1.00mg\;CAE/g$) and CM extract ($97.49{\pm}0.66mg\;CAE/g$), respectively. The same trend was also could be found in antioxidant activity assays except for reducing power assay. These results implied that these extracts from thermal treatment yam might be useful to take a good part in prevention of human diseases and aging.

A Comparison between Wet-only and Bulk Deposition at Two Forest Sites in Japan

  • Imamura, Naohiro;Iwai, Noriko;Tanaka, Nobuaki;Ohte, Nobuhito
    • Asian Journal of Atmospheric Environment
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    • 제12권1호
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    • pp.67-77
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    • 2018
  • To investigate the effects of forest and the surrounding natural and anthropogenic sources on the bulk depositions on forested land, this study examined differences in ion concentrations between wet-only and bulk samples at two forested sites in Japan. The surrounding natural and anthropogenic sources at each site were different; Shirasaka is in a rural area and Tanashi is an urban environment. The volume weighted (vw) mean concentrations of $K^+$ and $Ca^{2+}$ in the bulk samples were significantly (p<0.05) higher than those in the wet-only samples at both sites. The forest canopy and a nearby incineration plant were hypothesized to be the main sources of $K^+$ contaminants at Shirasaka and Tanashi, respectively. The transport of sea salt and urban dust may explain the presence of enriched $Ca^{2+}$ concentrations in the bulk samples at Shirasaka and Tanashi, respectively. The $NH_4{^+}$ concentrations in the Shirasaka bulk samples were significantly (p<0.05) lower than those in the wet-only samples. The vw mean $SO{_4}^{2-}$ and $NO_3{^-}$ concentrations in both sample types were not significantly different at either site. This study demonstrated that the ion concentration differences between wet-only and bulk samples were affected by nearby natural and anthropogenic sources even at forest sites, similar to previous findings for non-forested locations. However, the $K^+$ concentration differences between wet-only and bulk samples may be higher owing to forest sources, even in the absence of anthropogenic sources.

생성메카니즘에 따른 부유분진 등 입자상 nitrate 농도 (Concentration of Particulate Nitrate Classified by Formation Mechanism in Seoul Ambient Air)

  • 천만영;김희강
    • 한국대기환경학회지
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    • 제11권1호
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    • pp.37-44
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    • 1995
  • Concentration of particulate nitrate classified by formation mechanism and particle diameter in ambient air was determined from Feb. to Oct. 1993. Sampling was carried out using a two-stage Andersen air sampler at the top of a five-story building located at Kon-Kuk University in seoul. Concentration of N $H_{4}$N $O_{3}$ in TSP was measured by pyrolysis of sample filters at 160.deg.C for 1hr. concentration of N $H_{4}$N $O_{3}$ was higher in winter time compared with that in summmer time. Also, concentration of N $H_{4}$N $O_{3}$ was higher in fine particles compared with that in coarse particle. The range of N $H_{4}$N $O_{3}$ concentration was between 2.9 and 9.9.mu.g/ $m^{3}$. Weight fraction of N $H_{4}$N $O_{3}$ in total particulate nitrate was 31.1 .sim. 59.5%, and weight fraction of N $H_{4}$N $O_{3}$ in TSP was 2.1 .sim. 11.2%. Concentration of NaN $O_{3}$, which originated from sea salt, was highest in spring time and lowest in summer time,and the concentration range was between 0.1 and 0.7.mu.g/ $m^{3}$. NaN $O_{3}$/TSP ratio was very low (0.1 .sim. 0.4%) indicating that the portion of NaN $O_{3}$in TSP was negligible. Concentration of particulate nitrate originated from soil was 2.4 .sim. 2.9.mu.g/ $m^{3}$. Weight fraction of that in total particulate nitrate was 14.0 .sim. 37.1%.

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Seasonal Composition Characteristics of TSP and PM2.5 Aerosols at Gosan Site of Jeju Island, Korea during 2008-2011

  • Kim, Won-Hyung;Hwang, Eun-Yeong;Ko, Hee-Jung;Kang, Chang-Hee
    • Asian Journal of Atmospheric Environment
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    • 제7권4호
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    • pp.217-226
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    • 2013
  • The collection of TSP and $PM_{2.5}$ aerosols has been made at the Gosan Site of Jeju Island during 2008-2011, and their ionic and elemental species were analyzed, in order to examine the seasonal variation and characteristics of aerosol compositions. The anthropogenic components ($NH_4{^+}$, $nss-SO_4{^{2-}}$, $NO_3{^-}$, S, Zn, Pb) and the soil components ($nss-Ca^{2+}$, Al, Fe, Ca) showed high concentrations in spring as the prevailing westerly wind, but the concentrations of the sea-salt components ($Na^+$, $Cl^-$) were high in winter. In TSP, the neutralization by $NH_3$ increased in summer, but the neutralization by $CaCO_3$ increased in spring and fall seasons. The organic acids ($HCOO^-$, $CH_3COO^-$) contributed to the acidification of the aerosols by only 5.0%, so the acidification could be mostly contributed by the inorganic acids ($SO_4{^{2-}}$, $NO_3{^-}$). From the examination of the source origins by factor analysis, the compositions of TSP were influenced by the order of soil > anthropogenic > marine, on the other hand, those of $PM_{2.5}$ were by the order of anthropogenic > marine > soil. The backward trajectory analyses showed that the concentrations of $NH_4{^+}$, $nss-SO_4{^{2-}}$, $NO_3{^-}$ and $nss-Ca^{2+}$ increased highly when the air masses had moved from China continent into Gosan area of Jeju Island.

뇌경색 후유증 환자의 고지혈증과 변비에 대한 함초환(鹹草丸) 호전 1례 (A Case Report of Hyperlipidemia and Constipation in a Patient with Cerebral Infarction Treated with Herbal Prescription.)

  • 우성호;김병철;김진원;정병주;나유진;심효주;김용호;서호석;이원희
    • 대한한방내과학회지
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    • 제27권4호
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    • pp.945-953
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    • 2006
  • Hyperlipidemia is one of the major factors causing the atherosclerosis of coronary arteries and a well-documented modifiable risk factor for stroke, especially of the ischemic type. Constipation is the condition of being unable to empty the bowels frequently enough or effectively. However, it is usually temporary and not a serious disease. Salicornia herbacea is a sea coast plant that grows on the western and southern coastal beaches and salt flats of the Korean peninsula. Belonging to Chenopodiaceae by biological classification. Salicornia herbacea is not known from research except that it contains plenty of minerals. The purpose of this study was to evaluate the effect of treatment with Hamcho-hwanand to observe changes in total cholesterol (T-Chol) high-density lipoprotein cholesterol (HDL), triglyceride (TG) and constipation. After treatment, total cholesterol decreased from 273mg/dl to 235mg/dl. Triglyceride decreased from 201mg/dl to 126mg/dl. HDL cholesterol increased from 30mg/dl to 40mg/dl. Constipation changed for the better. These results support a role for oriental medical therapy in treating hyperlipidemia and constipation. Further case studies of herbal treatment of this ailment are needed.

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