• Title/Summary/Keyword: sea-salt

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Development of Testing and Analysis Model for Evaluation of Absorbed Water Diffusion into Concrete (콘크리트 흡수 수분확산계수 산정을 위한 실험 및 수치해석 모델 개발)

  • Park, Dong-Cheon;Ahn, Jae-Cheol
    • Journal of the Korea Institute of Building Construction
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    • v.11 no.4
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    • pp.371-378
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    • 2011
  • Concrete is affected by various deterioration factors, such as $CO_2$ and chloride ions from the sea, which cause carbonation and salt attack on concrete. These deterioration phenomena cause steel corrosion in RC structures. Although a great deal of research has been carried out in this area thus far, it is difficult to know the point at which corrosion will occur to a reinforced bar. As the diffusion of deterioration factors depends on the water content in concrete, it is imperative to assess the condition of absorbed water content. A mass measuring method was applied to calculate the absorbed water diffusion coefficient, as well as non-linear finite element method(FEM) analysis. As a result, it was found that W/C and unit water content in concrete mixture affect the diffusion coefficient decision.

Chemical Composition Characteristics of Precipitation at Two Sites in Jeju Island

  • Kang, Chang-Hee;Kim, Won-Hyung;Lee, Won
    • Bulletin of the Korean Chemical Society
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    • v.24 no.3
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    • pp.363-368
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    • 2003
  • The major ionic components of precipitation collected at the 1100 Site of Mt. Halla and Jeju city have been determined. The reliability of the analytical data was verified by the comparison of ion balances, electric conductivities and acid fractions; all of their correlation coefficients were above 0.94. Ionic strengths lower than $10^{-4}$ M were found in 53% of the 1100 Site samples and 28% of the Jeju city samples. Compared with other inland areas, the wet deposition of $Na^+,\;Cl^-\;and\;Mg^{2+}$ was relatively larger, but that of $NH_4^+,\;nss-SO_4^{2-}$(non-sea salt sulfate) and $NO_3^-$ was lower. Especially the wet deposition increase of $Ca^{2+}$ in the spring season supports the possibility of the Asian Dust effect. The acidification of precipitation was caused mostly by $SO_4^{2-}\;and\;NO_3^-$ in the Jeju area, and the organic acids have contributed only about 7% to the acidity. The neutralization factors by NH₃were 0.47 and 0.48, and that of CaCO₃was 0.31 and 0.25 at the 1100 Site and Jeju city, respectively. Investigation into major influencing sources on precipitation components by factor analysis showed that the precipitation at the 1100 Site had been influenced mostly by an anthropogenic source, followed by soil and seawater sources. The precipitation at Jeju city was mainly influenced by oceanic sources, followed by anthropogenic and soil sources.

Pollution Characteristics of PM2.5 Fine Particles Collected at Gosan Site in JeJu Island during 1997~2001 (1997~2001년 제주도 고산지역 PM2.5 미세분진의 오염 특성)

  • 강창희;김원형;한진석;선우영;문길주
    • Journal of Korean Society for Atmospheric Environment
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    • v.19 no.3
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    • pp.263-273
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    • 2003
  • P $M_{2.5}$ fine particles have been collected at the Cosan measurement station in Jeju Island, and the major water-soluble components have been analyzed in order to Investigate the aerosol compositions and pollution characteristics. The mean concentrations of the components were in the order of S $O_4$$^{2-}$> N $H_4$$^{+}$> N $O_3$$^{[-10]}$ > N $a^{+}$> $K^{+}$>C $l^{[-10]}$ >C $a^2$$^{+}$>M $g^2$$^{+}$. The major components were S $O_4$$^{2-}$, N $H_4$$^{+}$ and N $O_3$$^{[-10]}$ , whose compositions were 58%, 18% and 10% of the total ions, respectively. Most of the components showed higher concentrations in spring season, and especially $Ca^2$$^{+}$, N $O_3$$^{[-10]}$ and S $O_4$$^{2-}$ concentrations were increased 2.8, 1.9 and 1.2 times higher than the annual mean concentrations. The most parts of S $O_4$$^{2-}$ and N $H_4$$^{+}$ were distributed in fine particles below 2.1 ${\mu}{\textrm}{m}$ size, but the $Ca^2$$^{+}$, N $a^{+}$ and C $l^{[-10]}$ showed relatively higher concentrations in coarse particles. Based on the factor analysis, the P $M_{2.5}$ fine particles were considered to be largely influenced by anthropogenic sources, and followed by sea salt and soil sources. In the variations of concentrations as a function of wind direction, most components have shown higher concentrations notably as the northwesterly prevails.thwesterly prevails.

Monitoring of the Fugitive and Suspended Dust Dispersion at the Reclaimed Land and Neighboring Farms: Monitoring in Gim-je (간척지 인근 농경지에서의 비산 및 부유먼지 확산 모니터링(II): 김제 모니터링)

  • Hwang, Hyun-Seob;Lee, In-Bok;Shin, Myeong-Ho;Hong, Se-Woon;Seo, Il-Hwan;Yoo, Jae-In;Bitog, Jessie.P.;Kwon, Kyeong-Seok;Kim, Yong-Hee
    • Journal of The Korean Society of Agricultural Engineers
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    • v.51 no.2
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    • pp.59-67
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    • 2009
  • A study on fugitive dusts was conducted at Saemangeum reclaimed land located in Gim-je area. The monitoring result on the fugitive and suspended dust was significantly affected by the farming activities (harvesting and land cultivation) and vehicles passing nearby the measuring points. The concentration of the fugitive dust generated from the reclaimed land was reduced remarkably by the effect of halophyte present on the ground and the tide embankment. Comparing the data collected in 2006 and 2007, the concentrations of TSP and PM10 decreased by 47.4% and 29.5%, respectively. After harvesting operations at paddy field, TSP increased by 22% while PM10 increased by 54%. The concentration of a Cl- which is a representative ion of sea-salt decreased to about 35% in 2007 compared with 2006. This represents that the inside area change and plant covering rate affected on the decrease of fugitive dust. The correlation analysis for the compounds of topsoil at each measuring point shows that near the coastline is more comparable. The canopy of halophyte in the source area also increased which reduced the fugitive dust remarkably. The dust distribution measured by dust spectrometer at the same point shows that most particles are $0.5{\mu}m$ to 2um size but not greater than $5{\mu}m$.

Optimal Condition for Eicosapentaenoic Acid Production and Purification from Psychrophillic Marine Baterium Shewanella sp. L93 (호냉성 해양세균 Shewanella sp. L93로부터 Eicosapentaenoic Acid 생산 및 정제를 위한 최적화 조건)

  • Mo, Sang-Joon;Hong, Hye-Won;Bang, Ji-Heon;Cho, Ki-Woong
    • Microbiology and Biotechnology Letters
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    • v.39 no.3
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    • pp.218-223
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    • 2011
  • To obtain eicosapentaenoic acid (EPA)-producing bacteria, some 600 strains of bacteria were isolated from Antarctic sediment and marine organisms during the summer expedition of 1999-2000 and 7 EPA-producing bacteria were obtained through screening with TLC and GC. A strain designated as L93 showed the highest EPA production, which was gram-negative, rod-shaped bacterium. L93 strain was identified as Shewanella sp., from the sequence analysis of 16S rDNA. Optimal conditions temperature and pH for the growth and EPA production were about $4^{\circ}C$ and pH 7. In addition, its production was optimized by 50%(w/v) sea salt. We establish the optimal production system to produce about 320 mg per liter by using this optimal EPA production conditions. EPA-methyl ester was purified from cultured L93 strain to a purity of higher than 97% and typical purification yield is greater than 72% of the input amount via urea complexation and HPLC.

PspAG97A: A Halophilic α-Glucoside Hydrolase with Wide Substrate Specificity from Glycoside Hydrolase Family 97

  • Li, Wei;Fan, Han;He, Chao;Zhang, Xuecheng;Wang, Xiaotang;Yuan, Jing;Fang, Zemin;Fang, Wei;Xiao, Yazhong
    • Journal of Microbiology and Biotechnology
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    • v.26 no.11
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    • pp.1933-1942
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    • 2016
  • A novel ${\alpha}-glucoside$ hydrolase (named PspAG97A) from glycoside hydrolase family 97 (GH97) was cloned from the deep-sea bacterium Pseudoalteromonas sp. K8, which was screened from the sediment of Kongsfjorden. Sequence analysis showed that PspAG97A belonged to GH97, and shared 41% sequence identity with the characterized ${\alpha}-glucoside$ BtGH97a. PspAG97A possessed three key catalytically related glutamate residues. Mutation of the glutamate residues indicated that PspAG97A belonged to the inverting subfamily of GH97. PspAG97A showed significant reversibility against changes in salt concentration. It exhibited halophilic ability and improved thermostability in NaCl solution, with maximal activity at 1.0 M NaCl/KCl, and retained more than 80% activity at NaCl concentrations ranging from 0.8 to 2.0 M for over 50 h. Furthermore, PspAG97A hydrolyzed not only ${\alpha}-1,4-glucosidic$ linkage, but also ${\alpha}-1,6-$ and ${\alpha}-1,2-glucosidic$ linkages. Interestingly, PspAG97A possessed high catalytic efficiency for long-chain substrates with ${\alpha}-1,6-linkage$. These characteristics are clearly different from other known ${\alpha}-glucoside$ hydrolases in GH97, implying that PspAG97A is a unique ${\alpha}-glucoside$ hydrolase of GH97.

Skin Brightening Effect of Gel Essence Containing High Concentrated-Marine Minerals in Silicon Copolyol Network Film in vivo (고농도의 미네랄을 실리콘 네트워크 필름에 포집한 젤 에센스 제형의 피부 밝기 개선 효과)

  • Kim, Sun-Kyong;Kim, Young-So;Joo, Kyung-Mi;Kim, Eun-Joo;Lee, Ji-Eun;Chae, Byung-Gun;Cho, Jun-Cheol;Han, Sang-Hoon
    • Journal of the Society of Cosmetic Scientists of Korea
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    • v.37 no.3
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    • pp.283-288
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    • 2011
  • Since minerals are in ionic forms in aqueous phase (like deep sea water), it is very hard to incorporate concentrated minerals in gel like cosmetic formulations which are generally composed of carbomer or acrylates polymer. In this study, we invented a salt-resistant network formulation made of silicon copolyol. It was found that the network formulation traps minerals (especially from marine) in a mesh-like silicone copolyol structure. Since the mineral-containing formulation makes a very thin film on the skin, minerals could be easily absorbed into stratum corneum. In 6 weeks in vivo test, it was found that the novel mineral formulation increased the amounts of amino acids, major components of natural moisturizing factors (NMFs), as well as levels of minerals. It was also found that the moisture contents and the brightness of the skin increased.

Estimation of low impact development duration of estuaries at urban area (도시 유역에 위치한 하구를 구성하는 하천의 저영향 개발 기간 산정)

  • Jeong, Anchul;Lim, Jeongcheol;Kim, Songhyun;Baek, Chungyeol
    • Journal of Wetlands Research
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    • v.21 no.4
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    • pp.290-297
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    • 2019
  • The estuary is a transition zone where fresh water and salt water meet because the stream is connected to the open sea area. So estuaries have very high biodiversity and form a unique ecosystem. However, before the recognition of the ecological value of the estuaries, various damage and disturbances have been occurred so countermeasures are needed. The river master plan is acting as a disturbance factor. However, the river master plan has the public object such as water disaster defense, river function improvement, and national water resources management. Therefore, it is necessary to study the ways in which the opposite relationship of development and ecosystem protection coexist. In this study, the concept of environmental windows were used to estimate the low impact development duration. We expected that proposed method for low impact development duration estimation can be used as a basis and basic data to protected the ecosystem from development project and disturbance in the future.

A Compound Deterioration Assessment of Concrete Subjected In Freezing-Thawing and Chloride Attack (동결융해와 염해의 복합작용을 받는 콘크리트의 내구성능 저하 평가)

  • 고경택;김도겸;김성욱;조명석;송영철
    • Journal of the Korea Concrete Institute
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    • v.13 no.4
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    • pp.397-405
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    • 2001
  • In clod weather regions, a strong seasonal wind brings sea salts to the land. In addition to it, recently, the spreading amount of deicing salts has increased numerously for purpose of removing snow and ice. Thus the salts environment around concrete structures becomes so severe that various damages of concrete due to applied salts will be brought up. Much of countries such as America, Europe etc. is carried out study for effects of deicing salts on concrete. However, there are not test methods for deterioration of concrete subjected to both freezing-thawing and chloride in Korea. In this study, we carried out test for the compound deterioration subjected to both freezing-thawing and chloride attack, to investigate the effects of sodium chloride on the deterioration of concrete. The test was performed to investigate the effects of cement type, strength and air content on the scaling deterioration of concrete. As a result, the scaling deterioration was accelerated in the presence of salts. And the resistance to scaling was strongly influenced by the type of cement, the strength and air content of concrete.

The Effect of Seawater on Hydration of Clinker Minerals (I) Effects of SO42- and Cl- ions (시멘트 클린커 광물의 수화에 미치는 해수성분의 영향 (I)SO42- 및 Cl-이온에 의한 영향)

  • 신도철;송태웅;한기성;최상흘
    • Journal of the Korean Ceramic Society
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    • v.24 no.1
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    • pp.77-85
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    • 1987
  • Hardened cement paste is mainly affected by corrosion of sulphate and chlorine ions in sea water. In this investigation, many specimens were made with the cement clinker minerals such as C3S, C3A, C4AF and their mixture according to cement composition added various blending materials. After the specimens were immersed in 4% MgSO4 and MgCl2 solutions, the product of reaction, the microstructure of specimen and Ca+2 ion leached in the solution were studied. The formation of Ca(OH)2 in the specimen of C3S is reduced relatively by adding pozzolanic admixtures. The chlorine ion is easily diffuse into the C3S specimen and produced CaCl2 compound, and it makes the specimen porous by leaching out itself into the solution. The specimen of C3A, C4AF are broken down by expanding reaction of ettringite and gypsum compound produced in the MgSO4 solution. At a later period, the ettringite is transformed into gypsum and 5MgO.2Al2O3·15H2O. The C3A in the MgCl2 solution combines chlorine ion to form Friedel's salt and prevents the diffusion reaction of chlorine ion into the specimen. Granulated slag shows inferior effect on the resistance of the specimen in MgSO4 solution by forming ettringite and gypsum, but good result in MgCl2 solution. Pozzolanic materials, on the whole, offer noticable effect on the resistance of the specimen in both solutions.

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