• Title/Summary/Keyword: sc-Si

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Major, Trace and Rare Earth Element Geochemistry, and Oxygen-Isotope Systematics of Illite/smectite in the Reindeer D-27 Well, Beaufort-Mackenzie Basin, Arctic Canada (카나다 보포트-맥켄지 분지의 일라이트/스멕타이트의 원소 지화학 및 산소동위원소 연구)

  • Ko, J.;Hesse, R.;Longstaffe, F.J.
    • Economic and Environmental Geology
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    • v.28 no.4
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    • pp.351-367
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    • 1995
  • The elemental geochemistry and oxygen isotopes of illite/smectite (I/S) have been studied in relationship to the mineralogical trend in the Reindeer D-27 well, Beaufort-Mackenzie Basin. The increase in concentrations of $K_2O$, Rb and rare earth elements (REE), the decrease in concentrations of tetrahedral elements such as Mg, Ti, Sc, Zn and Zr, and the increase in concentrations of tetrahedral elements such as Be and V can be related to I/S compositions that vary systematically with depth. Layer formulae of S- and I-layers are estimated as $[Al_{1.57}Fe_{.19}Mg_{.31}Ti_{.07}][Si_{3.84}Al_{.16}]O_{10}(OH)_2$ and $[Al_{1.84}Mg_{.16}][Si_{3.33}Al_{.67}]O_{10}(OH)_2$, respectively. The mobilization of REE appears to occur during illitization. The increase in concentrations of REE, especially La and Ce, with depth is probably linked to incorporation of ions with high valency (e.g. $V^{5+}$) in tetrahedral sites. The excess valency due to V is partly counter-balanced by ions with low valency (e.g. $Be^{2+}$) and, in turn, the local valency deficiency caused by $Be^{2+}$ could be compensated by high-charge interlayer cations such as REE (+3). ${\delta}^{18}O$ values of I/S range from 2.91 to 15.72‰ (SMOW), and increase with depth, contrasting to trends observed in the Gulf Coast and elsewhere. The increase in ${\delta}^{18}O$ of I/S results from the rapid increase in ${\delta}^{18}O$ of pore water that overcomes the decrease in temperature-dependent fractionation values with increasing burial depth (${\delta}^{18}O_{pore\;water}>-d{\Delta}/_{I/S-water};\;d{\delta}^{18}O_{I/S}>0$). Calculated ${\delta}^{18}O$ values of pore water in equilibrium with I/S suggest that the original water was probably meteoric water. The stratification of pore water is postulated from the presence of an isotopically light interval, about 450m thick. The depth range of the isotopically light zone overlaps, but does not coincide with the interval of lowered I-content and $K_2O$ concentrations, suggesting that oxygens may have been exchanged independently of mineralogical and geochemical reactions.

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Geochemical Study on Geological Groups of Stream Sediments in the Gwangju Area (광주지역 하상퇴적물에 대한 지질집단별 지구화학적 연구)

  • Kim, Jong-Kyun;Park, Yeung-Seog
    • Economic and Environmental Geology
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    • v.38 no.4 s.173
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    • pp.481-492
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    • 2005
  • The purpose of this study is to determine geochemical characteristics for stream sediments in the Gwangju area. We collect the stream sediments samples by wet sieving along the primary channels and dry these samples slowly in the laboratory and grind to under 200mesh using an alumina mortar fur chemical analysis. Major elements, trace and rare earth elements are determined by XRF, ICP-AES and NAA analysis methods. For geochemical characteristics on geological groups of stream sediments, we separate geologic groups which are derived from Precambrian granite gneiss area, Jurassic granite area and Cretaceous Hwasun andesite area. Contents range of major elements for stream sediments in the Gwangju area are $SiO_2\;51.89\~70.63\;wt.\%,\;Al_2O-3\;12.91\~21.95\;wt.\%,\;Fe_2O_3\;3.22\~9.89\;wt.\%,\;K_2O\;1.85\~4.49\;wt.\%,\;MgO\;0.68\~2.90\;wt.\%,\;Na_2O\;0.48\~2.34\;wt.\%,\;CaO\;0.42\~6.72\;wt.\%,\;TiO_2\;0.53\~l.32\;wt.\%,\;P_2O_5\;0.06\~0.51\;wt.\%\;and\;MnO\;0.05\~0.69\;wt.\%.$ According to the AMF diagram for stream sediments and rocks, the stream sediments are plotted on boundary of tholeiitic series and calk alkaline series, which shows that contents of $Fe_2O_3$ are higher in stream sediments than rocks. According to variation diagram of $SiO_2$ versus $(K_2O+Na_2O),$ stream sediments are plotted on subalkaline series. Contents range of trace and rare earth elements for stream sediments in the Gwangiu area are Ba$590\~2170$ppm, Be1\~2.4$ppm, Cu$13\~79$ppm, Nb$20\~34$ppm, Ni$10\~50$ppm, Pb$17\~30$ppm, Sr$70\~1025$ ppm, V$42\~135$ppm, Zr$45\~171$ppm, Li$19\~77$ppm, Co$4.3\~19.3$ppm, Cr$28\~131$ppm, Cs$3.1\~17.6$ppm, Hf$5\~27.6$ppm, Rb$388\~202$ppm, Sb$0.2\~l.2$ ppm, Sc$6.4\~17$ppm, Zn$47\~389$ppm, Pa$8.8\~68.8$ppm, Ce$62\~272$ppm, Eu$1\~2.7$ppm and Yb$0.9\~6$ppm.

High-k ZrO2 Enhanced Localized Surface Plasmon Resonance for Application to Thin Film Silicon Solar Cells

  • Li, Hua-Min;Zang, Gang;Yang, Cheng;Lim, Yeong-Dae;Shen, Tian-Zi;Yoo, Won-Jong;Park, Young-Jun;Lim, Jong-Min
    • Proceedings of the Korean Vacuum Society Conference
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    • 2010.02a
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    • pp.276-276
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    • 2010
  • Localized surface plasmon resonance (LSPR) has been explored recently as a promising approach to increase energy conversion efficiency in photovoltaic devices, particularly for thin film hydrogenated amorphous silicon (a-Si:H) solar cells. The LSPR is frequently excited via an electromagnetic (EM) radiation in proximate metallic nanostructures and its primary con sequences are selective photon extinction and local EM enhancement which gives rise to improved photogeneration of electron-hole (e-h) pairs, and consequently increases photocurrent. In this work, high-dielectric-constant (k) $ZrO_2$ (refractive index n=2.22, dielectric constant $\varepsilon=4.93$ at the wavelength of 550 nm) is proposed as spacing layer to enhance the LSPR for application to the thin film silicon solar cells. Compared to excitation of the LSPR using $SiO_2$ (n=1.46, $\varepsilon=2.13$ at the wavelength of 546.1 nm) spacing layer with Au nanoparticles of the radius of 45nm, that using $ZrO_2$ dielectric shows the advantages of(i) ~2.5 times greater polarizability, (ii) ~3.5 times larger scattering cross-section and ~1.5 times larger absorption cross-section, (iii) 4.5% higher transmission coefficient of the same thickness and (iv) 7.8% greater transmitted electric filed intensity at the same depth. All those results are calculated by Mie theory and Fresnel equations, and simulated by finite-difference time-domain (FDTD) calculations with proper boundary conditions. Red-shifting of the LSPR wavelength using high-k $ZrO_2$ dielectric is also observed according to location of the peak and this is consistent with the other's report. Finally, our experimental results show that variation of short-circuit current density ($J_{sc}$) of the LSPR enhanced a-Si:H solar cell by using the $ZrO_2$ spacing layer is 45.4% higher than that using the $SiO_2$ spacing layer, supporting our calculation and theory.

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Trace Elements Characterization of PM10 in Seoul Area (서울지역의 PM10 중 미량원소의 특성 평가)

  • 신은상;최민규;영선우;정용삼
    • Journal of Korean Society for Atmospheric Environment
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    • v.18 no.5
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    • pp.363-372
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    • 2002
  • PM$_{10}$ aerosols were collected using low volume air sampler every month intervals from September 1992 to August 1991 in Seoul. These samples were analyzed for 20 trace elements (Al, As, Ba, Br, Ca, Cl, Co, Cr, Fe, K, Mn, Na, Ni, Pb, Sc, Se, Si, Ti, V and Zn) by INAA (instrumental neutron activation analysis), XRF (x-ray fuorescence spectrometer), and ICP (inductively coupled plasma). PM$_{10}$ mass concentrations higher than 70 $\mu$g/m$^3$ were 32% of 60 samples and had significantly higher concentrations in spring and winter than in summer and fall (p-value<0.001). The elements of As, Br, Cl, Ni, Pb, Se, V, and Zn are enriched by factors of 20 to 2,000 relative to their natural abundance in crustal soil. To further identify common sources of pollution-related trace elements, factor analysis was applied to the trace elements concentration data. Major sources that contribute to the atmospheric loading of these elements were found to include fossil fuel combustion, automobile and waste incineration (33.2%), metal processing industry (18.2%), and soil(29.8%).8%).

The 2D/3D Time-of-Flight, Phase Contrast and Contrast Enhanced Magnetic Resonance Angiograph (2D/3D Time-of-Flight, Phase Contrast 그리고 Contrast Enhanced 자기 공명 혈관조영기법에 관한 연구)

  • Yi, Yun;Choi, Jung-Hwan;Park, Seung-Hun;Kim, Si-Seung;Chung, Sung-Taek
    • Journal of the Institute of Electronics Engineers of Korea SC
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    • v.40 no.4
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    • pp.291-298
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    • 2003
  • It is important to visualize a lesion accurately in diagnosis of disease. Many diseases result in a change of lesion. Magnetic resonance angiography can visualize the morphological characteristics of blood vessel. The magnetic resonance angiography (MRA) can be categorized to time-of-flight, phase contrast, and contrast enhanced MRA. In this paper, we introduce a principle, sequence, and feature of angiography For better image quality we describe data processing methods and show several applications to human bodies

A Study on Behavior of Cell Fabricated by Sputtering for Phase Change Memory (스퍼터링을 통해 제작된 상변화 메모리용 셀의 I-V 거동 연구)

  • Baek, Seung-Cheol;Song, Ki-Ho;Lee, Hyun-Yong
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2010.06a
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    • pp.55-55
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    • 2010
  • 상변화 메모리용 셀은 전류 구동형으로써 셀에 전류를 인가하였을 때 저항이 높은 상태(비정질상)과 저항이 낮은 상태(결정질상)의 두가지 특성을 갖는다. 저항이 높은 상태에서 전류나 전압을 인가하면 높은 저항을 보이다가 일정 값(threshold voltage) 이상에서 낮은 저항을 갖는 현상을 보인다. 이때 상변화물질의 종류 혹은 셀의 사이즈에 따라 threshold voltage의 차이가 나타나는데 이 값을 줄임으로서 상변화 메모리의 구동 전류의 감소에 기여할 수 있다. 본 연구에서는 스퍼터링 방법을 이용해 박막형식의 셀을 제작하여 전기적 특성을 관찰하였다. 셀은 Si 기판 위에 radio frequency power supply 와 direct current power supply를 사용해 하부전극과 상변화층, 그리고 상부전극의 순으로 증착하여 제작하였다. 상변화층은 $Ge_2Sb_2Te_5$를 사용하였고 제작된 셀은 scanning electon microscope(SEM)를 이용하여 표면의 상태를 확인하였고 Keithley 4200scs를 이용하여 인가된 전류 혹은 전압에 따른 특성변화를 측정하였다.

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Studies of MMPI on the Somatic Disorder of CVA Patients (뇌졸중 입원 환자의 신체장애 부위별 MMPI 조사연구)

  • Yang, Hee-Suk;Jang, Hyun-Ho;Ahn, Dae-Joong;Kang, Hyung-Won;Lyu, Yeoung-Su;Min, Sang-Jun
    • Journal of Oriental Neuropsychiatry
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    • v.13 no.2
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    • pp.75-92
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    • 2002
  • To evaluate the relations between strokes and psychological characteristics, the authors surveyed Minnesota Multiphasic Personal Inventory(MMPI) in CVA Patients. The results are as follows.1. In the cerebral infarction patients group, the measure of F, Hy, Pd, Pt and Sc has appeared significantly high. 2. In the cerebral hemorrhage patients group, the measure of F and Ma has appeared significantly high. 3. In dysphasia-hemiparesis patients group, the measure of D has appeared high.4. In the Soyangin patients group, the measure of Pd and Ma has appeared high. 5. In the Soeumin patients group, the measure of D, Pt and Si has appeared high.

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Effective electromechanical coupling coefficient of adaptive structures with integrated multi-functional piezoelectric structural fiber composites

  • Koutsawa, Yao;Tiem, Sonnou;Giunta, Gaetano;Belouettar, Salim
    • Smart Structures and Systems
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    • v.13 no.4
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    • pp.501-515
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    • 2014
  • This paper presents a linear computational homogenization framework to evaluate the effective (or generalized) electromechanical coupling coefficient (EMCC) of adaptive structures with piezoelectric structural fiber (PSF) composite elements. The PSF consists of a silicon carbide (SiC) or carbon core fiber as reinforcement to a fragile piezo-ceramic shell. For the micro-scale analysis, a micromechanics model based on the variational asymptotic method for unit cell homogenization (VAMUCH) is used to evaluate the overall electromechanical properties of the PSF composites. At the macro-scale, a finite element (FE) analysis with the commercial FE code ABAQUS is performed to evaluate the effective EMCC for structures with the PSF composite patches. The EMCC is postprocessed from free-vibrations analysis under short-circuit (SC) and open-circuit (OC) electrodes of the patches. This linear two-scale computational framework may be useful for the optimal design of active structure multi-functional composites which can be used for multi-functional applications such as structural health monitoring, power harvest, vibration sensing and control, damping, and shape control through anisotropic actuation.

MMPI Characteristics of the Victim of the Sexual Violence (성폭력 피해자에서 MMPI 특성)

  • Kim, Jeong Hyeon;Do, Jin A;Choi, In Chul;Lim, Myung Ho
    • Anxiety and mood
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    • v.11 no.1
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    • pp.12-18
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    • 2015
  • Objective : The current study investigated the personality characteristics in the victims of sexual violence, by using the Minnesota Multiphasic Personality Inventory (MMPI) test which are commonly used in clinical medicine. Methods : A total of 40 victims of sexual violence (only female) completed the Korean version of the MMPI. 31 (77.5%), and theywere patients with posttraumatic stress disorder. These victims of sexual violence had been admitted to the Dankook University Hospital in Cheonan. Results : The MMPI scores of the sexual victims were significantly higher on Hs, D, Hy, Pd, Pa, Pt, Sc, and Si, than the comparison group by ANCOVA. Conclusion : The victims of sexual violence may have developed the following characteristics: hypochondriasis, depression, hysteria, psychopathic deviate, paranoia, psychasthenia, schizoid and social introversion. The finding suggests psychotic psychopathology rather than neurotic psychopathology. These results suggested that the psychopatholgy in the victims of sexual violence may be different, compared to the control group.

The Effect of Acid Treatment on the Removal of Metal Ions and the Brightness of Pulp (산처리가 펄프의 금속 이온 제거 및 백색도에 미치는 영향)

  • Lee, Sung-Gyu;Paik, Ki-Hyon
    • Journal of Korea Technical Association of The Pulp and Paper Industry
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    • v.40 no.4
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    • pp.51-58
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    • 2008
  • This paper presents the effect of acid treatment on the removal of metals and the brightness of pulp. The bleached kraft pulps, metal-absorbed pulps and recycled pulps((ONP, OCC, MOW, and SC) were treated with the acidic solutions. Among metals in the bleached kraft pulps, Cu, Ca and Mg were removed easily by the acid washing, whereas Fe, Al and Si were not removed. The acid washing also removed distinctly metals from the metal-absorbed pulps. The metals absorbed in pulps reduced the brightness (%, ISO). Especially, Fe was the most detrimental metal. However, the brightness which was decreased by metals was restored to the status quo by the acid washing. The level of metals in recycled pulps was gradually reduced after the first flotation and acid treatment. Hence, the degree of metal removal by the acid washing was mainly dependent upon the kinds of waste pulps and metal ions.