• Title/Summary/Keyword: sand compounds

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Effects of Asian Dust (KOSA) Deposition Event on Bacterial and Microalgal Communities in the Pacific Ocean

  • Maki, Teruya;Ishikawa, Akira;Kobayashi, Fumihisa;Kakikawa, Makiko;Aoki, Kazuma;Mastunaga, Tomoki;Hasegawa, Hiroshi;Iwasaka, Yasunobu
    • Asian Journal of Atmospheric Environment
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    • v.5 no.3
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    • pp.157-163
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    • 2011
  • Atmospheric aerosol deposition caused by Asian dust (KOSA) events provide nutrients, trace metals, and organic compounds over the Pacific Ocean that enhance ocean productivity and carbon sequestration and, thus, influence the atmospheric carbon dioxide concentrations and climate. Using dust particles obtained from the snow layers on Mt. Tateyama and the surface sand of Loess Plateau in incubation experiments with natural seawater samples on a shipboard, we demonstrate that dust-particle additions enhanced the bacterial growth on the first day of incubation. Gram-positive bacterial group and alpha-proteobacteria were specifically detected form seawater samples including the mineral particles. Although the remarkable dynamics of trace elements and nutrients depend on dust-particle additions, it is possible that organic compounds present in the mineral particles or transported microbial cells could also contribute to an increase in the quantities of bacteria. The chlorophyll concentrations at fractions of every size indicated a similar pattern of change between the seawater samples with and without the dust-particle additions. In contrast, the chlorophyll measurement using submersible fluorometer revealed that the dynamics of phytoplankton composition were influenced by the dust-particles treatments. We conclude that the phytoplankton that uses the bacterial products would increase their biomass. We show that KOSA deposition can potentially alter the structures of bacterial communities and indirectly influence the patterns of marine primary production in the Pacific Ocean.

Masking Effect of Chlorine on Algae-related Taste and Odor in Drinking Water Supplies (염소의 상수원 내 조류 이취미 Masking 효과)

  • Kim, Young-il;Lee, Yu-Jeong;Shin, Heung-Sup;Bae, Byung-Uk
    • Journal of Korean Society of Water and Wastewater
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    • v.22 no.2
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    • pp.227-232
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    • 2008
  • The masking effect of chlorine on algae-related taste and odor(T&O) compounds has long been an important issue for water suppliers. In this study, masking experiments with chlorine were performed on two kinds of treated water and one of raw water. After adding chlorine(0 to 0.8 mg/L) to water samples, odor intensity was evaluated by a newly developed sensory method(2-out-of-5 odor test) for three days along with the measurement of residual chlorine concentration. Even though the relationship between the residual chlorine concentration and odor reported by the sensory analysts was not always coincident, it was proved that residual chlorine more than a certain concentration could completely mask both added geosmin and naturally occurring T&O compounds. For the sand-filtered water spiked with 10 ng/L of geosmin, 0.12-0.18 mg/L of residual chlorine was necessary to achieve complete masking. In the case of GAC-filtered water, 10 ng/L of spiked geosmin was completely masked by 0.15-0.1 mg/L of residual chlorine. Combined ozone and GAC was not enough to treat raw water spiked with 300 ng/L of geosmin. In this experiment, sensory analysts were able to detect earthy or musty odors from the treated water. From a masking experiment with raw water taken from the Daechung Reservoir, it was found that fishy odor was more difficult to mask with chlorine than earthy odor. As the chlorine residual declined, the analysts began to notice the original odor and the fishy odor was noticed earlier than the earthy odor.

The Reclamation of Secondary Effluent to Industrial Water by Co-60 γ Irradiation (Co-60 γ선을 이용한 하수처리수의 공업용수로의 재이용)

  • Lee, Myun-Joo;Jeoung, Young-Do;Nho, Young-Chang;Shon, Jong-Sik
    • Applied Chemistry for Engineering
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    • v.10 no.6
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    • pp.838-842
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    • 1999
  • In order to reclaim the effluent discharged from sewage treatment facilities application of an irradiation technique was investigated in this study for industrial water reuse. Samples were filtered using a sand filter to remove particles. Co-60 was used as an irradiation source and the irradiation dose was varied from 0.1 kGy to 15 kGy. The major source of colour in secondary treatment effluent was humic substances, which could be easily removed by irradiation with a dose 5 kGy. Bacteria could be also disinfected even at low doses. It was possible to get high quality water for industrial water reuse. But the effluent still contained a small amount of organic compounds. Further treatment, of residual organic compounds will be necessry if the higher quality water is required.

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chemopreventive Effects of 2-(Allylthio) pyrazine

  • Kim, Nak-Doo;Kim, Sang-Geon
    • Archives of Pharmacal Research
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    • v.22 no.2
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    • pp.99-107
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    • 1999
  • A series of organosulfur compounds were synthesized with the aim of developing chemopreventive compounds active against hepatotoxicity and chemical carcinogesis. 2-(Allylthio) prazine (2-AP) was effective in inhibiting cytochrome P450 2E1-mediated catalytic activities and protein expression, and in inducing microsomal epoxide hydrolase and major glutathione S-transferases. 2-AP reduced the hepatotoxicity caused by toxicant sand elevated cellular GSH content. Development of skin tumors, pulmonary adenoma and aberrant crypt foci in colon by various chemical carcinogens was inhibited by 2-AP pretreatment. Anticarcinogenic effects of 2-AP at the stage of initiation of tumors were also observed in the aflatoxin B1 ($AFB_1$)-induced three-step medium-term hepatocarcinogenesis model. Reduction of $AFB_1$-DNA adduct by 2-AP appeared to result from the decreased formation of $AFB_1$-8,9-epoxide via suppression of cytochrome P450, while induction of GST 2-AP increases the excretion of glutathione-conjugated $AFB_1$ . 2-AP was a radioprotective agent effective against the lethal dose of total body irradiation and reduced radiation-induced injury in association with the elevation of detoxifying gene expression. 2-AP produces reactive oxygen species in vivo, which is not mediated with the thiol-dependent production of oxidants and that NF-KB activation is not involved in the induction of the detoxifying enzymes. the mechanism of chemoprotection by 2-AP may involve inhibition of the P450-mediated metabolic activation of chemical carcinogens and enhancement of electrophilic detoxification through induction of phase II detoxification enzymes which would facilitate the clearance of activated metabolites through conjugation reaction.

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Scientific Analysis of Slags and Furnace Wall collected from Iron Production Site at Suryong-ri Wonmorongi in Chungju (충주 수룡리 원모롱이 야철지 수습 철재 및 노벽의 과학적 분석)

  • Cho, Hyun-Kyung;Cho, Nam-Chul;Kang, Dai Ill
    • Journal of Conservation Science
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    • v.29 no.2
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    • pp.139-147
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    • 2013
  • This study focused on iron making related information through analyzing slags and furnace wall collected from iron production site of Suryong-ri Wonmorongi, Chungju. Total Fe content of slags were from 36.98% to 44.47% and this range was general recovery rate of iron in ancient. Compounds of calcium included slags was supposed to add intentionally during smelting process as deoxidation agent in order that these helped to separate iron from impurities. Furnace wall didn't make of high alumina clay because of low $Al_2O_3$. Microstructure and main components of slags show that No. 1 to 3 slags with fayalite and wustite were products of iron ore smelting. However, No.4 slag is more likely to smelt by iron sand because of ulvospinel with $TiO_2$ in No. 4 slag. Therefore, iron ore were not only used but iron sand in smelting and furnace wall made of general clay with low $Al_2O_3$ content in this area.

Removal of Heavy Metal and Phenol from Aqueous Solution Using Fe(III) loaded Adsorbent (3가철 함유 흡착제를 이용한 수용액상의 중금속 및 페놀제거연구)

  • Kim, Seok-Jun;Kim, Won-Gee;Lee, Seung-Mok;Yang, Jae-Kyu;Lee, Nam-Hee
    • Journal of Korean Society of Environmental Engineers
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    • v.31 no.7
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    • pp.541-548
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    • 2009
  • Iron coated media (activated carbon, sand and starfish) were prepared at pH 4 and applied for the treatment of landfill leachate containing organic compounds and soluble metal ions such as $Zn^{2+},\;Cu^{2+},\;Mn^{2+}$ in batch and column experiment. The amount of iron coated in media was analyzed with EPA 3050B method. The removal efficiency of metal ions and phenol was compared with iron coated media. The amount of iron coated in Fe-AC and ICS(iron coated sand) were 1,612 mg/kg and 1,609 mg/kg, respectively, while it was higher with 1,768 mg/kg in ICSF(iron coated starfish). The result of batch study represent the highest removal efficiency in the treatment of wastewater using iron coated starfish. In column study, the removal efficiency of phenol and metal ions was higher in multi-layered system of ICS, Fe-AC and ICSF compared to single layered system. Breakthrough time in the effluent was relatively enhanced for $Cu^{2+}$ and $Zn^{2+}$ in multi-layered system while the removal efficiency of $Mn^{2+}$ were not varied much. Therefore, multi-layered system was identified as the better system for the treatment of wastewater containing of metal ions and organic compound.

Production of Hydrogen Sulfide Gas from Sediments in Concrete Sewer (하수관내 침전물의 황화수소가스 발생에 관한 연구)

  • Cho, Sun-Hyoung;Ko, Young-Song;Nam, Sang-Ho
    • Journal of Korean Society of Water and Wastewater
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    • v.10 no.3
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    • pp.83-91
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    • 1996
  • The pulverized wastes originated from kitchen garbage grinder cause an additional load in sewage treatment plant and water environment. Therefore, several problems occur in sewer, such as microbial corrosion, odor, psychoda and fly interrupting flow of sewage etc. by their precipitation with earth and sand. This study was conducted on two experiments: hydrogen sulfide gas generation from sediments in sewer and anaerobic batch test. In anaerobic batch test, gas generation was increased when organic compounds were increased in concentration. Sulfide was decreased upon decreasing in sulfate concentration. In $H_2S$ gas generation test along the depth of sediments there were two different sampling sites which are apart from about 50 cm each other in a menhole. The one has the thickness of 55 cm from the surface, the other, of 60 cm. The hydrogen sulfide gas production rates were measured based on ranges from 0 to 10 cm, 10 to 20 cm, 20 to 30 cm for two samples. The results obtained were 1.08, between 0 to 10 cm in depth for the sample thickness of 55 cm and 3.07, 5.36, $5.42{\mu}g/g-VS{\cdot}hr$ in order of depth for the sample thickness of 60 cm, respectively.

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Application of Hybrid Constructed Wetland System for Stream Water Quality Improvement (오염하천 수질개선을 위한 Hybrid형 인공습지의 적용)

  • Kim, Seung-jun;Choi, Yong-su;Bae, Woo-keun
    • Journal of Korean Society on Water Environment
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    • v.22 no.2
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    • pp.209-214
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    • 2006
  • The purpose of this study is to improve the stream water quality by the experimental hybrid constructed wetland system. It consisted of the water layer, sand bed planted reeds, irises and roses, gravel bed, yellow-soil media bed and a flow shifter (FS) which can reverse top and bottom flow in the middle of the wetland. The organic compounds and nitrogen removal efficiencies varied with the seasons, namely temperature change. In summer, the mean efficiencies of COD and TN in the outflow from this wetland system were 63.4 and 48.0% and shown the highest, respectively, whereas, the suspended solids and phosphorus removal efficiencies seemed to be less affected by temperature. As a result of inspecting the decreasing trend of pollutants, nitrification-denitrification in the wetland was the major removal mechanism for nitrogen, the nitrogen reduction was especially enhanced by the application of a FS in the wetland, and phosphorus reduction was mainly occurred as a consequence of adsorption of the yellow-soil media.

Utilization of Waste Tires as Soil Reinforcement; (2) Environmental Effects (지반보강재로서 폐타이어의 활용; (2) 환경적 영향)

  • 윤여원;문창만;김건흥
    • Journal of the Korean Geotechnical Society
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    • v.20 no.3
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    • pp.119-128
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    • 2004
  • Environmental impact of waste tires as gound-reinforcing material is studied. Analysis for chemical compounds and toxic effect were performed on effluents from twelve lysimeters in which waste tires were mixed with sand and three initially different environmental solutions of acidic, neutral, and basic circulated through the mixture. The test results of effluents collected from the lysimeters provided that the contaminant concentrations were lower than those of Korean drinking water standards for all the selected and tested metal elements. While iron concentration increased slightly with the exposure period, other metal concentrations decreased with the number of circulation times. From the comparison with previous investigations, the contaminant concentration decreased with the increase of tire size, i.e. increases with the increase of the exposed surface of tire metals. From the toxicity tests, no deteriorative effect was observed and it could be concluded that waste tires are not biologically hostile materials.

Strength and abrasion resistance of roller compacted concrete incorporating GGBS and two types of coarse aggregates

  • Saluja, Sorabh;Goyal, Shweta;Bhattacharjee, Bishwajit
    • Advances in concrete construction
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    • v.8 no.2
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    • pp.127-137
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    • 2019
  • Roller Compacted Concrete (RCC) is a zero slump concrete consisting of a mixture of cementitious materials, sand, dense graded aggregates and water. In this study, an attempt has been made to investigate the effect of aggregate type on strength and abrasion resistance of RCC made by using granulated blast furnace slag (GGBS) as partial replacement of cement. Mix proportions of RCC were finalized based upon the optimum water content achieved in compaction test. Two different series of RCC mixes were prepared with two different aggregates: crushed gravel and limestone aggregates. In both series, cement was partially replaced with GGBS at a replacement level of 20%, 40% and 60%. Strength Properties and abrasion resistance of the resultant mixes was investigated. Abrasion resistance becomes an essential parameter for understanding the acceptability of RCC for rigid pavements. Experimental results show that limestone aggregates, with optimum percentage of GGBS, perform better in compressive strength and abrasion resistance as compared to the use of crushed gravel aggregates. Observed results are further supported by stoichiometric analysis of the mixes by using basic stoichiometric equations for hydration of major cement compounds.