• Journal of the Korean Society of Manufacturing Process Engineers
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• v.19 no.11
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• pp.102-108
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• 2020

The demand for lightweight materials and high-strength steel has rapidly increased to help reduce the weight of a vehicle body; it improves the fuel efficiency of automobiles and provides passenger safety. Additionally, as the material becomes thinner, the demand for its resistance against corrosion becomes higher. Hence, the application of the surface-treated steel sheet has surged rapidly. In this study, a weld bonding experiment using a delta spot welding machine is performed on a thin sheet of a different material (Al6061-T6/GA440). The thickness of the material was kept at 1 mm to reduce the weight of the automobile body parts. Additionally, the purpose of this study is to control the heat input by applying the welding conditions of a multi-stage pressure pattern to improve corrosion resistance shear strength. The analysis of nugget diameter measurement, shear tensile test, and salt spray test was performed to achieve the aim.

• Journal of the Korea Safety Management & Science
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• v.2 no.4
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• pp.197-208
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• 2000

ABS sensor ring has been manufactured by powder metallurgy (P/M) method using 400 series ferrite stainless steel. The results are following. It is supposedly sufficient to use for control computer due to good experimental results of magnetic characteristics. Compared with sensor ring made by iron, 400 series ferrite stainless steel has shown a good corrosion resistance without an addition surface treatment. Thus the decreasing production process has been obtained. As a result mechanical characteristics of hardness and tensile test, 400 series ferrite stainless steel shown a good endurance when it is combined to constant velocity joint(C/V), and has a good hardness properties endurable to sand and pebble impact. The products before sintering are much more corrodible in the condition of spray test of salt water and ammonia than humidity and nitrogen condition.

• Clean Technology
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• v.11 no.3
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• pp.153-164
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• 2005

This study found a reliable evaluation for four kinds of pb-Free plating solutions and it's layers, through pure Sn, SnAg, SnBi and SnCu. These four kind of solutions are widely used to pb-Free plating. Hull-cell, Harring-blum, coverage, throwing power, current efficiency, stability, life-time, composition, hardness, roughness, abrasion, scratch, solderability, corrosion, contact angle, morphology, SIR(Surface insulation resistance) and Whisker test were experimented. Also, Using ICP, XRF, FE-SEM, EDS, temperature/humidity chamber, solderability tester, hardness tester, roughness tester, abrasion tester, salt spray tester, contact angle tester, SIR tester, and microscope. In this paper could be shown the systematic and various analysis for reliability about four kinds of pb-Free plating solutions, processes and it's deposit surface.

• Corrosion Science and Technology
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• v.12 no.1
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• pp.27-33
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• 2013

According to its merits about high curing speed and low emission of volatile organic compounds, UV curable inorganic-organic coating technology has been developed as an alternative for toxic and carcinogenic chromate-based treatments for years. It is consistently observed that ultra-thin films offer excellent corrosion protection as well as paint adhesion to metals. Based on the tetra-ethylorthosilicate(TEOS) and methacryloxypropyl trimethoxysilane(MPTMS), inorganic sol was synthesized and formed hybrid networks with UV curable acrylic monomer, 6-hexanediol diacrylate(HDDA), trimethylolpropane triacrylate(TMPTA), pentaerylthritol triacrylate(PETA). Several methods were used to test their properties such as salt spray test, potentiodynamic measurement, tape peel test, etc. It was shown that anti-corrosive property and stability of storage were affected by the molecular ratios of inorganic and organic compounds. It was not only the stability of storage, but had a excellent anti-corrosive, paint adhesive, and anti-solvent properties in a final molar ratios of 0.6/0.04/0.86/0.005 (TEOS/MPTMS/Acetone/HNO3) and 0.08/0.106/0.081/0.02 (TMPTA/HDDA/PETA/photo initiator).

• Journal of Welding and Joining
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• v.33 no.4
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• pp.37-43
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• 2015

Characteristics of dissimilar metal welds between STS 316L and carbon steel ASTM A516 Gr.70 made with GTAW have been evaluated in terms of microstructure, ferrite content, chemical analysis, hardness and corrosion resistance. Three heat inputs of 9.00, 11.25, 13.00kJ/cm were employed to make joints of dissimilar metals with ER309 wire. Based on microstructural examination, the amount of vermicular type of ${\delta}$-ferrite was increased with increasing heat input due to the increase of Creq/Nieq in the second layer of welds. Based on the EDX analysis of weld metals, Cr and Ni content in the 2nd layer increased while those content in the first layer of welds decreased with heat inputs. Cellular solidification mode in the 1st layer and dendritic solidification mode in the 2nd layer due to different cooling rates were prevailed, respectively. Heat affected zone which formed hard microstructure showed higher hardness than the weld metal. The salt spray test of dissimilar metals weld joints showed that the carbon steel surfaces only corroded. The weight loss rate due to corrosion increased up to 100hours but it decreased above 100 hours. There was little difference in the weight loss caused by corrosion regardless of heat inputs.

• Polymer(Korea)
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• v.34 no.5
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• pp.405-409
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• 2010

New sol-gel precursors having the ability to protect iron against corrosion were synthesized and used to prepare organic-inorganic hybrid coatings based on epoxy. Bisphenol A epoxy was modified with 3-isocyanatopropyltriethoxysilane to improve the compatibility, and water and HCl were used as catalysts for sol-gel process. Various coating formulations were prepared depending on the type of sol-gel precursors and the amount of each ingredient, and cast on iron substrates by dip-coating and thermally cured. Corrosion protection properties of coated iron were studied by a salt spray test and electrochemical impedance spectroscopy under 0.1 M NaCl electrolyte. Hybrid coatings containing anticorrosive functional group exhibited excellent corrosion protection on iron, compared to that of typical hybrid coatings. From electrochemical impedance spectroscopy, the hybrid coatings containing anticorrosive functional group could maintaine the initial impedance after 500 h, while the impedance of hybrid coatings without them started to decrease after 24 h.

• Journal of the Korean institute of surface engineering
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• v.49 no.5
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• pp.454-460
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• 2016

Double-layered Al-Mg films have been deposited by using an e-beam deposition method on a cold-rolled steel sheet(CR), which the structure of the film was Al/Mg/CR. The micro-structure, alloy phase, and corrosion resistance of the Al-Mg coated CR were investigated before and after heat treatment at $400^{\circ}C$ for 2, 3, and 10 min in a nitrogen atmosphere. Total thickness of Al-Mg films was fixed at $3{\mu}m$ and the thickness ratio of Al and Mg layers(Al:Mg) has been changed from 5:1 to 1:5. The cross-sectional morphology of the films, which had the thickness ratio of 2:1(Al:Mg), 1:1, and 1:2, was changed after heat treatment from columnar to featureless structure. The x-ray diffraction data for as-deposited films showed only pure Al and Mg peaks. Al-Mg alloy peaks such as $Al_3Mg_2$ and $Al_{12}Mg_{17}$ phase appeared after the heat treatment. The Al-Mg coating with the thickness ratio of 1:1(Al:Mg) showed the best corrosion resistance of up to 500 hours by salt spray test.

• Proceedings of the Korean Institute of Surface Engineering Conference
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• 2015.05a
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• pp.32-32
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• 2015

Electrophoretic paint (E-paint) was investigated on four different magnesium substrates: as-extruded AZ61 (AZ61), heat-treated AZ61 (AZ61-H), as-extruded TZ61 (TZ61) and heat-treated TZ61 (TZ61-H), to elucidate the effect of heat treatment and alloying elements on the deposition and corrosion resistance of E-paint. It was found that, a rapid increase of voltage, indicating that the deposition of E-paint had started, was observed after an induction time of 0.39 min for AZ61-H, 0.43 min for AZ61, 0.51 min for TZ61-H and 0.58 min for TZ61. The amount of E-paint deposited on the four samples was approximately similar, but the electrical charge used for the deposition process on the heat-treated samples was smaller than that on the as-extruded samples. The current efficiencies of E-paint on AZ samples (AZ61 and AZ61-H) were higher than those of TZ samples (TZ61 and TZ61-H), and on the heat-treated samples were higher than on as-extruded samples. All E-paintings on the four magnesium substrates had an excellent adhesion without any paint detached by tape peel-test. However, many large blisters were formed on the surface of AZ samples, and none, or very small blisters were observed on TZ samples after immersion test in DI-water for 500 h at $40^{\circ}C$. Under salt spray test (SST) conditions, E-paint on AZ samples showed blistering adjacent to scribes, while blistering of E-paint occurred on intact areas of TZ samples. The E-paint on heat-treated samples showed much better corrosion resistance than that on as-extruded samples. The ranking of greater to lesser corrosion resistance of the E-paint on these four different magnesium substrates is indicated by the order: AZ61-H > AZ61 > TZ61-H > TZ61.

• Journal of Nuclear Fuel Cycle and Waste Technology(JNFCWT)
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• v.8 no.1
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• pp.33-39
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• 2010

The electrolytic reduction of a spent oxide fuel involves a liberation of the oxygen in a molten LiCl electrolyte, which results in a chemically aggressive environment that is too corrosive for typical structural materials. Accordingly, it is essential to choose the optimum material for the processing equipment that handles the high molten salt. In this study, hot corrosion studies were performed on bare as well as coated superalloy specimens after exposure to lithium molten salt at $675^{\circ}C$ for 216 h under an oxidizing atmosphere. The IN713LC superalloy specimens were sprayed with an aluminized NiCrAlY bond coat and then with an $Y_2O_3$ top coat. The bare superalloy reveals an obvious weight loss due to spalling of the scale by the rapid scale growth and thermal stress. The chemical and thermal stability of the top coat has been found to be beneficial for increasing to the corrosion resistance of the structural materials for handling high temperature lithium molten salts.

• Applied Chemistry for Engineering
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• v.18 no.3
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• pp.296-302
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• 2007

A trivalent chromate conversion coating solution which is composed with $KCr_2(SO_4)$ as main component was investigated to test a feasibility of use as an alternative six-valent chromate conversion coating for improvement of anti-corrosion of zinc plating. The proposed trivalent convesion coating was consisted of $KCr(SO_4)$ 35~45 g/L as trivalent chromium source, $NaH_2PO_4$ 20~30 g/L as phosphate, $CoSO_4$, 10~20 g/L, $ZnSO_4$ 10~20 g/L as metallic sulfates. This trivalent chromate films which are coated by this chromate conversion coating solution under pH 2.0~2.2, immersion time of 20~25 s at room temperature are able to achieve over 120 h in neutral salt spray test to 5% white rust.