• Title/Summary/Keyword: salt dispersion

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Retention and Drainage Characteristics with Inverse Emulsion Type C-PAM

  • Son, Dong-Jin;Kim, Bong-Yong
    • Journal of Korea Technical Association of The Pulp and Paper Industry
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    • v.38 no.5 s.118
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    • pp.24-30
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    • 2006
  • This study was performed to characterize inverse emulsion type cationic polyacrylamide (PAM) and to compare with powder and salt dispersion type PAMs as a retention and drainage aid. Salt dispersion type PAM has defects of high amount of salt which increases conductivity of white water, low active polymer contents and relatively worse retention and drainage properties than others because of its low molecular weight. Powder type PAM has benefit of high active polymer contents and good retention and drainage properties, but defects of low dissolution speed and insoluble particle generation were observed. However, inverse emulsion type showed the best retention and drainage aids among them by controlling molecular weight and morphology easily and it had relatively higher active polymer contents and better solubility.

Interaction of Rare Earth Chloride Salts to Alumina and Mullite in LiCl-KCl at 773 K

  • Horvath, David;Warmann, Stephen;King, James;Marsden, Kenneth;Hoover, Robert
    • Journal of Nuclear Fuel Cycle and Waste Technology(JNFCWT)
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    • v.18 no.3
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    • pp.337-346
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    • 2020
  • Two commonly used ceramics in molten salt research are alumina and mullite. The two ceramics were exposed to a combination of rare earth chlorides (YCl3, SmCl3, NdCl3, PrCl3, and CeCl3; each rare earth chloride of 1.8 weight percent) in LiCl-KCl at 773 K for approximately 13 days. Scanning electron microscopy with wave dispersion spectra was utilized to investigate a formation layer or deposition of rare earths onto the ceramic. Only the major constituents of the ceramics (Al, Si, and O2) were observed during the wave dispersion spectra. X-ray fluorescence was used as well to determine concentration changes in the molten salt as a function of ceramic exposure time. This study shows no evidence of ionic exchange or layer formation between the ceramics and molten chloride salt mixture. There are signs of surface tension effects of molten salt moving out of the tantalum crucible into secondary containment.

Effects of the Water Quality on the Dispersion Properties of Bentonites Used for Drilling Fluid (시추이수용 벤토나이트의 분산 특성에 미치는 수질의 영향)

  • Akther, Shamima;Hwang, Jin-Yeon;Lee, Hyo-Min
    • Journal of the Mineralogical Society of Korea
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    • v.20 no.1 s.51
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    • pp.21-33
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    • 2007
  • The dispersion/flocculation behavior of bentonite is a major concern in performance of drilling fluid. We studied the dispersion/flocculation characteristics of three commercial bentonites [two CMC (carboxymethyl cellulose) treated and one untreated] in waters of different pHs and salt concentrations. We also examined changes in the viscosity of bentonite suspensions in such waters as a major rheological property of drilling fluid. The dispersion/flocculation behaviors of bentonites were measured by two methods: colorimetric and light scattering method. Light scattering method allows estimating the floc diameter and flocculation rate. The dispersion and flocculation behaviors were diverse with the different bentonites and water qualities. In distilled water, all the bentonites were well dispersed up to first 10 minutes. After that, the CMC-bearing bentonites were flocculated. In salt waters, all the samples were flocculated and the flocculation rate is varied with salt concentration and polymer content. The volume of settled flocs decreased with increasing salt concentration. The flocculation rate and floc diameter increased with decreasing pH of solutions, whereas the volume of settled flocs increased with increasing pH of solutions. The bentonites of fast flocculation behavior had low viscosity. The results of the present study will be helpful in applying bentonites to drilling fluids in diverse environments.

The Effect of Glyceride Modified by Fatty Acid on Mechanical Properties of Silica filled Rubber Compounds (지방산으로 개질된 글리세라이드가 실리카 충진 배합고무의 가황과 기계적 물성에 미치는 영향)

  • Kim, Dong-Wook;Kim, Chang-Hwan;Jung, Ho-Kyun;Kang, Yong-Gu
    • Elastomers and Composites
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    • v.48 no.2
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    • pp.114-124
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    • 2013
  • To study the effects of structural difference and fatty acid chain length of glyceride, new dispersion agents having various glyceride structures such as mono-, di-, and tri-, were prepared using glycerol extracted from palm oil and fatty acid having various chain length ranges from 12 to 18. These dispersion agents were mixed with the rubber compounds and compared with conventional metal salt dispersion agents. Glyceride dispersion agent provided remarkable improvement in silica dispersion, compared to metal salt fatty acidic one, even though the viscosity of mixtures was relatively high due to low lubricating effect, and this was approved by mechanical properties, wear properties, and Payne effect. Also, the longer in chain length of fatty acid and the smaller in numbers of fatty acid, the dispersity of silica was improved.

Study on Surface Treatment and Test over the Barrel of Small Arms (개인화기 총열 표면처리 및 시험에 관한 연구)

  • Chae, Je-Wook;Kim, In-Woo;Lee, Young-Shin
    • Proceedings of the KSME Conference
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    • 2004.04a
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    • pp.722-727
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    • 2004
  • This paper includes the comparative study between Cr plating and nitriding process with an aim at improving corrosion, wear and maintainability for KNR(Korean Next Generation Rifle) 5.56mm barrel. The endurance test was conducted to compare the performance of standard barrel, Cr plating barrel and nitriding barrel. Main activities are described as follows; optimal Cr plating and nitriding process set-up for KNR 5.56mm barrel; durability test of each barrel(20,000 rounds); salt water immersion test; dispersion, initial velocity, inner diameter data acquisition. According to the results of this firing test, Cr plating barrel is superior to standard barrel and nitriding barrel in view of corrosion, wear and maintainability

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Study on Surface Treatment over the Barrel of Small Arms (소구경 총열 표면처리에 관한 연구)

  • 채제욱;김인우;이영신
    • Journal of the Korea Institute of Military Science and Technology
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    • v.7 no.1
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    • pp.5-12
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    • 2004
  • This paper includes the comparative study between Cr plating and nitriding process with an aim at improving corrosion, wear and maintainability for KNR(Korean Next Generation Rifle) 5.5mm barrel. The endurance test was conducted to compare the performance of standard barrel, Cr plating barrel and nitriding barrel. Main activities are described as follows; optimal Cr plating and nitriding process set-up for KNR 5.56mm barrel; durability test of each barrel(20,000 rounds); salt water immersion test; dispersion, initial velocity, inner diameter data acquisition. According to the results of this firing test, Cr plating barrel is superior to standard barrel and nitriding barrel in view of corrosion, wear and maintainability.

Effects of Ground Calcium Carbonate Dispersion by Sodium Polyacrylate (폴리아크릴산 소다에 의한 중질 탄산칼슘의 분산효과)

  • Ro, Yoon-Chan;Jeong, Tae-Young;Cho, Kyoung-Haeng;Roh, Seung-Ho;Nam, Ki-Dae
    • Journal of the Korean Applied Science and Technology
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    • v.10 no.1
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    • pp.49-55
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    • 1993
  • Ground Calcium Carbonate, among paper coating pigments, will influence less dispersant demand, less binder demand, increase coating solids from 58% to 70%, which means high speed coating, less shrinkage during drying, less energy consumption, more uniform coverage of fibers. The quality point of view of Ground Calcium Carbonate, brightness, particle size, Particle size distribution, hardness, impurities content are important. More important factors of Ground Calcium Carbonate which influence the paper coating process are dispersion mechanisms and their effects. The study was made to investigate the effect of Ground Calcium Carbonate dispersion by sodium salt of polyacrylate dispersant composition and dispersion condition. Basic tests such as physical, optical and chemical were perfumed, and dispersion effects were investigated by different conditions. The results showed that the type of dispersant affected the dispersion effects, and the Ground Calcium Carbonate has critical dispersant demand.

Preparation and Characteristics of Maleated Polyethylene Modified with Poly(dimethylsiloxane) (Poly(dimethylsiloxane) 변성 Maleated Polyethylene의 제조와 그 특성)

  • Lee Byoung-Chul;Kang Doo-Whan
    • Polymer(Korea)
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    • v.30 no.3
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    • pp.224-229
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    • 2006
  • Quaternary ammonium salt terminated silane was prepared from aminopropyldimethylethoxysilane with methyliodide and ionized 7,7,8,8-tetracyanoquinodimethane $(Li^+TCNQ^-)$ was prepared from TCNQ with methyliodide and lithium iodide. Quaternary ammonium salt silane-TCNQ adduct (ST) was prepared by reacting quaternary ammonium salt terminated silane with $Li^+TCNQ^-$ solution. Poly (dimethylsiloxane)-ST adduct (PST) was prepared by condensation of $\alpha,\omega-hydroxyl$ group terminated poly (dimethylsiloxane) (PDMS) with ST. Maleated polyethylene modified with PDMS (PST-g-MPE) was prepared by melt polymerization of maleated PE and PST in internal mixer and PST-g-MPE/carbon black (CB) and MPE/CB composites were prepared by compounding PST with MPE and PST-g-MPE, respectively. The thermal and mechanical properties of the composites were measured and dispersion characteristics of CB in matrix rosins show that the dispersion of CB in PST-g-MPE/CB was better than that of MPE/CB composite.

Electrical and Rheological Behavior of the Anhydrous ER Fluids Based on Chitosan Derivatives as the Dispersion Phases

  • Choi Ung-su;Sung Bo-hyun
    • Proceedings of the Korean Society of Tribologists and Lubrication Engineers Conference
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    • 2004.11a
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    • pp.323-329
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    • 2004
  • The electrical and rheological properties pertaining to the electrorheological (ER) behavior of chitosan derivatives, chitosan, chitosan ammonium salt and chitosan phosphate suspensions in silicone oil were investigated. Chitosan derivative suspensions showed a typical ER response (Bingham flow behavior) upon application of an electric field. However, chitosan phosphate suspension exhibited an excellent shear yield stress compared with chitosan and chitosan ammonium salt suspensions. The difference in behavior results from the difference in the conductivity of the disperse phases due to the difference of their polarizability. The shear stress for the chitosan, chitosan ammonium salt and chitosan phosphate suspensions exhibited a linear dependence on the volume fraction of particles and 1.18 ,1.41 and 1.67 powers of the electric field. On the basis of the experimental results, the newly synthesized chitosan derivative suspensions found to be an ER fluid.

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Electrical and Rheological Behavior of the Angydrous ER Fluids Based on Chitosan Derviatives as the Dispersion Phases

  • Choi, Ung-Su
    • KSTLE International Journal
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    • v.5 no.2
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    • pp.49-51
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    • 2004
  • The electrical and rheological properties pertaining to the electrorheological (ER) behavior of chitosan derivatives, chitosan, chitosan ammonium salt and chitosan phosphated suspensions in silicone oil were investigated. Chitosan derivative suspensions showed a typical ER response (Bingham flow behavior) upon application of an electric field. However, chitosan phosphate suspension exhibited an excellent shear yield stress compared with chitosan and chitosan ammonium salt suspensions. The difference in behavior results from the difference in the conductivity of the disperse phases due to the difference of their polarizability. The shear stress for the chitosan, chitosan ammonium salt and chitosan phosphate suspensions exhibited a linear dependence on the volume fraction of particles and 1.18, 1.41 and 1.67 powers of the electric field. On athe basis of the experimental results, the newly synthesized chitosan dervative suspensions found to be an ER fluid.