• Elastomers and Composites
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• 제28권2호
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• pp.103-107
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• 1993

To make new filler for conducting rubber, the sample of perovskite-related ferrite system $Dy_{2-x}Sr_{1+x}Fe_2O_{7-y}$ (x=0.0, 0.5, 1.0, 1.5, and 2.0) were synthesized at 1473K in air. $M{\ddot{o}}ssbauer$ spetrum of x=0.0 sample shows typical six line pattern with $M{\ddot{o}}ssbauer$ parameters, $I.S=3.6{\times}10^{-1}mm/sec,\;E_Q=-7.0{\times}10^{-2}mm/sec,\;H_{int}=5.19{\times}10^2\;Koe$. In case of x=2.0, the spectrum is composed of single line exhibiting coexistance of $Fe^{3+}(I.S.=3.7{\times}10^{-1}mm/sec)$ ions and $Fe^{4+}(I.S.=-1.9{\times}10^{-1}mm/sec)$ ions. With increase in x value electrical conductivity at constant temperature sharply increased and the activation energies decreased from $3.8{\times}10^{-1}\;to\;1.9{\times}10^{-1}\;eV$.

• 전산구조공학
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• 제8권2호
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• pp.103-113
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• 1995

고무 재질로 이루어진 차량 구조물의 연결요소에 대한 등가 강성계수는 차량 시스템 동역학 특성에 매우 민감하게 영향을 주므로 이에 대한 신뢰성있는 해석이 요구된다. 본 논문에서는, 고무의 역학 모델을 정하중 하에서는 유한 변형 및 Hook 모델로 그리고 동하중 하에서는 Voigt 모델로 가정하여, 연결요소의 등가 정-동강성계수를 유한요소법으로 해석하고자 한다. 실제 차량에 사용되고 있는 동일 모양의 방진고무들을 실험 평가한 결과 강성계수값들의 분산 정도가 심함을 알 수 있었다. 유한요소 해석에 필요한 고무 재질의 물성치의 신뢰성을 높이기 위하여 제품의 특정 방향 정특성 실험 데이타로부터 역으로 재질의 물성치를 규명하였다. 그 물성치로부터 원하는 방향에서의 강성계수를 산출하여 실험치와 비교하여 효용성을 보였다.

• 한국콘크리트학회:학술대회논문집
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• 한국콘크리트학회 2008년도 추계 학술발표회 제20권2호
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• pp.931-934
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• 2008

폴리우레탄은 방수재로 널리 사용되며 구조물에 발생되는 균열 및 거동에 의해 항상 외력을 받고있을 뿐만 아니라 사용 환경에 따라 각종 환경열화 인자에 노출되어 있다. 환경 열화인자로서는 자외선, 오존, 열, 수분 등이 잘 알려져 있다. 그 중에서 모든 열화의 기본이 되는 열의 영향, 특히 고온에서의 영향이 중요하다. 따라서, 노출형인 우레탄 고무계 1류 도막 방수재의 경우는 80$^{\circ}C$에서, 비노출형의 경우는 70$^{\circ}$C에서 촉진 열열화 시험을 3주간 실시하였다. 결과는 방수재의 기본물성과 인장 강도 및 신장율 모두 저하되는 경향을 보였으며, 특히 온도 60$^{\circ}$C에서 측정할 경우 급격히 물성 저하가 발생되었다.

• 대한기계학회논문집A
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• 제30권5호
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• pp.543-549
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• 2006

The bursting properties under various conditions were investigated to ascertain the optimum conditions to yield the best properties. Fiber aspect ratio (AR: length of fiber/diameter of fiber), interphase condition and fiber content were considered as variables which impact the bursting pressure, bulge constant, torsional rigidity ratio. The bursting pressure of reinforced rubber increases up to 8.73 times compared to the virgin material. The better interphase condition shows the higher bursting pressure at given AR and fiber content. The bulge constant and torsional rigidity highly decrease with increasing AR and better interphase condition at same fiber content. The bulge constant and torsional rigidity reveal the minimum of 11% and 0.6% of the matrix, respectively. The bursted shape after test shows the different patterns between unfilled and reinforced rubbers. The case of virgin rubber shows a radiating shape while that of reinforced rubber shows a fluctuating straight line. Overall, it was found that the fiber AR and interphase condition have an important effect on bursting properties.

• 대한기계학회논문집A
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• 제25권11호
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• pp.1887-1894
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• 2001

The effects of carbon black on the material properties and the fatigue life of the carbon-black filled natural rubbers were investigated. Different kinds of carbon blacks resulted in different fatigue lives, hysteresis, and critical J-values. It was noticed that the hysteresis was inversely proportional to the difference between DBPA and CTAB, and the critical J-value was almost the same regardless of the length of a precrack. In addition, different kinds of carbon blacks resulted in different fracture morphologies, and micro-scale and macro-scale roughnesses. The critical J-value was proportional to the micro-scale roughness. and it seemed relate to the size distribution of carbon black particles. By reviewing all the experimental data. it was finally noticed that the logarithmic value of the fatigue life could be linearly expressed by a multiplication of the critical J-value and the logarithmic value of the hysteresis.

• Elastomers and Composites
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• 제50권1호
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• pp.55-61
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• 2015

Manufacturing process of OLED contains adsorption-desorption process of glass substrate. There are several adsorption methods of glass substrate such as atmospheric pressure, vacuum and electrostatic adsorption. However, these methods are very complex to connect system. Therefore, the adsorption method using silicone rubber based sticking chuck was proposed in this study. Three types of silicone rubbers having 0, 19.3 and 32.2 wt% of fluorine were used and their mechanical properties, surface energies and adsorption properties were examined. According to the results ${\sigma}_{300}$ and hardness increased with increasing fluorine contents, but elongation was decreased. Also, fluorosilicone rubber containing 32.2 wt% of fluorine showed the lowest surface tension, among three types of rubber and resulted in the highest initial tack with glass substrate. After the adsorption-desorption test of 300,000 cycles was performed, the adsorption force of S-1 (silicone rubber) decreased largely from 2.34 to 0.73 MPa. However, the S-3 (fluorosilicone rubber having 32.2 wt%. of fluorine) decreased only from 3.15 to 2.24 MPa. From this study, we obtained the valuable equations related to long term durability of silicone based sticking chuck. Finally the transfer of silicone rubber to glass substrate with the adsorption-desorption process was not occurred and this phenomenon was examined by UV-Visible spectroscopy.

• Elastomers and Composites
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• 제52권1호
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• pp.48-58
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• 2017

Thermoplastic elastomers (TPEs), a unique class of polymers, combine the processing ease of thermoplastics with the advanced properties of thermoset rubbers. TPEs can be remelted several times without any significant loss of properties, and can be molded into complex shapes using conventional processing equipment. Due to their characteristics, TPEs are ideal for use in a variety of applications in the automotive field. Although the TPE market of the Republic of Korea is currently at its niche, the increasing manufacturing push from major companies is expected to open up multiple opportunities for these products in the automotive sector. This manuscript highlights a detailed technological trend of the global automotive thermoplastic elastomers market.

• 한국해양공학회:학술대회논문집
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• 한국해양공학회 2006년 창립20주년기념 정기학술대회 및 국제워크샵
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• pp.290-293
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• 2006

From the hydraulic experiment, it was concluded that upwelling could be enhanced when the relative structure height (the ratio of structure height to water depth) was 0.3 and stratification parameter was 3.0. In addition, the optimum size of rubbers was determined that the effect of the mean horizontal length of block was affected incident velocity than size of block. In the numerical experiment, the relation between the shape of rubber and stratification parameter was verified, ana the hydraulic characteristics of 3-D flow field around the artificial structures were investigated. Phenomena of flow field around the artificial upwelling structures corresponded with the results of hydraulic experiment. The position with maximum velocity in artificial upwelling structure was the center of top of its front side and the slip stream occurred at the inside and behind-bottom of artificial upwelling structures. The velocity of slip stream and early amplitude of velocity were higher in the inside than the behind-bottom.

• 한국전기전자재료학회논문지
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• 제17권10호
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• pp.1068-1078
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• 2004

In this paper we investigated the characteristics of surface degradation in silicone rubber due to corona exposure and recovery mechanism. It was shown that surface free energy was 22.42 mJ/$m^2$ on initial sample but surface free energy was approximately increased to 71.14 mJ/$m^2$ after 45 minutes. However, surface free energy on silicone rubber after corona discharge treatment was completely recovered within a short time due to diffusion of low molecular weight(LMW) silicone fluid. It was shown that corona discharge insured the increase of diffusible LMW chains, which could lead to recover the surface hydrophobicity. 200～370 g/mol distribution of LMW silicone fluid which was extracted by solvent-extraction with gel permeation chromatography (GPC) was contributed to recovery. The surface degradation characteristics on silicone rubbers and the recovery mechanism based on our results were discussed.

• 환경위생공학
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• 제13권1호
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• pp.82-90
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• 1998

The study was carried out to investigate on the response of environmental sanitation problems in action of the volume based waste charge system in Seoul. The responses from the 396 persons who dwelled in Seoul was stimulatively answered, this system was considered as a successful one 69.6% of total answers, but little portion (21.2%) of those was unknown on the mean of this system. And we knew that this system was need to the communication and education through the press media about this one. After the action of the volume based waste charge system, the volume of refuse discharged in a day was decreased 30-50% than before. In the problems of environmental sanitation after this system, the number of sanitary insect(cockroach etc) and rat was decreased, also the production of order and dust caused by refuse was decreased in comparison with those before. This results were considered that the Separate Collection should be perfectly performed. In response, the regular envelope of refuge was serious problems, the improvement for this one was demanded, The kind of difficult refuse treated was waste foodstuffs> electric products> rubbers> furniture> bottles, cans>papers, pulps etc. and the next proposal for this system should be prepared. Conclusively, the volume based waste charge system should be remarkable system in terms of resources recycling as well as wastes reduction. Above all in order to conform this system the separate collection system should be systematically performed, the next improvable proposal of the detailed methods in this system should be prepared.