• Elastomers and Composites
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• 제57권4호
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• pp.188-196
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• 2022

Styrene-butadiene rubber(SBR) is a copolymer of styrene and butadiene. It is composed of 1,2-unit, 1,4-unit, and styrene, and its properties are dependent on its microstructure. In general, rubber composites contain a single rubber or a blended rubber. Similarly, SBR is used by mixing with natural rubber(NR) and butadiene rubber(BR). The composition of a rubber article affects its physical and chemical properties. Herein, an analytical method for determining the microstructure of SBR using via pyrolysis is introduced. Pyrolysis-gas chromatography/mass spectrometry is widely used to analyze the microstructure of polymeric materials. The microstructure of SBR can be determined by analyzing the principal pyrolysis products formed from SBR, such as 4-vinylcyclohexene, styrene, 2-phenylpropene, 3-phenylcyclopentene, and 4-phenylcyclohexene. An analytical method for determining the composition of SBR/NR, SBR/BR, and SBR/NR/BR blends via pyrolysis is introduced. The composition of blended rubber can be determined by analyzing the principal pyrolysis products formed from each rubber component.

• 대한안전경영과학회:학술대회논문집
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• 대한안전경영과학회 2012년 추계학술대회
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• pp.355-368
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• 2012

This paper, the hardness of the silicone rubber wire for 50, 60 degrees, 70 degrees High Temperature Vulcanizing (HTV) method using specimens were fabricated. In this paper, in order to investigate the dielectric properties of silicone rubber for wire specimens, the temperature range of $30^{\circ}C{\sim}170^{\circ}C$, the frequency range from 100Hz~4.5MHz report surveyed about the frequency and temperature dependent properties.

• 고무기술
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• 제7권1호
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• pp.8-16
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• 2006

Plastic/rubber blends are ultrasonically treated during continuous extrusion in order to investigate the in-situ compatibilization of the blends without any chemicals. The mechanical properties of each blend were significantly improved by ultrasonic treatment. It is believed that ultrasonic treatment of the blends enhances intermolecular interaction, improves adhesion at the interface and creates copolymers during very short time. The created copolymers are believed to be a major reason for enhancing mechanical properties of the blends by in-situ compatibilization during extrusion. This process can be applied fur preparing plastic/rubber blends to make thermoplastic elastomers or plastic/plastic and rubber/rubber blends, and for making novel copolymers from practically any pairs of existing polymers to achieve desirable chemical and physical properties.

• Advances in concrete construction
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• 제14권1호
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• pp.15-34
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• 2022

The use of waste rubber in concrete can reduce natural aggregate consumption and improve some technical properties of concrete. Although there are several equations for estimating the mechanical properties of concrete containing waste rubber, limited numbers of machine learning-based models have been proposed to predict the mechanical properties of rubbercrete. In this study, an extensive database of the mechanical properties of rubbercrete was gathered from a comprehensive survey of the literature. To model the mechanical properties of rubbercrete, M5P tree and linear gene expression programming (LGEP) methods as two machine learning techniques were employed to achieve reliable mathematical equations. Two procedures of input variable selection were considered in this study. The crucial component ratios of rubbercrete and concrete age were assumed as the input variables in the first procedure. In contrast, the volumes of the coarse and fine waste rubber and the compressive strength of concrete without waste rubber were considered the second procedure of the input variables. The results show that the models obtained by LGEP are more accurate than those achieved by the M5P model tree and existing traditional equations. Besides, the volumes of the coarse and fine waste rubber and the compressive strength of concrete without waste rubber are better predictors of the mechanical properties of rubbercrete compared to the first procedure of input variable selection.

• Elastomers and Composites
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• 제54권3호
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• pp.175-181
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• 2019

The research and development of high-performance polymer materials with excellent gas barrier properties has gained considerable attention from the viewpoint of expanding their applications in various fields, including tire automobile parts and the polymer film industry. Natural rubber (NR) has been widely used as a rubber material in real-life, but its application is limited owing to its poor gas barrier properties. In this paper, we study the gas barrier properties of NR, epoxidized natural rubber (ENR), and their blend compositions by using molecular simulation. The results show that ENR-50 has superior oxygen barrier properties than those of NR. Moreover, the oxygen barrier properties of a blend of NR/ENR-50 improve with increasing volume fraction of ENR-50. The trend of improved oxygen barrier properties of NR, ENR-50, and their blend is in good agreement with experimental observations.

• International Journal of Concrete Structures and Materials
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• 제4권1호
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• pp.17-23
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• 2010

The feasibility of the use of scrap tire rubber in concrete was investigated. The tests conducted in two groups: replacing of coarse aggregates with crumb rubber and cement particles with rubber powder. To distinguish the properties of new concrete, the following mechanical and durability tests were designed: compressive, tensile and flexural strength, permeability and water absorption. Rubber addition could affect the concrete properties depend on the type and percentage of the rubber added. Although the rubber addition modifies the mechanical characteristics of concrete in a way, but higher rubber content could not be useful. Concrete durability showed more dependency to the type of rubber instead of percentage of rubber. Moreover, to optimize the mechanical and durability of rubberized concrete, the useful percentage of rubber has been recommended.

• Elastomers and Composites
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• 제1권1호
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• pp.41-48
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• 1966

The physical properties of rubber coated fabrics, treated by means of spreading and topping process were studied. 1. The tearing strength of the rubber coated fabrics has shown decreasing tendency in comparison with fabric itself 2. Generally, the tearing strength is inversely proportional to the adhesion. 3. The value of hydrostatic pressure is in proportion to the density and tensile strength of the fabrics. 4. The topping process shows greater difference in adhesion initial and after water immersion than spreading process.

• 아시안잔디학회지
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• 제16권1호
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• pp.19-30
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• 2002

경직된 지반의 물리성 개선재로서 rubber chip의 토양 내 혼합 또는 배토는 잔디의 생육과 지반의 이·화학성 및 중금속 추출 실험을 통하여 다음과 같은 결론을 얻었다. Rubber chip의 토양 내 혼합은 지면의 온도 상승효과를 가져왔으며 이는 겨울철의 동해방지 및 맹아출현기를 앞당길 수 있을 것이라 추정된다. 그러나 복사열이 높은 여름에는 rubber chip에 의한 표면, 지중 온도의 상승으로 잔디의 피해가 우려된다. 또한 토양 내에 rubber chip의 혼합함량(rubber chip 20%, 40%)이 많을수록 잔디의 발아와 생육 및 피복에 부정적인 영향을 끼쳤다. Rubberchip의 토양혼합은 지반의 이·화학성 변화에 크게 작용하지 않았으며 중금속 추출실험에서도 차이를 나타내지 않아 토양환경 오염이 없을 것으로 판단된다. Rubber chip을 배토용 재료로서 사용했을 경우, 경직된 토양구조를 개선시켜 주었다. 특히 통기작업 후 rubber chip의 배토는 지반의 표면탄성을 현저히 완화시켰다. 따라서 현재 우리나라에서 보수중이 거나 건설중인 연습구장, 보조구장에 재활용이 가능한 폐타이어 rubber chip을 지반 답압 개선용, 배토용 재료로서 사용이 가능할 것으로 판단된다.

• 대한기계학회:학술대회논문집
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• 대한기계학회 2004년도 춘계학술대회
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• pp.132-137
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• 2004

In this work, effects of hyper-elastic rubber material properties on the indentation load-deflection curve and subindenter deformation are first examined via [mite element (FE) analyses. An optimal data acquisition spot is selected, which features maximum strain energy density and negligible frictional effect. We then contrive two normalized functions. which map an indentation load vs. deflection curve into a strain energy density vs. first invariant curve. From the strain energy density vs. first invariant curve, we can extract the rubber material properties. This new spherical indentation approach produces the rubber material properties in a manner more effective than the common uniaxial tensile/compression tests. The indentation approach successfully measures the rubber material properties and the corresponding nominal stress.strain curve with an average error less than 3%.

• Elastomers and Composites
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• 제42권1호
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• pp.32-46
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• 2007

고무부품의 신뢰성을 확보하기 위해서 고무재료의 기계적 물성을 정확히 파악하는 것이 매우 중요하다. 본 연구에서는 천연 및 합성고무에 대해 다양한 환경조건에서 물성시험을 수행하여 경도, 신율 및 응력-변형률 관계와 동 특성을 파악하였다. 또한, 고무부품의 유한요소 해석에 필요한 비선형 재료상수를 단축인장과 이축인장시험을 통해 결정하였다.