• Elastomers and Composites
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• 제49권3호
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• pp.220-224
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• 2014

자동차 타이어의 트레드는 노면과 직접적으로 접촉하며 제동력, 구동력, 소음 등 중요한 역할을 한다. 트레드는 많은 그루브로 이루어져 있는데 고무의 형상을 형성하는 가류 공정에서 불량이 발생하게 되면 트레드의 기능이 저하되어 자동차 성능의 문제로 이어지게 된다. 본 논문은 CAE 해석을 통하여 가류 공정 중 구체적인 고무의 흐름을 분석하였다. 트레드 형상에 따라 고무 흐름의 편차가 발생하기 때문에 형상에 따른 트레드의 고무가 금형에 접촉되는 순서와 속도 그리고 고무의 흐름을 관찰하였다. 트레드의 형상에 따라서 고무가 금형에 안착되는 양상이 다르게 나타났으며 고무의 흐름에 큰 변화를 주는 것을 확인할 수 있었다.

• Bulletin of the Korean Chemical Society
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• 제21권1호
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• pp.69-74
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• 2000

Applicability of Thermal field flow fractionation (ThFFF) was investigated for the analysis of masticated natural rubber (NR) adhesives produced bya hot melt mastication process. An optimum ThFFF condition for NR analysis was found by using tetrahydrofuran (THF) as a solvent/carrier and a field-programming. Low flowrate (0.3 mL/min) was used to avoid stopping the flow for the sample relaxation. Measured molecular weight distribution was used to monitor degradation of rubber during the mastication process. Rubber samples collected at three different stages of the mastication process and were analyzed by ThFFF. It was found that in an anaerobic process rubber degradation occurs at the resin-mixing (compounding) zone as well as in the initial break-down zone, while in an aerobic process most of degradation occurs at the initial breakdown zone. It was also found that E-beam radiation on NR causes a slight increase in the NR molecular weight due to the formation of a branched structure.

• 한국응용과학기술학회지
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• 제32권2호
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• pp.320-325
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• 2015

Flow mark is a sort of surface defect on the composite that can arise during the filling stage of the injection molding process. The purpose of this study is to clarify a mechanism of the flow mark which appears on the surface of injection molded Polypropylene (PP) through the characterization of the surface structure. The materials used in this report are PP/rubber and PP/talc compounding, which are widely used in automobile part. The flow mark shows two different constitutions, such as a luster part and a cloud part on the surface of the injection molded PP. We have investigated the surface structure of PP/rubber and PP/talc composites by using scanning electron microscope (SEM), energy dispersive x-ray spectroscopy (EDAX) and optical microscopy (OM). As a result, the cloud part contains higher contents of the rubber and talc compare to the luster part.

• 한국정밀공학회:학술대회논문집
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• 한국정밀공학회 2006년도 춘계학술대회 논문집
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• pp.375-376
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• 2006

Thermoplastic elastomer(TPE) can be molded by conventional injection molding. Therefore TPE injection molding could be analyzed by commercial flow analysis software. However there are a little of gaps on CAE simulation results and practical molding. In this study, the properties of TPE were measured and applied to CAE simulation for comparing the simulation flow pattern and real flow pattern. The pattern that was controlled by injection time was match. The pattern that was controlled by injection stroke and rate was not match.

• Elastomers and Composites
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• 제51권4호
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• pp.263-268
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• 2016

In the polymer shaping process that uses molds, the quality of the molded products is determined not only by the flow of the (molten) polymer but also by the air venting in the cavity. Inadequate air venting in the cavity can cause defects in the product, such as voids, short shot, or black streaks. As it is critical to consider the location and size of the vents for proper venting of the air in the cavity, a method that predicts the flow of air and material is required. The venting of air by the flow of rubber inside the cavity was simulated by using a multi-phase computational fluid dynamics method. Through computer simulation, the interface of rubber and air over time was predicted. Then, the velocity and pressure distribution of the venting air were observed. Our research proposes a fundamental method for analyzing the multi-phase flow of polymer materials and air inside the cavity of a mold.

• Elastomers and Composites
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• 제54권2호
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• pp.156-160
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• 2019

The changes in the dispersion of carbon black in liquid polyisoprene under shear flow with time have been investigated by time-resolved ultra small-angle X-ray scattering (USAXS) method. The analyses of USAXS profile immediately after the start of shear flow clarified that the aggregates of carbon black with a mean radius of gyration of 14 nm and surface fractal dimension of 2.5 form the fractal network structure with mass-fractal dimension of 2.9. After the application of the shear flow, the scattering intensity increases with time at the observed whole entire q region, and then the a shoulder appears at $q=0.005nm^{-1}$, indicating that the agglomerate is broken and becomes smaller by shear flow. The analysis by the Unified Guinier/Power-law approach yielded several characteristic parameters, such as the sizes of aggregate and agglomerate, mass-fractal dimension of agglomerate, and surface fractal dimension of the primary particle. While the mean radius of gyration of the agglomerate decreases with time, the mean radius of gyration of the aggregate, mass fractal dimension, and surface fractal dimension don't change with time, indicating that the aggregates peel off the surface of the agglomerate.

• 반도체디스플레이기술학회지
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• 제12권2호
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• pp.79-84
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• 2013

Nanoimprint lithography (NIL) is the next generation photolithography process in which the photoresist is dispensed onto the substrate in its liquid form and then imprinted and cured into a desired pattern instead of using traditional optical system. There have been considerable attentions on NIL due to its potential abilities that enable cost-effective and high-throughput nanofabrication to the display device and semiconductor industry. Although one of the current major research trends of NIL is large-area patterning, the technical difficulties to keep the uniformity of the residual layer become severer as the imprinting area increases more and more. In this paper, with the rolling type imprinting process, a mold, placed upon the $2^{nd}$ generation TFT-LCD glass sized substrate($370{\times}470mm^2$), is rolled by a rubber roller to achieve a uniform residual layer. The prediction of residual layer thickness of the photoresist by rolling of the rubber roller is crucial to design the rolling type imprinting process, determine the rubber roller operation conditions-mpressing force & feeding speed, operate smoothly the following etching process, and so forth. First, using the elasticity theory of contact problem and the empirical equation of rubber hardness, the contact length between rubber roller and mold is calculated with consideration of the shape and hardness of rubber roller and the pressing force to rubber roller. Next, using the squeeze flow theory to photoresist flow, the residual layer thickness of the photoresist is calculated with information of the viscosity and initial layer thickness of photoresist, the shape of mold pattern, feeding speed of rubber roller, and the contact length between rubber roller and mold previously calculated. Last, the effects of rubber roller operation conditions, impressing force & feeding speed, on the residual layer thickness are analyzed with consideration of the shape and hardness of rubber roller.

• Korean Chemical Engineering Research
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• 제48권4호
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• pp.490-498
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• 2010

K사의 방진고무 사출성형에 있어서 애로사항인 토크로드부시(torque rod bush)의 캐비티 가장자리(edge) 구간에서의 에어트랩(air-trap) 발생 및 다이내믹 댐퍼(dynamic damper)에 있어서 사출시 미성형(short shot) 발생 등의 문제점을 해결하기 위하여, 상용 CAE 프로그램인 MOLDFLOW(Ver. 5.2)를 이용한 전산모사를 수행하여 적정금형설계를 도출하고 적정작업조건을 구축하였다. 그 결과 방진고무 중에서 토크로드부시의 사출성형에서의 에어트랩 발생 등의 공정문제를 최적 캐비티 가장자리 경사각 및 게이트 수를 조절함으로써 캐비티 가장자리에서의 유동선단(flow-front)의 유동정체를 방지하고 유동을 원활하게 하여 해결하였다. 한편 다이내믹 댐퍼의 사출시 충전(filling) 단계에서의 캐비티 비충전으로 인한 미성형 불량은 에어벤트(air-vent) 구를 에어트랩 발생 빈도가 매우 높은 유동선단 상향류와 하향류의 두 흐름이 만나는 지점에 설치함으로써 미성형 불량을 해결하였다. 또한 게이트 위치를 댐퍼 상단에서 중단으로 변경하거나 게이트 수를 증가시킨 경우에 미성형 불량이 K사의 경우보다 개선되었다.

• Elastomers and Composites
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• 제49권4호
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• pp.275-283
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• 2014

건축용 접착제로 활용되고 있는 부틸고무는 주로 시트의 형태로 사용된다. 본 연구에서는 컴퓨터 해석을 통해 부틸고무 시트 압출용 다이를 설계하였다. 압출용 다이의 내부는 크게 매니폴드와 랜드로 나뉜다. 매니폴드는 다이중앙에서 유입되는 재료가 폭 방향으로 흐름이 이루어 지도록 하는 역할을 한다. 랜드는 재료가 흐름 방향으로 균일하게 흐르게 하여 균일한 두께의 시트가 성형되도록 한다. 다이는 매니폴드와 랜드 외에도 아일랜드를 설치하여 흐름의 안정을 주도록 하는 경우가 많다. 본 연구에서는 컴퓨터 해석을 통하여 다이에서 매니폴드의 각도와 길이, 랜드 길이 그리고 아일랜드를 설계 변수로 하여 다이 출구에서 다이 폭 방향으로 균일한 흐름이 형성되도록 하는 최적의 다이형상을 연구하였다.

• Elastomers and Composites
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• 제51권4호
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• pp.280-285
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• 2016

The purpose of this study is to get optimum design and operation conditions of the heating rubber roller for laminating process. The cause of performance degradation of heating rubber roller is delamination of rubber on metal tube, rubber aging due to high temperature. We measured the material properties of thermal expansion, thermal conductivity, specific heat and density and analyzed thermal distributions of rubber layer using finite element method. As a result of heat/flow analysis, the density distribution of heating coil must shorten the stabilization time by reducing the temperature deviation on the length direction at the temperature rising section after increasing the density of the area contacting with the laminate film at the center part which is an opposite of the current composition while enabling to maintain the temperature of heater to be consistent while maintaining the temperature deviation to be low when heat loss is created. Finally, we determined optimum heating method of heating rubber roller.