• Journal of Environmental Science International
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• v.25 no.11
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• pp.1541-1554
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• 2016

To understand the characteristics of vanadium leaching from soils formed by the weathering of basalts, paleo soil at Gosan, Jeju Island, Korea, and several present-day soils from neighboring areas were collected. Leaching experiments were carried out by two approaches: 1) batch experiments under various geochemical conditions (redox potential (Eh) and pH) and 2) continuous leaching experiments under conditions similar to those of natural environments. From the batch experiments, leached vanadium concentrations were highest under alkaline (NaOH) conditions, with a maximum value of $2,870{\mu}g/L$, and were meaningful (maximum value, $114{\mu}g/L$) under oxidizing ($H_2O_2$) conditions, whereas concentrations under other conditions (acidic-HCl, $neutral-NaHCO_3$, and $reducing-Na_2S_2O_3$) were negligible. This indicated that the geochemical conditions, in which soil-water reactions occurred to form groundwater with high vanadium concentrations, were under alkaline-oxidizing conditions. From the continuous leaching experiments, the pH and leached vanadium concentrations of the solution were in the ranges of 5.45~5.58 and $6{\sim}9{\mu}g/L$, respectively, under $CO_2$ supersaturation conditions for the first 15 days, whereas values under $O_2$ aeration conditions after the next 15 days increased to 8.48~8.62 and $9.7{\sim}12.2{\mu}g/L$, respectively. Vanadium concentrations from the latter continuous leaching experiments were similar to the average concentration of groundwater in Jeju Island ($11.2{\mu}g/L$). Furthermore leached vanadium concentrations in continuous leaching experiments were highly correlated with pH and Al, Cr, Fe, Mn and Zn concentrations. The results of this study showed that 1) alkaline-oxidizing conditions of water-rock (soil) interactions were essential to form vanadium-rich groundwater and 2) volcanic soils can be a potential source of vanadium in Jeju Island groundwater.

• Journal of Korean Society of Forest Science
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• v.89 no.5
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• pp.564-575
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• 2000

This study was carried out to reveal characteristics of long-term runoff by using HYCYMODEL in a small forested watershed. From May to September in 1998 and in 1999, the fitness of HYCYMODEL and runoff characteristics were estimated by HYCYMODEL using rainfall and discharge at the experimental watershed. The function of stage and discharge in the experimental watershed was determined as following equation $Q=11.148H^{2.5867}$($R^2=0.9956$). From May to September in 1998 and in 1999, the runoff rates were 57.7% in 1998 and 87.1% in 1999 at the experimental watershed. The discharge was assumed to be increased because of rainfall intensity difference and thinning. By applicability test, the HYCYMODEL showed good estimation of runoff by optimized fifteen parameters. Comparing runoff characteristics before and after thinning by calculating through HYCYMODEL, direct runoff and base runoff increased 4%, 7%, respectively as evapotranspiration decreased 11%. Parameters $D_{50}$ and $K_h$, which were related to the direct run, and a parameter $K_u$, which was related to the baseflow, were assumed to indicate that forest was changed by the effect of thinning and weathering process of bed rock.

• KSCE Journal of Civil and Environmental Engineering Research
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• v.33 no.4
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• pp.1499-1508
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• 2013

Freeze-thaw tests were performed on gneiss samples collected from Terra Nova Bay, Antarctica in order to examine the engineering properties of rocks with slightly weathered (SW) and moderately weathered (MW). The tests were conducted under temperature ranging from $20{\pm}2^{\circ}C$ to $-20{\pm}2^{\circ}C$. A cycle of test consisted of 5 hours of freezing followed by another 5 hours of thawing under full saturation. In this paper, total 200 cycles of freeze-thaw test were performed with measurements of porosity, absorption, ultrasonic velocity, and shore hardness per each 20 cycle and that of uniaxial compressive strength (UCS) per each 50 cycle. The UCS of the SW rocks approximately decreased 0.07 MPa per a single cycle, while that of MW rocks decreased around 0.2 MPa per a single cycle. During the 200 cycles of SW rocks, the absorption increased from 0.23% to 0.39%, the P-wave velocity decreased from 4,054 m/s to 3,227 m/s and S-wave velocity decreased from 2,519 m/s to 2,079 m/s. Similarly, those of MW rocks changed from 0.65% to 1.6%, 3,207 m/s to 2,133 m/s and 2,028 m/s to 1,357 m/s. In conclusion, it was inferred that the properties of SW rocks experienced approximately 200-300 cycles of freeze-thaw process become close to those of MW rocks.

• The Journal of Engineering Geology
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• v.17 no.2 s.52
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• pp.205-215
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• 2007

In this study, the soil characteristics are analyzed using the result of various soil tests as an object of the soil layer of natural slopes in landslides areas. Also, the relationship with landslides and interrelation with each soil properties are analyzed. The landslides in three areas with different geological condition are occurred due to heavy rainfall in same time. The geology of Jangheung area, Sangju area and Pohang area is gneiss, granite, and the tertiary sedimentary rock, respectively. However soil characteristics have a little differentiation to geological condition, the soils sampled from landslide area have higher proportion of fine particle and porosity, and lower density than those from non landslide area. In case of same geological condition, landslides are occurred in the terrain slope with high permeability. The permeability is mainly influenced by the soil characteristics such as particle size distribution, porosity, particle structure, and the geological origins such as weathering, sedimentary environment. The soil layer with high internal friction angle is more stable than that with low internal friction angle in all geological condition. The permeability is mainly influenced by effective particle size, coefficient of uniformity, coefficient of gradation, porosity, density and so on. Also, those have interrelation with each factor. These interrelations are similar in all study area. Meanwhile, in proportion as the void ratio and the porosity rises the permeability increases.

• Journal of the Korean GEO-environmental Society
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• v.11 no.8
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• pp.83-93
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• 2010

The purpose of this study is to present emergency rehabilitation, cause and the countermeasure of reinforcement about reinforced retaining wall and the slope collapse of the phyllite ground. The study area is broken easily because this area has rock mass discontinuity such as stratification, foliation, joint and fold. And this area consists of the ground where it happens easily to the failure of structure like reinforced retaining wall because of the phyllite ground sensitive to weathering. Counterweight fill in front of reinforced retaining wall was performed as emergency rehabilitation about displacement of reinforced retaining wall and the failure at the rear of slope on phyllite ground. After that, additional displacement didn't occur. Boring and geophysical exploration were launched to present emergency rehabilitation and develop the long-term method of reinforcement. This could grasp anticipated range of the failure section and identify internal and external factors of the cause of the slope collapse. Several methods of reinforcement were suggested by conducting the numerical analysis. When conducting design and construction of major structures at the ground which has complex discontinuities, the precise site investigation should be conducted. During construction, immediate action for over-displacement should be taken by performing the periodic measurement.

• The Korean Journal of Quaternary Research
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• v.3 no.1
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• pp.17-34
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• 1989

The distribution characteristics of incised meander river are analysed concerning topography, geology, stream order and altitude. Additionally geomorphological development of the Korean peninsular is considered with incised meander. The main findings are as follows: 1. The incised meander is intensively distributed on the west and north slope of T'aebak and Sobaek mountain range, but sparsely distributed on the opposite slopes. 2. Geologically, the occurrence rate of incised meander is high orderly as follows: Joseon supergroup, Pyeongan supergroup, Daedong supergroup metamorphic rock, Gyeongsang supergroup, and granite. The incised meander is developed well on the following conditions: hard rocks against weathering, stratified structure, geologic arrange across the river channel and contacting zone of geological formations. 3. The higher stream orders are, the higher occurrence of incised meander is. 4. Comparing the altitude of present river bed with the summit level of restored map, it is supposed that the incised meander rivers have been dissected about 300-500m down ward. 5. Considering the distribution characteristic of incised meander, it is suggested that not only T'aebak mountain range but Sobaek mountain range is the axis of asymmetrical up-warping in the Korean peninsular. 6. Considering the distribution characteristic of incised meander on the restored map and the stream order, it seems that present incised meander channel was inherited from antecedent meander river that had flowed on High and Middle level erosion surface. But the channel pattern has been modified.

• Journal of Conservation Science
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• v.25 no.2
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• pp.147-154
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• 2009

The change of strength and water vapour diffusion resistant by soluble salts was investigated in the tuff and granite used in many stone monuments of Gyeongju area. With $Na_2SO_4$ and $CaSO_4{\cdot}2H_2O$ were treated the rock samples to understand the difference of solubility. The densities of the tested rocks were increased by the impregnation of $CaSO_4{\cdot}2H_2O$ and $Na_2SO_4$. The flexural strength was increased in the tuff samples but decreased in the granite as the salts increased in the pore. In the tuff, the uniaxial compressive strength was increased by $CaSO_4{\cdot}2H_2O$, but decreased by $Na_2SO_4$. In the granite, it was decreased slightly by $CaSO_4{\cdot}2H_2O$, but increased by $Na_2SO_4$. The water vapour diffusion resistant was increased by the salts in both rocks. As results, it was cleared that the mechanical strength colud be increased in early stage of weathering by the accumulation of salt and water vapour diffusion resistant.

• The Journal of Engineering Geology
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• v.15 no.1
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• pp.9-17
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• 2005

A set of soil samples were picked up from a failed slope formed by rainfall in limestone zone in Jangseong-gun, Jeonnam, Korea, to find out its physical and mechanical characteristics for this study, and variation of safety factor depending on slope inclination was defined by analysing slope stability affected by rainfall. Decomposed limestone soil in the research area is composed of quartz, orthoclase, gibbsite, geothite, etc., with specific gravity of 2.73, and this soil is included in SC by unified soil classification system. Calcium ingredient decreased remarkably during weathering at its mother rock. Coefficient of permeability is 2.56×10/sup -4/ cm/ sec, similar to its value of silty clay. Cohesion decreases remarkably from 3.0 t/ ㎡ to 0.72 t/ ㎡, and Φ value of internal friction angle tends to decrease as it turns to be saturated soil from partial saturated soil in the shear test. To analyze slope stability affected by rainfall, it is reasonable to seek seepage depth with reference to rainfall＊ intensity. In the slope stability analysis, when the seepage depth is the larger, its safety factor is the less, which makes the slope unstable. Comparing with minimum safety factor, 1.5 of cut slope in consideration of the seep-age line, safety factor is found to be satisfactory only when inclination of cut slope of decomposed limestone soil is more than 1：1.2 slope at least considering rainfall. It is also found that decrease of cohesion has great effect on decline of safety factor of slope while partial saturated soil turns to be saturated soil.

• Economic and Environmental Geology
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• v.34 no.6
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• pp.539-553
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• 2001

Geochemical data of the Han river water, including four tributary water samples in the main Han river are presented in this paper. The concentration of dissolved ions in the North Han river water decreases in order of Ca>Na>K>Mg and HCO$_3$>NO$_3$>SO$_4$>Cl, which it mainly affected by the chemical weathering of granite and gneiss in the drainage basin. Meanwhile, the South Han river water shows a decreasing order of Ca>Mg>Na>K and HCO$_3$>SO$_4$>NO$_3$>Cl, which is controlled by the bed rock geology of carbornate rooks and the inflow of acid mine drainage from the metal and coal mines in the Taebaegsan and Hwanggangri areas. The main Han river waters are characterized by unusually high concentration of Na, Cl and SO$_4$ (Ca>Na>K>Mg and HCO$_3$>SO$_4$>CI>NO), indicating a significant anthropogenic pollution by human activities in the metropolitan Seoul city. The geochemical data of the Han river waters from 1981 through 1996 to 1999 records a significant increase in SO$_4$ and NO$_3$, which responsible for the increasing arid mane drainage and municipal anthropogenic pollution.

• The Journal of the Petrological Society of Korea
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• v.16 no.1 s.47
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• pp.27-37
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• 2007

Here we discuss a geochemical characterisitc of rare earth element (REE) pattern of a Precambrain leucogranitic gneiss at Imweon, Gangwon Province, Korea. The outcrop includes biotite gneiss xenolith. The leucocratic granite gneiss contacting with biotite gneiss is pegmatitic. However, there is no evidence of contact metamorphism between biotite gneiss and leucocratic-pegmatitic granite gneiss. The leucocratic granite gneiss shows a specific phenomenon of M-type (convex curved) tetrad effect in chondrite-normalized REE patterns with large negative Eu anomaly. The degree of REE tetrad effect in the leucocratic-pegmatitic granitec gneiss is weak and shows partly W-type (concave curved) tetrad effect. The Eu anomaly of leucocratic granite gneiss has close relationship with the degree of tetrad effect as well as Ca/Sr ratio. Our results suggest that the REE tetrad effect from the leucocratic granite gneiss should be formed during differentiation process of granitic magma. We also confirmed that the weathering might affect Eu or Ce anomaly rather than the formation of REE tetrad effect in granitic rock.