• Title/Summary/Keyword: ring transformation

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Total Synthesis of 11-Deoxy-$\beta$-rhodomycinone Antitumor Antibiotics (항암항생제 11-Deoxy-$\beta$-rhodomycinone의 합성)

  • 노영쇠;강혼수;신홍식
    • YAKHAK HOEJI
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    • v.37 no.6
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    • pp.555-560
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    • 1993
  • Methyl 3-[(phenylsulfonyl)methyl]-1, 4, 8-trimethoxy-2-naphthoate(7) preparad by 3 steps was condensed with 5-ethyl-2-cyclohexen-1-one(8) to afford the teracyclic aromatic ring system compound 10, which was stepwise converted into the precursor of 11-Deoxy-$\beta$-rhodomycinone by means of various functional groups transformation.

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Flexure Analysis of Inertial Navigation Systems

  • Kim, Kwang-Jin;Park, Chan-Gook;Park, Jai-Yong
    • 제어로봇시스템학회:학술대회논문집
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    • 2004.08a
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    • pp.1958-1961
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    • 2004
  • Ring Laser Gyroscopes used as navigational sensors inherently experience a lock-in region, where very low rotational rates are not measurable. Most RLG manufacturers use a mechanical dither motor that applies a small oscillatory rotational motion larger than this region to resolve this problem. Any input acceleration that bends this dithering axis causes flexure error, which is a noncommutative error that can not be compensated by simply using integrated gyro sensor output. This paper introduces noncommutative error equations that define attitude errors caused by flexure errors. In this paper, flexure error is classified as sensor level error if the sensing axis coincides with the dithering axis and as system level error if the two axes do not coincide. The relationship between gyro output and the rotation vector is introduced and is used to define the coordinate transformation matrix and angular motion. Equations are derived for both sensor level and system level flexure error analysis. These equations show that RLG based INS attitude error caused by flexure is directly proportional to time, amount of input acceleration and the dynamic frequency of the vehicle.

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Synthesis of Phenolbetaine Derivatives : Introduction of Functional Groups to C-ring and Chemical Transformation of BC-ring of Protoberberine (페놀베타인 유도체합성 : 프로토베르베린에서 C-환의 관능기도입 및 BC-환의 화학적 변환)

  • Woo, Seong-Ju;Hwang, Soon-Ho;Park, Yea-Jin;Hong, You-Hwa;Lee, Ma-Se;Kim, In-Jong;Kim, Sin-Kyu
    • YAKHAK HOEJI
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    • v.40 no.6
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    • pp.621-624
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    • 1996
  • Betaine was treated with hydrochloric acid and then with sodium borohydride to give a hydroxy compound 2. The reaction of 2 with thionyl chloride followed by thiourea led a comp ound 5. Oxidation of compound 2 with pyridinium dichromate(PDC) and succesive treatment with Lawesson's reagent also afforded the same compound 5. Cleavage of N-C14 bond compound of 7 was carried out via two reaction sequence from the compound 4. Finally, compound 10 was sythesized by a series of transformations from the compound 4.

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CONTACT PRESSURE DISTRIBUTION OF RADIAL TIRE IN MOTION WITH CAMBER ANGLE

  • Kim, Seok-Nam;Kondo, Kyohei;Akasaka, Takashi
    • Proceedings of the KSME Conference
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    • 2000.11a
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    • pp.387-394
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    • 2000
  • Theoretical and experimental study is conducted on the contact pressure distribution of a radial tire in motion under various camber angles. Tire construction is modelled by a spring bedded elastic ring, consisted of sidewall springs and a composite belt ring. The contact area is assumed to be a trapezoidal shape varying with camber angles and weighted load. The basic equation in a quasi-static form is derived for the deformation of a running belt with a constant velocity by the aid of Lagrange-Euler transformation. Galerkin's method and stepwise calculation are applied for solving the basic equation and the mechanical boundary condition along both sides of the contact belt part subjected to shearing forces transmitted from the sidewall spring. Experimental results on the contact pressure, measured by pressure sensors embedded in the surface of the drum tester, correspond well with the calculated ones for the test tire under various camber angles, running velocities and weighted loads. These results indicate that a buckling phenomenon of the contact belt in the widthwise direction occurs due to the effect of camber angle.

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The Facile Synthesis of Pyrrolidinobenzenes from Succinaldehyde and Phenylenediamines using HFe(CO)$_4^-$ (사카르보닐 철산염, HFe(CO)$_4^-$을 이용한 숙신알데히드와 페닐렌디아민으로부터 피로리디노벤젠의 편리한 합성)

  • Sim, Sang Cheol;U, Byeong Won;Do, Chil Hun;Choe, Gwi Nam;Yeo, Yeong Guk
    • Journal of the Korean Chemical Society
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    • v.34 no.6
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    • pp.641-645
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    • 1990
  • Ethanolic tetracarbonylhydridoferrate, HFe(CO)$_4^-$, combined with aqueous succinaldehyde is very efficient for the selective transformation of an amino group into a pyrrolidine ring. Phenylendiamines react with aqueous succinaldehyde in the presence of HFe(CO)$_4^-$, at room temperature under atmospheric pressure of carbon monoxide to give the corresponding pyrrolidines in moderate yields. In these reactions, the molar ratio of 1.0:1.0:1.0 of the ferrate-succinaldehydephenylenediamine system gave one pyrrolidine ring, and the case of 1.0:2.0:1.0 gave two pyrrolidine rings, selectively.

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Dynamic Characteristics of Metal-induced Unilaterally Crystallized Polycrystalline Silicon Thin-film Transistor Devices and Circuits Fabricated with Precrystallization (선결정화법을 이용한 금속 유도 일측면 결정화에 의해 제작된 다결정 실리콘 박막 트랜지스터 소자 및 회로의 전기적 특성 개선 효과)

  • Hwang, Wook-Jung;Kang, Il-Suk;Kim, Young-Su;Yang, Jun-Mo;Ahn, Chi-Won;Hong, Soon-Ku
    • Journal of the Korean Vacuum Society
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    • v.17 no.5
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    • pp.461-465
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    • 2008
  • The phase transformation in a film influences its surrounding. Effects of the precrystallization method, which removes influences on gate oxide caused by lateral crystallization, in metal-induced unilaterally crystallized polycrystalline silicon thin-film transistor devices and circuits were studied. Device by the method was shown to have a higher current drive, compared with conventional postcrystallized device. Moreover, we studied DC bias-induced changes in the performance of ring oscillator. PMOS inverters fabricated using precrystallized silicon films have very high dynamic and stable performance, compared with inverters fabricated using postcrystallized silicon films.

Image Calibration Techniques for Removing Cupping and Ring Artifacts in X-ray Micro-CT Images (X-ray micro-CT 이미지 내 패임 및 동심원상 화상결함 제거를 위한 이미지 보정 기법)

  • Jung, Yeon-Jong;Yun, Tae-Sup;Kim, Kwang-Yeom;Choo, Jin-Hyun
    • Journal of the Korean Geotechnical Society
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    • v.27 no.11
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    • pp.93-101
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    • 2011
  • High quality X-ray computed microtomography (micro-CT) imaging of internal microstructures and pore space in geomaterials is often hampered by some inherent noises embedded in the images. In this paper, we introduce image calibration techniques for removing the most common noises in X-ray micro-CT, cupping (brightness difference between the periphery and central regions) and ring artifacts (consecutive concentric circles emanating from the origin). The artifacts removal sequentially applies coordinate transformation, normalization, and low-pass filtering in 2D Fourier spectrum to raw CT-images. The applicability and performance of the techniques are showcased by describing extraction of 3D pore structures from micro-CT images of porous basalt using artifacts reductions, binarization, and volume stacking. Comparisions between calibrated and raw images indicate that the artifacts removal allows us to avoid the overestimation of porosity of imaged materials, and proper calibration of the artifacts plays a crucial role in using X-ray CT for geomaterials.

The Research on Extraction of Topology Model Using Straight Medial Axis Transformation Algorithm (SMAT 알고리즘을 이용한 위상학적 모델 추출 방법)

  • Park, So-Young;Lee, Ji-Yeong
    • Spatial Information Research
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    • v.20 no.2
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    • pp.117-127
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    • 2012
  • The purpose of this study is to develop the auto-building algorithm of the Geometric Network Model(GNM), a topology model including geometric information because of the need to reflect the features' geometric characteristic into the topology model, which is for development of indoor 3D virtual model enabling queries. As the critical algorithm, the Straight Medial Axis Transformation(SMAT) algorithm is proposed in order to automatically extract the medial axis of features. The SMAT algorithm is generalized from the existing S-MAT algorithm and a range of target features where applicable is extended from simple polygons to weakly simple polygons which mean the polygons containing the inner ring inside. The GNM built automatically is finally printed out as the .csv file for easy access and w ide application in other systems. This auto-building algorithm of the GNM is available for plenty of cases such as finding a shortest path, guiding a route in emergency situation, and semantic analysis.

오존에 의한 토양유기물질의 구조적 변화 특성

  • 정해룡;배기진;최희철
    • Proceedings of the Korean Society of Soil and Groundwater Environment Conference
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    • 2001.04a
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    • pp.45-48
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    • 2001
  • The packed column experiments were conducted with a field soil, collected directly from the aquifer located at Bonchon industrial complex in K-city in order to characterize SOM reaction with ozone and to delineate the transformation of water soluble SOM after ozonation. As reaction time increased, water soluble organic matter increased, and this organic matter was in the range of 500∼1000 dalton. pH of extractants decreased with the increase of ozonation time. This Is because aromtic compounds in SOM were oxidized and carboxylic acid groups were formed. From the FT-IR spectra, the content of carboxylate increased as ozone injection time increased and hydroxyl group, which represents phenolic and alcoholic hydroxyl groups decreased. This is because oxidative ring fission formed carboxyl acid groups. This result provides a good agreement with pH decrease.

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Implementation of the rotating tool clamping device using a shape memory alloy (형상기억합금을 이용한 회전공구 클램핑 장치 구현)

  • Chung, J.M.;Park, J.K.;Lee, D.J.;Shin, W.C.
    • Transactions of the Korean Society of Machine Tool Engineers
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    • v.17 no.1
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    • pp.16-20
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    • 2008
  • This paper presents the construction of micro tool clamping device using a Ni-Ti shape memory alloy(SMA) ring. Clamping force of the device is produced by elastic force of the SMA reverted to its original shape in normal temperature. Phase transformation of the SMA was realized by temperature control using a peltier element. Prototype of the SMA tool clamping device was fabricated and examined its clamping force and clamping/unclamping operation.